Patent US3981884A successfully refreshed from Google Patents.
US3981884A
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US
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Multichromophoric benzotriazole ultraviolet stabilizers
Assignee: Eastman Kodak Co
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Filing: 1974-09-03
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Granted: 1976-09-21
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Expires: 1994-09-03
Abstract
Abstract The invention relates to multichromophoric compounds which have been found to be effective ultraviolet stabilizers. The invention also relates to ultraviolet degradable organic compositions containing a stabilizing amount of the multichromophoric composition to prevent such degradation. These stabilizers are effective in the presence of other additives commonly employed in polymeric compositions including, for example, pigments, colorants, fillers, reinforcing agents and the like. These ultraviolet stabilizers may also be incorporated into the organic compositions in the polymer melt or dissolved in the polymer dope, coated on the exterior of the molded article, film or extruded fiber.
Inventors
- 👤 Richard H. S. Wang
- 👤 Joseph S. Zannucci
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-06 15:03
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/16; C08K5/34; C08K5/3442; C07; C07D; C07D249/00; C07D249/16; C07D249/18; C07D249/20; C08K5/3467; C08K5/3472; C08K5/3475; C09; C09K; C09K15/00; C09K15/04; C09K15/30
Claims Analysis
Total Claims: 35
Claim 1
Independent Claim
302 words
A composition of matter comprising multichromophoric compounds having the formula: A--B--C wherein A is a group having the structure ##SPC6## wherein R 1 , r 2 , r 3 and R 4 are hydrogen, chloro, bromo, lower alkyl, cycloalkyl, phenyl, lower alkyl phenyl, phenyl-substituted-phenyl, alkoxy, cyano, carboxy and the substituents R 1 R 2 , R 2 and R 3 , and R 3 and R 4 , combined with the carbon atoms to which they are attached, are joined alkylene groups completing a carbocyclic ring, which ring can also be substituted with one or more of the substituents listed above for R 1 , R 2 , R 3 and R 4 ; I is the same as R 1 , R 2 , R 3 and R 4 and is present on all positions of the benzenoid ring, except the carbon atom attached to the heterocyclic ring and the carbon atom attached to the B group connecting the heterocyclic aromatic A group with the aromatic C group, wherein B is a linking group connecting A and C and is alkylene, phenylene, carbonyloxy, oxycarbonylalkyleneoxy, oxycarbonyl, alkyleneoxycarbonyloxy, oxyalkylenecarbonyloxy, oxycarbonyloxy, alkyleneoxy, oxyalkylene, alkyleneoxyalkyleneoxy, oxyalkylenephenylenealkyleneoxy, sulfinyldioxy, oxy(alkoxy)phosphinooxy, N-alkylamino carbonyl, N-phenylaminocarbonyl, N-alkylaminocarbonylalkyleneoxy, N-phenylaminocarbonylalkyleneoxy, N-alkylaminocarbonylamino, N,N-dialkylaminocarbonyl, N-phenylaminocarbonyl, N-alkylaminocarbonyl, N,N-diphenylaminocarbonyl, N-alkylamino, N-phenylamino, N-alkylaminoalkyleneoxy, N-phenylaminoalkyleneoxy, oxyalkyleneoxy, oxyphenyleneoxy, alkyleneaminoalkylene, phenyleneaminophenylene, phenyleneaminoalkylene and alkyleneaminophenylene; and wherein C is a hydroxybenzophenone group having the formula ##SPC7## wherein I is the same substituent as listed above and is present in all positions of the benzoid rings except the carbon atom attached to the B group connecting the A and C moieties, said B connecting group is attached to the benzoid ring in the ortho, meta or para position from the keto group of the benzophenone, and said I substituents can all be one of the substituents listed above or different listed substituents.
Claim 2
Dependent Claim
302 words
A composition of matter comprising multichromophoric compounds having the formula: A--B--C wherein A is a group having the structure ##SPC6## wherein R 1 , r 2 , r 3 and R 4 are hydrogen, chloro, bromo, lower alkyl, cycloalkyl, phenyl, lower alkyl phenyl, phenyl-substituted-phenyl, alkoxy, cyano, carboxy and the substituents R 1 R 2 , R 2 and R 3 , and R 3 and R 4 , combined with the carbon atoms to which they are attached, are joined alkylene groups completing a carbocyclic ring, which ring can also be substituted with one or more of the substituents listed above for R 1 , R 2 , R 3 and R 4 ; I is the same as R 1 , R 2 , R 3 and R 4 and is present on all positions of the benzenoid ring, except the carbon atom attached to the heterocyclic ring and the carbon atom attached to the B group connecting the heterocyclic aromatic A group with the aromatic C group, wherein B is a linking group connecting A and C and is alkylene, phenylene, carbonyloxy, oxycarbonylalkyleneoxy, oxycarbonyl, alkyleneoxycarbonyloxy, oxyalkylenecarbonyloxy, oxycarbonyloxy, alkyleneoxy, oxyalkylene, alkyleneoxyalkyleneoxy, oxyalkylenephenylenealkyleneoxy, sulfinyldioxy, oxy(alkoxy)phosphinooxy, N-alkylamino carbonyl, N-phenylaminocarbonyl, N-alkylaminocarbonylalkyleneoxy, N-phenylaminocarbonylalkyleneoxy, N-alkylaminocarbonylamino, N,N-dialkylaminocarbonyl, N-phenylaminocarbonyl, N-alkylaminocarbonyl, N,N-diphenylaminocarbonyl, N-alkylamino, N-phenylamino, N-alkylaminoalkyleneoxy, N-phenylaminoalkyleneoxy, oxyalkyleneoxy, oxyphenyleneoxy, alkyleneaminoalkylene, phenyleneaminophenylene, phenyleneaminoalkylene and alkyleneaminophenylene; and wherein C is a hydroxybenzophenone group having the formula ##SPC7## wherein I is the same substituent as listed above and is present in all positions of the benzoid rings except the carbon atom attached to the B group connecting the A and C moieties, said B connecting group is attached to the benzoid ring in the ortho, meta or para position from the keto group of the benzophenone, and said I substituents can all be one of the substituents listed above or different listed substituents.
