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Low silicon high strength low alloy steel

Assignee: Jones and Laughlin Steel Inc
•
Filing: 1975-10-02
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Granted: 1976-09-28
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Expires: 1995-10-02
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Abstract

Abstract The incidence of rare earth oxy-sulfide inclusions in killed hot-rolled high strength low alloy steels of the vanadium-nitrogen type is lowered through restriction of the silicon content to 0.05% maximum without a concurrent reduction of yield strength to values below 80,000 p.s.i. through a balance of composition, product thickness and hot-rolling collection temperature.

Inventors

  • 👤 Peter J. Koros
  • 👤 John David Grozier

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 21:17
CPC Classifications
C; C21; C21D; C21D8/00; C21D8/02; C21D8/0221; C21D8/0226

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 175 words
A killed high strength low alloy steel product having been hot-rolled to a thickness, spray cooled, and collected immediately thereafter at temperature of from 950° to 1300° F.; having a composition consisting essentially of from 0.09% to 0.22% carbon, 1.65% maximum manganese, 0.05% maximum silicon, 0.25% maximum sulfur, from 0.015% to 0.031% nitrogen, from 0.10% to 0.14% vanadium, from 0.01% to 0.10% rare earth or rare earth mixture, 0.01% to 0.09% aluminum, balance iron; said steel composition, thickness and collection temperature also satisfying the following relationship; YS ≦98,430+182,310 (V)+80,662 (C) + 433,220 (N) -36.7 (CT)-26,184(T) -92,543 (Al), wherein, Ys = yield Strength and is 88,776 p.s.i.; V = % vanadium; C = % carbon; N = % nitrogen; Ct = collection Temperature, ° F; T = hot-Rolled Thickness, inches; and Al = % Aluminum; and said steel product having an ultimate tensile strength of 95,000 p.s.i. minimum, a yield strength of 80,000 p.s.i. minimum and ductility as measured by percent elongation (2 inches) 18% minimum; and being substantially free of macroscopic rare earth oxy-sulfide inclusions.
Claim 2
Dependent Claim 175 words
A killed high strength low alloy steel product having been hot-rolled to a thickness, spray cooled, and collected immediately thereafter at temperature of from 950° to 1300° F.; having a composition consisting essentially of from 0.09% to 0.22% carbon, 1.65% maximum manganese, 0.05% maximum silicon, 0.25% maximum sulfur, from 0.015% to 0.031% nitrogen, from 0.10% to 0.14% vanadium, from 0.01% to 0.10% rare earth or rare earth mixture, 0.01% to 0.09% aluminum, balance iron; said steel composition, thickness and collection temperature also satisfying the following relationship; YS ≦98,430+182,310 (V)+80,662 (C) + 433,220 (N) -36.7 (CT)-26,184(T) -92,543 (Al), wherein, Ys = yield Strength and is 88,776 p.s.i.; V = % vanadium; C = % carbon; N = % nitrogen; Ct = collection Temperature, ° F; T = hot-Rolled Thickness, inches; and Al = % Aluminum; and said steel product having an ultimate tensile strength of 95,000 p.s.i. minimum, a yield strength of 80,000 p.s.i. minimum and ductility as measured by percent elongation (2 inches) 18% minimum; and being substantially free of macroscopic rare earth oxy-sulfide inclusions.
Claim 3
Dependent Claim 21 words
The killed high strength low alloy steel product of claim 1, wherein the collection temperature ranges from 950° to 1200° F.
Claim 4
Dependent Claim 18 words
The killed high strength low alloy steel of claim 1, wherein said carbon ranges from 0.13% to 0.22%.
Claim 5
Dependent Claim 18 words
The killed high strength low alloy steel of claim 1, wherein said nitrogen ranges from 0.024% to 0.031%.
Claim 6
Dependent Claim 18 words
The killed high strength low alloy steel of claim 1, wherein said vanadium ranges from 0.12% to 0.14%.
Claim 7
Dependent Claim 18 words
The killed high strength low alloy steel of claim 1, wherein said aluminum ranges from 0.01% to 0.07%.
Claim 8
Dependent Claim 17 words
The killed high strength low alloy steel of claim 1, wherein said silicon content is 0.03% maximum.
Claim 9
Independent Claim 223 words
A method of producing a high strength low alloy steel product, comprising: a. hot rolling a killed steel having a composition consisting essentially of from 0.09% to 0.22% carbon, 1.65% maximum manganese, 0.05% maximum silicon, 0.025% maximum sulfur, from 0.015% to 0.31% nitrogen, from 0.10% to 0.14% vanadium, from 0.01% to 0.10% rare earth or rare earth mixture, 0.01% to 0.09% aluminum, balance iron to a thickness at a finishing temperature of above the Ar 3 temperature of the steel to about 1700° F., spray cooling said hot-rolled steel at a rate of from 20° F. to 135° F. per second, and collecting said hot-rolled steel at a temperature of from 950° F. to 1300° F. immediately upon termination of spray cooling so as to produce a hot-rolled product having an ultimate tensile strength of 95,000 p.s.i. minimum, a yield strength of 80,000 p.s.i. minimum, and ductility as measured by percent elongation (2 inches) of 18% minimum and substantially free of macroscopic rare earth oxy-sulfides inclusions, said steel composition, thickness and collection temperature also satisfying the following relationship: YS ≦98,430+182,310 (V)+80,662 (C)+433,220 (N)- 36.7(CT)-26,184(T) -92,543 (Al), wherein, Ys = yield Strength and is 88,776 p.s.i. V = % vanadium; C = % carbon; N = % nitrogen; Ct = collection Temperature, ° F; T = hot-Rolled Thickness, inches; and Al = % Aluminum.
Claim 10
Independent Claim 223 words
A method of producing a high strength low alloy steel product, comprising: a. hot rolling a killed steel having a composition consisting essentially of from 0.09% to 0.22% carbon, 1.65% maximum manganese, 0.05% maximum silicon, 0.025% maximum sulfur, from 0.015% to 0.31% nitrogen, from 0.10% to 0.14% vanadium, from 0.01% to 0.10% rare earth or rare earth mixture, 0.01% to 0.09% aluminum, balance iron to a thickness at a finishing temperature of above the Ar 3 temperature of the steel to about 1700° F., spray cooling said hot-rolled steel at a rate of from 20° F. to 135° F. per second, and collecting said hot-rolled steel at a temperature of from 950° F. to 1300° F. immediately upon termination of spray cooling so as to produce a hot-rolled product having an ultimate tensile strength of 95,000 p.s.i. minimum, a yield strength of 80,000 p.s.i. minimum, and ductility as measured by percent elongation (2 inches) of 18% minimum and substantially free of macroscopic rare earth oxy-sulfides inclusions, said steel composition, thickness and collection temperature also satisfying the following relationship: YS ≦98,430+182,310 (V)+80,662 (C)+433,220 (N)- 36.7(CT)-26,184(T) -92,543 (Al), wherein, Ys = yield Strength and is 88,776 p.s.i. V = % vanadium; C = % carbon; N = % nitrogen; Ct = collection Temperature, ° F; T = hot-Rolled Thickness, inches; and Al = % Aluminum.
Claim 11
Dependent Claim 16 words
The method of claim 8, wherein said collection temperature is from 950° F. to 1200° F.

References Cited (Backward Citations)

US3666452A Cited
US3926686A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-09-28 1980-03-29 1980-09-28 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-09-28 1984-03-29 1984-09-28 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-09-28 1988-03-29 1988-09-28 $7700.00 Window Closed / Lapsed

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