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US3975357A
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Stabilized synthetic polymer compositions
Assignee: Sankyo Co Ltd
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Filing: 1974-04-05
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Granted: 1976-08-17
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Expires: 1994-04-05
Abstract
Abstract A synthetic polymer composition stabilized against photo- and thermal-deterioration thereof wherein there is incorporated, in a sufficient amount to prevent such deterioration, 1-substituted piperidine derivatives.
Inventors
- 👤 Keisuke Murayama
- 👤 Syoji Morimura
- 👤 Takao Yoshioka
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-03 03:24
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/16; C08K5/34; C08K5/3467; C08K5/3472; C08K5/3475; C08K5/04; C08K5/13; C08K5/132; C08K5/20; C08K5/3412; C08K5/3432; C08K5/3435
Claims Analysis
Total Claims: 10
Claim 1
Independent Claim
431 words
A synthetic polymer composition stabilized against photo- and thermal-deterioration wherein there is incorporated, in a sufficient amount to prevent said deterioration, a compound having the formula ##SPC15## wherein n represents 1 or 2, R a , R b , R c and R d represent a methyl group, and R 1 represents, when n = 1, an alkyl group having 4 to 12 carbon atoms; an alkenyl group having 3 to 10 carbon atoms; an alkynyl group having 3 or 4 carbon atoms; a benzyl group optionally substituted with 1 to 3 substituents, which may be the same or different, selected from chlorine, an alkyl having 1 to 4 carbon atoms, an alkoxy having 1 to 8 carbon atoms and hydroxy in its phenyl moiety; phenethyl group; 2,3-epoxypropyl group; or a group of the formula --CH.sub.2 --CO.O--R.sub.2, wherein R 2 represents an alkyl group having 1 to 18 carbon atoms, an alkenyl group having 3 to 6 carbon atoms, phenyl group, benzyl group, cyclohexyl group or 2,3 epoxypropyl group; or a group of the formula ##EQU1## wherein R 3 represents hydrogen atom, methyl group or phenyl group; R 4 represents a hydroxy group or a group of the formula --O.COR 5 ; R 5 represents an alkyl group having 1 to 17 carbon atoms, an alkenyl group having 2 to 4 carbon atoms, a phenyl group optionally substituted with 1 to 3 substituents, which may be the same or different, selected from chlorine, an alkyl having 1 to 4 carbon atoms, an alkoxy having 1 to 8 carbon atoms and hydroxy, benzyl group, 3,5-di-tertiary butyl-4-hydroxyphenethyl group, styryl group or cyclohexyl group; or R 1 may be a group of the formula --CO--R.sub.6, wherein R 6 represents a hydrogen atom, methyl group, an alkenyl group having 2 or 3 carbon atoms, an alkoxy group having 1 to 8 carbon atoms, benzyloxy group or phenoxy group; and when n = 2, R 1 represents an alkylene group having 1 to 6 carbon atoms in which the alkylene chain may optionally be interrupted by an oxygen atom; 2-butenylene group; or a group of the formula --CH.sub.2 CO.O--R.sub.7 --O-COCH.sub.2 --, wherein R 7 represents an alkylene group having 2 to 6 carbon atoms or xylylene group; or a group of the formula --CH.sub.2.CH.sub.2 --O.CO -- R.sub.8 ).sub.m CO.O--CH.sub.2.CH.sub.2 -- wherein m represents 0 or 1; R 8 represents an alkylene group having 1 to 10 carbon atoms in which the alkylene chain may optionally be interrupted by a sulfur atom; an alkenylene group having 2 to 4 carbon atoms, a phenylene group or 1,4-cyclohexylene group.
Claim 2
Dependent Claim
431 words
A synthetic polymer composition stabilized against photo- and thermal-deterioration wherein there is incorporated, in a sufficient amount to prevent said deterioration, a compound having the formula ##SPC15## wherein n represents 1 or 2, R a , R b , R c and R d represent a methyl group, and R 1 represents, when n = 1, an alkyl group having 4 to 12 carbon atoms; an alkenyl group having 3 to 10 carbon atoms; an alkynyl group having 3 or 4 carbon atoms; a benzyl group optionally substituted with 1 to 3 substituents, which may be the same or different, selected from chlorine, an alkyl having 1 to 4 carbon atoms, an alkoxy having 1 to 8 carbon atoms and hydroxy in its phenyl moiety; phenethyl group; 2,3-epoxypropyl group; or a group of the formula --CH.sub.2 --CO.O--R.sub.2, wherein R 2 represents an alkyl group having 1 to 18 carbon atoms, an alkenyl group having 3 to 6 carbon atoms, phenyl group, benzyl group, cyclohexyl group or 2,3 epoxypropyl group; or a group of the formula ##EQU1## wherein R 3 represents hydrogen atom, methyl group or phenyl group; R 4 represents a hydroxy group or a group of the formula --O.COR 5 ; R 5 represents an alkyl group having 1 to 17 carbon atoms, an alkenyl group having 2 to 4 carbon atoms, a phenyl group optionally substituted with 1 to 3 substituents, which may be the same or different, selected from chlorine, an alkyl having 1 to 4 carbon atoms, an alkoxy having 1 to 8 carbon atoms and hydroxy, benzyl group, 3,5-di-tertiary butyl-4-hydroxyphenethyl group, styryl group or cyclohexyl group; or R 1 may be a group of the formula --CO--R.sub.6, wherein R 6 represents a hydrogen atom, methyl group, an alkenyl group having 2 or 3 carbon atoms, an alkoxy group having 1 to 8 carbon atoms, benzyloxy group or phenoxy group; and when n = 2, R 1 represents an alkylene group having 1 to 6 carbon atoms in which the alkylene chain may optionally be interrupted by an oxygen atom; 2-butenylene group; or a group of the formula --CH.sub.2 CO.O--R.sub.7 --O-COCH.sub.2 --, wherein R 7 represents an alkylene group having 2 to 6 carbon atoms or xylylene group; or a group of the formula --CH.sub.2.CH.sub.2 --O.CO -- R.sub.8 ).sub.m CO.O--CH.sub.2.CH.sub.2 -- wherein m represents 0 or 1; R 8 represents an alkylene group having 1 to 10 carbon atoms in which the alkylene chain may optionally be interrupted by a sulfur atom; an alkenylene group having 2 to 4 carbon atoms, a phenylene group or 1,4-cyclohexylene group.