Claim 3
Dependent Claim
208 words
A composition of matter according to claim 1 having the formula: ##SPC8## wherein E is a member selected from the group consisting of a branched or unbranched alkylene group containing 1 to 8 carbon atoms, carbonylalkylene group containing 2 to 9 carbon atoms, alkylenecarbonyl group containing 2 to 9 carbon atoms, an alkylene phenylenealkylene group containing 8 to 18 carbon atoms, and F is oxygen, nitrogen or sulfur; R 1 , r 2 , r 3 and R 4 are hydrogen, chloro, bromo, lower alkyl, cycloalkyl, phenyl, lower alkyl phenyl, alkoxy, amino, cyano, carboxy and the substituents R 1 and R 2 , R 2 and R 3 , R 3 and R 4 , combined with the carbon atoms to which they are attached, are joined alkylene groups completing a carbocyclic ring, which ring is substituted with one or more of the substituents listed above for R 1 R 2 , R 3 and R 4 ; I is the same as R 1 , R 2 R 3 and R 4 and is present on all positions of the benzenoid ring, except the carbon atom attached to the FEF substituent, said I substituent can all be one of the substituents listed above or different listed substituents.
Claim 4
Dependent Claim
12 words
A composition of matter according to claim 2 having the formula: ##SPC9##
Claim 5
Dependent Claim
12 words
A composition of matter according to claim 2 having the formula: ##SPC10##
Claim 6
Dependent Claim
12 words
A composition of matter according to claim 2 having the formula: ##SPC11##
Claim 7
Dependent Claim
12 words
A composition of matter according to claim 2 having the formula: ##SPC12##
Claim 8
Dependent Claim
12 words
A composition of matter according to claim 2 having the formula: ##SPC13##
Claim 9
Dependent Claim
12 words
A composition of matter according to claim 2 having the formula: ##SPC14##
Claim 10
Dependent Claim
12 words
A composition of matter according to claim 2 having the formula: ##SPC15##
Claim 11
Dependent Claim
12 words
A composition of matter according to claim 2 having the formula: ##SPC16##
Claim 12
Dependent Claim
12 words
A composition of matter according to claim 2 having the formula: ##SPC17##
Claim 13
Dependent Claim
12 words
A composition of matter according to claim 2 having the formula: ##SPC18##
Claim 14
Dependent Claim
12 words
A composition of matter according to claim 2 having the formula: ##SPC19##
Claim 15
Dependent Claim
12 words
A composition of matter according to claim 2 having the formula: ##SPC20##
Claim 16
Dependent Claim
12 words
A composition of matter according to claim 2 having the formula; ##SPC21##
Claim 17
Dependent Claim
12 words
A composition of matter according to claim 2 having the formula: ##SPC22##
Claim 18
Dependent Claim
12 words
A composition of matter according to claim 2 having the formula: ##SPC23##
Claim 19
Dependent Claim
12 words
A composition of matter according to claim 2 having the formula: ##SPC24##
Claim 20
Dependent Claim
12 words
A composition of matter according to claim 2 having the formula: ##SPC25##
Claim 21
Dependent Claim
12 words
A composition of matter according to claim 2 having the formula: ##SPC26##
Claim 22
Dependent Claim
12 words
A composition of matter according to claim 2 having the formula: ##SPC27##
Claim 23
Dependent Claim
12 words
A composition of matter according to claim 2 having the formula: ##SPC28##
Claim 24
Dependent Claim
12 words
A composition of matter according to claim 2 having the formula: ##SPC29##
Claim 25
Dependent Claim
12 words
A composition of matter according to claim 2 having the formula: ##SPC30##
Claim 26
Dependent Claim
12 words
A composition of matter according to claim 2 having the formula: ##SPC31##
Claim 27
Dependent Claim
12 words
A composition of matter according to claim 2 having the formula: ##SPC32##
Claim 28
Dependent Claim
12 words
A composition of matter according to claim 2 having the formula: ##SPC33##
Claim 29
Dependent Claim
12 words
A composition of matter according to claim 2 having the formula: ##SPC34##
Claim 30
Dependent Claim
12 words
A composition of matter according to claim 2 having the formula: ##SPC35##
Claim 31
Dependent Claim
12 words
A composition of matter according to claim 2 having the formula: ##SPC36##
Claim 32
Dependent Claim
12 words
A composition of matter according to claim 2 having the formula: ##SPC37##
Claim 33
Dependent Claim
12 words
A composition of matter according to claim 2 having the formula: ##SPC38##
Claim 34
Dependent Claim
12 words
A composition of matter according to claim 2 having the formula: ##SPC39##
Claim 35
Dependent Claim
12 words
A composition of matter according to claim 2 having the formula: ##SPC40##
References Cited (Backward Citations)
US3766205A
Cited
GB1212466A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1979-09-21 | 1980-03-22 | 1980-09-21 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1983-09-21 | 1984-03-22 | 1984-09-21 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1987-09-21 | 1988-03-22 | 1988-09-21 | $7700.00 | Window Closed / Lapsed |