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US3980693A Expired / Lapsed US ⏱️ 0.0 years remaining

N-(Trihalomethylthio)-carbamic acid oxime esters

Assignee: Bayer AG
•
Filing: 1975-02-24
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Granted: 1976-09-14
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Expires: 1995-02-24
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Abstract

Abstract N-(trihalomethylthio)-carbamic acid oxime ester of the formula ##EQU1## IN WHICH R is alkyl; cycloalkyl; or aryl optionally carrying at least one halogen, nitro, C 1 -C 6 alkyl, trifluoromethyl or C 1 -C 6 alkoxy radical; R' and R" each independently is alkyl or alkenyl optionally substituted by an alkoxycarbonyl or amidocarbonyl radical; cycloalkyl; aryl optionally carrying at least one halogen, nitrile, nitro, trifluoromethyl, C 1 -C 6 alkyl or C 1 -C 6 alkoxy radical; nitrile; halogen; alkoxycarbonyl; or amidocarbonyl; or R' and R", conjointly with the carbon atom that links them, form a cycloalkylidene group with 5 or 6 carbon atoms optionally carrying at least one C 1 -C 6 alkyl, C 1 -C 6 alkylene or cycloalkyl radical; and n is 0, 1, 2 or 3, Which possess fungicidal and microbicidal properties.

Inventors

  • 👤 Engelbert Kuhle
  • 👤 Erich Klauke
  • 👤 Brigitte Hamburger
  • 👤 Hans Scheinpflug

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 10:54
CPC Classifications
A; A01; A01N; A01N47/00; A01N47/08; A01N47/10; A01N47/24

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 149 words
An N-(trihalomethylthio)carbamic acid oxime ester of the formula ##EQU8## in which R is alkyl of up to 4 carbon atoms; or phenyl optionally carrying at least one halogen, nitro, C 1 -C 6 alkyl, trifluoromethyl or C 1 -C 6 alkoxy radical; R' is alkyl or alkenyl of up to 20 carbon atoms optionally substituted by an alkoxycarbonyl with a total of up to 5 carbon atoms or an amidocarbonyl radical; cyclohexyl; phenyl optionally carrying at least one halogen, nitro, trifluoromethyl, C 1 -C 6 alkyl or C 1 -C 6 alkoxy radical; halogen; alkoxycarbonyl with a total of up to 7 carbon atoms; or amidocarbonyl; R" is alkyl or alkenyl of up to 20 carbon atoms substituted by an alkoxycarbonyl with a total of up to 5 carbon atoms; or alkoxycarbonyl with a total of up to 7 carbon atoms; and n is 0, 1, 2 or 3.
Claim 2
Dependent Claim 149 words
An N-(trihalomethylthio)carbamic acid oxime ester of the formula ##EQU8## in which R is alkyl of up to 4 carbon atoms; or phenyl optionally carrying at least one halogen, nitro, C 1 -C 6 alkyl, trifluoromethyl or C 1 -C 6 alkoxy radical; R' is alkyl or alkenyl of up to 20 carbon atoms optionally substituted by an alkoxycarbonyl with a total of up to 5 carbon atoms or an amidocarbonyl radical; cyclohexyl; phenyl optionally carrying at least one halogen, nitro, trifluoromethyl, C 1 -C 6 alkyl or C 1 -C 6 alkoxy radical; halogen; alkoxycarbonyl with a total of up to 7 carbon atoms; or amidocarbonyl; R" is alkyl or alkenyl of up to 20 carbon atoms substituted by an alkoxycarbonyl with a total of up to 5 carbon atoms; or alkoxycarbonyl with a total of up to 7 carbon atoms; and n is 0, 1, 2 or 3.
Claim 3
Dependent Claim 68 words
A compound according to claim 1, in which R is alkyl of up to 4 carbon atoms, or phenyl optionally substituted by fluorine, chlorine, nitro, methyl, trifluoromethyl or methoxy; n is 1, 2 or 3; and R" is alkyl of up to 20 carbon atoms substituted by alkoxycarbonyl with a total of up to 5 carbon atoms; or alkoxycarbonyl with a total of up to 7 carbon atoms.
Claim 4
Dependent Claim 34 words
A compound according to claim 1, in which R is methyl, phenyl or chlorophenyl, n is 2 or 3, and R' and R" each individually is alkyl substituted by lower alkoxycarbonyl, or lower alkoxycarbonyl.
Claim 5
Dependent Claim 18 words
A compound according to claim 1, wherein such compound is N-(fluorodichloromethylthio)-N-phenylcarbamic acid ethylacetoacetate-oxime ester of the formula ##EQU9##
Claim 6
Dependent Claim 19 words
A compound according to claim 1, wherein such compound is N-(fluorodichloromethylthio)-N-methyl carbamic acid ethylacetoacetate-oxime ester of the formula ##EQU10##
Claim 7
Dependent Claim 18 words
A compound according to claim 1, wherein such compound is N-(fluorodichloromethylthio)-N-methylcarbamic acid diethyl-γ-ketopimelate-oxime ester of the formula ##EQU11##
Claim 8
Dependent Claim 18 words
A compound according to claim 1, wherein such compound is N-(fluorodichloromethylthio)-N-methylcarbamic acid diethyl-γ-ketomalonate-oxime ester of the formula ##EQU12##
Claim 9
Dependent Claim 18 words
A compound according to claim 1, wherein such compound is N-(fluorodichloromethylthio)-N-phenylcarbamic acid diethyl-γ-ketomalonate-oxime ester of the formula ##EQU13##
Claim 10
Dependent Claim 18 words
A compound according to claim 1, wherein such compound is N-(fluorodichloromethylthio)-N-phenylcarbamic acid diethyl-γ-ketopimelate-oxime ester of the formula ##EQU14##

References Cited (Backward Citations)

US3576834A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-09-14 1980-03-15 1980-09-14 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-09-14 1984-03-15 1984-09-14 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-09-14 1988-03-15 1988-09-14 $7700.00 Window Closed / Lapsed

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