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US3977878A Expired / Lapsed US ⏱️ 0.0 years remaining

Epoxy resin photoresist with iodoform and bismuth triphenyl

Assignee: Primerica Inc
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Filing: 1975-02-26
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Granted: 1976-08-31
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Expires: 1995-02-26
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Abstract

Abstract Photopolymerizable compositions and processes for photopolymerizing such compositions are provided, said process comprising admixing with said epoxides, photosensitive organohalogen compounds in combination with an organometallic compound and thereafter applying energy to the resulting mixture. The organohalogens decompose to liberate an active catalyst which then serves to initiate polymerization of the epoxide material. The organometallic compound functions synergistically with the organohalogen to enhance the film forming properties of the resulting polymer and or sensitivity of the polymerizable system.

Inventors

  • 👤 Jerome Roteman

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 02:03
CPC Classifications
G; G03; G03F; G03F7/00; G03F7/004; G03F7/027; G03F7/028; G03F7/029; G03F7/0295; G03F7/038; Y; Y10; Y10S; Y10S430/00; Y10S430/1053; Y10S430/1055; Y10S430/114; Y10S430/115; Y10S430/126

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 162 words
As an article of manufacture, a composite sheet, comprising: A support; and in surface contact therewith, an organic-solvent-soluble layer responsive to electromagnetic or electron-beam radiation containing, in admixture, (a) a monomeric or prepolymeric epoxide or mixture thereof, said epoxide being polymerizable to higher molecular weights through the action of a cationic catalyst; and, (b) as a latent curing agent for polymerizing and insolubilizing said epoxide, a radiation-sensitive catalyst precursor which decomposes upon exposure to electromagnetic or electron-beam radiation to provide an active catalyst effective to initiate polymerization of said epoxide, said precursor being an organohalogen compound wherein the organo radicals are alkyl, aryl, alkaryl, aralkyl, alkoxy and aroxy in combination with an oranometallic compound having the formula R 3 M wherein M is P, As, Sb or Bi and R is a hydrocarbyl radical or hydrogen with the proviso that at least one R is a hydrocarbyl radical; said latent curing agent having had substantially no exposure to electromagnetic or electron-beam radiation.
Claim 2
Dependent Claim 162 words
As an article of manufacture, a composite sheet, comprising: A support; and in surface contact therewith, an organic-solvent-soluble layer responsive to electromagnetic or electron-beam radiation containing, in admixture, (a) a monomeric or prepolymeric epoxide or mixture thereof, said epoxide being polymerizable to higher molecular weights through the action of a cationic catalyst; and, (b) as a latent curing agent for polymerizing and insolubilizing said epoxide, a radiation-sensitive catalyst precursor which decomposes upon exposure to electromagnetic or electron-beam radiation to provide an active catalyst effective to initiate polymerization of said epoxide, said precursor being an organohalogen compound wherein the organo radicals are alkyl, aryl, alkaryl, aralkyl, alkoxy and aroxy in combination with an oranometallic compound having the formula R 3 M wherein M is P, As, Sb or Bi and R is a hydrocarbyl radical or hydrogen with the proviso that at least one R is a hydrocarbyl radical; said latent curing agent having had substantially no exposure to electromagnetic or electron-beam radiation.
Claim 3
Dependent Claim 13 words
An article as defined in claim 1 in which said support is metal.
Claim 4
Dependent Claim 15 words
An article as defined in claim 1 in which said organometallic compound is triphenyl bismuthine.
Claim 5
Dependent Claim 13 words
An article as defined in claim 3 in which said organohalogen is iodoform.
Claim 6
Dependent Claim 23 words
An article as defined in claim 4 in which said epoxide is a glycidyl ether novolak resin or glycidyl ether of bisphenol A.
Claim 7
Dependent Claim 11 words
An article as defined in claim 1 wherein R is phenyl.
Claim 8
Dependent Claim 18 words
An article as defined in claim 1 wherein said organometallic compound is triphenylbismuthine and said organohalogen is iodoform.
Claim 9
Dependent Claim 28 words
An article as defined in claim 7 wherein said catalyst precursor is present in an amount by weight equal to between about 5 and 50% of the epoxide.

References Cited (Backward Citations)

US3427259A Cited
US3522194A Cited
US3708296A Cited
US3720634A Cited
US3711391A Cited
US3721617A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-08-31 1980-03-01 1980-08-31 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-08-31 1984-03-01 1984-08-31 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-08-31 1988-03-01 1988-08-31 $7700.00 Window Closed / Lapsed

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