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US3981895A
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Novel autoxidative derivatives of maleinized monocarboxylic fatty acid
Assignee: Dulux Australia Ltd
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Filing: 1974-11-29
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Granted: 1976-09-21
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Expires: 1994-11-29
Abstract
Abstract Novel derivatives of maleinized fatty acids are disclosed. The derivatives comprise mono-esters of both a selected type of diol and an alkylene oxide, they contain free carboxyl and hydroxyl groups and have acid values of 40-100 mg KOH per g. They are useful film-forming components of high-solids coating compositions.
Inventors
- 👤 Bruce Leary
- 👤 Frederick John Lubbock
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-04 20:24
CPC Classifications
C; C11; C11C; C11C3/00; C09; C09D; C09D167/00; C09D167/08
Claims Analysis
Total Claims: 3
Claim 1
Independent Claim
180 words
A derivative of an autoxidisable maleinised monocarboxylic fatty acid, said derivative being the product obtained by heating together: a. an autoxidisable maleinised monocarboxylic fatty acid comprising the reaction product of 1 mol of maleic anhydride per mol of monocarboxylic fatty acid and b. a diol selected from 2,2-bis (4-hydroxy cyclohexyl)propane and the reaction product of 1 mol of 2,2-bis (p-hydroxy phenyl)propane with 2 mol of an alkylene oxide selected from ethylene, propylene and butylene oxide, so as to form a mono-ester of said diol and open the maleic anhydride ring, and reacting the resulting ring-opened product by heating with c. an alkylene oxide selected from ethylene, propylene and butylene oxide and a compound of the formula: ##EQU4## where x, y and z are integers and x + y + z = 4-6 inclusive, so as to obtain a mono-ester of said oxide (c), said derivative being characterised by having both carboxyl and hydroxyl groups, and an acid value of 40-100 KOH/gm and being further characterised by the presence of a mono-ester linkage of (b) and a mono-ester linkage of (c).
Claim 2
Dependent Claim
180 words
A derivative of an autoxidisable maleinised monocarboxylic fatty acid, said derivative being the product obtained by heating together: a. an autoxidisable maleinised monocarboxylic fatty acid comprising the reaction product of 1 mol of maleic anhydride per mol of monocarboxylic fatty acid and b. a diol selected from 2,2-bis (4-hydroxy cyclohexyl)propane and the reaction product of 1 mol of 2,2-bis (p-hydroxy phenyl)propane with 2 mol of an alkylene oxide selected from ethylene, propylene and butylene oxide, so as to form a mono-ester of said diol and open the maleic anhydride ring, and reacting the resulting ring-opened product by heating with c. an alkylene oxide selected from ethylene, propylene and butylene oxide and a compound of the formula: ##EQU4## where x, y and z are integers and x + y + z = 4-6 inclusive, so as to obtain a mono-ester of said oxide (c), said derivative being characterised by having both carboxyl and hydroxyl groups, and an acid value of 40-100 KOH/gm and being further characterised by the presence of a mono-ester linkage of (b) and a mono-ester linkage of (c).
Claim 3
Dependent Claim
30 words
The derivative of claim 1 wherein (c) is a compound of the formula: ##EQU5## where x, y and z are integers and x + y + z = 4-6 inclusive.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1979-09-21 | 1980-03-22 | 1980-09-21 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1983-09-21 | 1984-03-22 | 1984-09-21 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1987-09-21 | 1988-03-22 | 1988-09-21 | $7700.00 | Window Closed / Lapsed |