Claim 3
Dependent Claim
106 words
A synthetic polymer composition stabilized against photo- and thermal-deterioration wherein there is incorporated, in a sufficient amount to prevent said deterioration, a compound having the formula ##SPC16## wherein n represents 2, R 1 represents alkylene group having 2 to 6 carbon atoms, a group of the formula --CH.sub.2.CO.O--R.sub.7 --O.CO.CH.sub.2 -- wherein R 7 represents an alkylene group having 2 to 6 carbon atoms or a group of the formula --CH.sub.2.CH.sub.2.O.CO.--R.sub.8 --CO.O.CH.sub.2.CH.sub.2 -- wherein R 8 represents an alkylene group having 1 to 8 carbon atoms, m-phenylene group or p-phenylene group, and R a , R b , R c and R d represent a methyl group.
Claim 4
Dependent Claim
106 words
A synthetic polymer composition stabilized against photo- and thermal-deterioration wherein there is incorporated, in a sufficient amount to prevent said deterioration, a compound having the formula ##SPC16## wherein n represents 2, R 1 represents alkylene group having 2 to 6 carbon atoms, a group of the formula --CH.sub.2.CO.O--R.sub.7 --O.CO.CH.sub.2 -- wherein R 7 represents an alkylene group having 2 to 6 carbon atoms or a group of the formula --CH.sub.2.CH.sub.2.O.CO.--R.sub.8 --CO.O.CH.sub.2.CH.sub.2 -- wherein R 8 represents an alkylene group having 1 to 8 carbon atoms, m-phenylene group or p-phenylene group, and R a , R b , R c and R d represent a methyl group.
Claim 5
Dependent Claim
31 words
The synthetic polymer composition according to claim 1, wherein said compound (I) is incorporated in an amount of 0.01 - 5.0% by weight, based upon the amount of the synthetic polymer.
Claim 6
Dependent Claim
158 words
The synthetic polymer composition according to claim 1, wherein, n represents 1, R 1 represents an alkyl group having 4 to 12 carbon atoms; allyl group; benzyl group which may be substituted with an alkyl having 1 to 4 carbon atoms, methoxy or 3,5-di-tertiarybutyl-4-hydroxy in the phenyl moiety; a group of the formula --CH 2 CO.OR 2 wherein R 2 represents an alkyl group having 1 to 18 carbon atoms or an allyl group; or R 1 may be a group of the formula ##STR3## wherein R 3 represents hydrogen atom, methyl group or phenyl group and R 4 represents hydroxy group or a group of the formula --O.COR 5 wherein R 5 represents an alkyl group having 1 to 17 carbon atoms, alkenyl group having 2 or 3 carbon atoms, 3,5-di-tertiarybutyl-4-hydroxyphenethyl group or phenyl group which may be substituted with an alkyl having 1 to 4 carbon atoms, alkoxy having 1 to 8 carbon atoms or hydroxy.
Claim 7
Dependent Claim
87 words
The synthetic polymer composition according to claim 1, wherein n represents 1, R 1 represents a group of the formula ##STR4## wherein R 3 represents hydrogen atom and R 4 represents hydroxy group or a group of the formula --O.COR 5 wherein R 5 represents an alkyl group having 1 to 17 carbon atoms, alkenyl group having 2 or 3 carbon atoms, or phenyl group which may be substituted with an alkyl having 1 to 4 carbon atoms, alkoxy having 1 to 8 carbon atoms or hydroxy.
Claim 8
Dependent Claim
48 words
The synthetic polymer composition according to claim 1, wherein said polymer is selected from the group consisting of a polyvinyl chloride, a polyvinylidene chloride, a polyacetal, a polyester, a polyamide having recurring amide groups as integral parts of the main polymer chain, a polyurethane and an epoxy resin.
Claim 9
Dependent Claim
34 words
The synthetic polymer composition according to claim 1, wherein said compound (I) is selected from the group consisting of 1-(2-stearoyloxyethyl)-2,2,6,6-tetramethylpiperidine, 1,6-bis (2,2,6,6-tetramethylpiperidino) hexane, bis [2-(2,2,6,6-tetramethylpiperidino)ethyl] succinate, bis [2-(2,2,6,6-tetramethylpiperidino)ethyl] -1,10-decane dicarboxylate and bis [2-(2,2,6,6-tetramethylpiperidino)ethyl] terephthalate.
Claim 10
Dependent Claim
14 words
The synthetic polymer composition according to claim 1, wherein said polymer is a polyolefin.
References Cited (Backward Citations)
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1979-08-17 | 1980-02-16 | 1980-08-17 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1983-08-17 | 1984-02-16 | 1984-08-17 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1987-08-17 | 1988-02-16 | 1988-08-17 | $7700.00 | Window Closed / Lapsed |