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Smoke retardant vinyl chloride and vinylidene chloride polymer compositions

Assignee: Geon Co
•
Filing: 1975-06-02
•
Granted: 1976-08-17
•
Expires: 1995-06-02
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Abstract

Abstract Smoke retardant vinyl chloride and vinylidene chloride polymer compositions are obtained by including therein a synergistic mixture of (A) at least one nickel compound selected from the group consisting of NiI 2 , NiMoO 4 , NiO and nickel dimethylglyoxime and (B) at least one aluminum compound selected from the group consisting of Al 2 (MoO 4 ) 3 , α-Al 2 O 3 , Al 2 (WO 4 ) 3 , ammonium-6-molybdoaluminate (III), and aluminum salicylate. Substantial smoke retardation is also obtained by including the above nickel compounds or aluminum compounds individually or aluminum ammonium sulfate, aluminum potassium sulfate, or aluminum acetylacetonate in the vinyl chloride or vinylidene chloride polymer compositions.

Inventors

  • 👤 Elmer Douglas Dickens, Jr.

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 11:01
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/16; C08K5/32; C08K3/00; C08K3/10; C08K3/18; C08K3/20; C08K3/22; C08K3/24; C08K5/0091; C08K5/04; C08K5/09

Claims Analysis

Total Claims: 29
Claim 1
Independent Claim 89 words
A smoke retardant composition comprising a vinyl chloride or vinylidene chloride polymer together with (A) at least one nickel compound selected from the group consisting of NiI 2 , NiMoO 4 , NiO and nickel dimethylglyoxime, and (B) at least one aluminum compound selected from the group consisting of α-Al 2 O 3 , Al 2 (WO 4 ) 3 , and aluminum salicylate, said compounds (A) and (B) being present in a total amount from about 0.25 to about 100 weight parts per 100 weight parts of polymer.
Claim 2
Dependent Claim 89 words
A smoke retardant composition comprising a vinyl chloride or vinylidene chloride polymer together with (A) at least one nickel compound selected from the group consisting of NiI 2 , NiMoO 4 , NiO and nickel dimethylglyoxime, and (B) at least one aluminum compound selected from the group consisting of α-Al 2 O 3 , Al 2 (WO 4 ) 3 , and aluminum salicylate, said compounds (A) and (B) being present in a total amount from about 0.25 to about 100 weight parts per 100 weight parts of polymer.
Claim 3
Dependent Claim 25 words
A composition of claim 1 wherein said polymer contains copolymerized therewith up to about 50% by weight of at least one other olefinically unsaturated monomer.
Claim 4
Dependent Claim 21 words
A composition of claim 2 wherein said polymer contains copolymerized therewith up to about 20% by weight of said other monomer.
Claim 5
Dependent Claim 47 words
A composition of claim 3 wherein said other monomer is selected from the group consisting of 1-olefins containing from 2 to 12 carbon atoms, vinyl esters, α,β-olefinically unsaturated carboxylic acids and esters thereof, amides of α,β -olefinically unsaturated carboxylic acids, and esters of fumaric and maleic acid.
Claim 6
Dependent Claim 18 words
A composition of claim 4 wherein said compound has an average particle size less than about 200 microns.
Claim 7
Dependent Claim 22 words
A composition of claim 5 wherein said compound (A) is NiI 2 and said compound (B) is α-Al 2 O 3 .
Claim 8
Dependent Claim 24 words
A composition of claim 5 wherein said compound (A) is NiMoO 4 and said compound (B) is Al 2 (WO 4 ) 3 .
Claim 9
Dependent Claim 23 words
A composition of claim 26 wherein said compound (A) is NiO and said compound (B) is Al 2 (MoO 4 ) 3 .
Claim 10
Dependent Claim 21 words
A composition of claim 5 wherein said compound (A) is NiO and said compound (B) is α-Al 2 O 3 .
Claim 11
Dependent Claim 18 words
A composition of claim 26 wherein said compound (A) is NiO and said compound (B) is ammonium-6-molybdoaluminate (III).
Claim 12
Dependent Claim 19 words
A composition of claim 5 wherein said compound (A) is nickel dimethylglyoxime and said compound (B) is aluminum salicylate.
Claim 13
Dependent Claim 63 words
A smoke retardant composition comprising a vinyl chloride or vinylidene chloride polymer together with at least one compound selected from the group consisting of nickel dimethylglyoxime, Al 2 (WO 4 ) 3 , aluminum ammonium sulfate, aluminum potassium sulfate, and aluminum acetylacetonate, said compound being present in an amount from about 0.25 to about 100 weight parts per 100 weight parts of polymer.
Claim 14
Dependent Claim 63 words
A smoke retardant composition comprising a vinyl chloride or vinylidene chloride polymer together with at least one compound selected from the group consisting of nickel dimethylglyoxime, Al 2 (WO 4 ) 3 , aluminum ammonium sulfate, aluminum potassium sulfate, and aluminum acetylacetonate, said compound being present in an amount from about 0.25 to about 100 weight parts per 100 weight parts of polymer.
Claim 15
Dependent Claim 25 words
A composition of claim 12 wherein said polymer contains copolymerized therewith up to about 50% by weight of at least one other olefinically unsaturated monomer.
Claim 16
Dependent Claim 21 words
A composition of claim 13 wherein said polymer contains copolymerized therewith up to about 20% by weight of said other monomer.
Claim 17
Dependent Claim 46 words
A composition of claim 14 wherein said other monomer is selected from the group consisting of 1-olefins containing from 2 to 12 carbon atoms, vinyl esters, α,β-olefinically unsaturated carboxylic acids and esters thereof, amides of α,β-olefinically unsaturated carboxylic acids, and esters of fumaric and maleic acid.
Claim 18
Dependent Claim 18 words
A composition of claim 15 wherein said compound has an average particle size less than about 200 microns.
Claim 19
Dependent Claim 11 words
A composition of claim 16 wherein said compound is nickel dimethylglyoxime.
Claim 20
Dependent Claim 16 words
A composition of claim 16 wherein said compound is Al 2 (WO 4 ) 3 .
Claim 21
Dependent Claim 12 words
A composition of claim 16 wherein said compound is aluminum ammonium sulfate.
Claim 22
Dependent Claim 12 words
A composition of claim 16 wherein said compound is aluminum potassium sulfate.
Claim 23
Dependent Claim 11 words
A composition of claim 16 wherein said compound is aluminum acetylacetonate.
Claim 24
Dependent Claim 80 words
A smoke retardant composition comprising a vinyl chloride or vinylidene chloride polymer together with (A) at least one nickel compound selected from the group consisting of NiI 2 , NiO and nickel dimethylglyoxime, and (B) at least one aluminum compound selected from the group consisting of Al 2 (MoO 4 ) 3 and ammonium-6-molybdoaluminate (III), said compounds (A) and (B) being present in a total amount from about 0.25 to about 100 weight parts per 100 weight parts of polymer.
Claim 25
Dependent Claim 80 words
A smoke retardant composition comprising a vinyl chloride or vinylidene chloride polymer together with (A) at least one nickel compound selected from the group consisting of NiI 2 , NiO and nickel dimethylglyoxime, and (B) at least one aluminum compound selected from the group consisting of Al 2 (MoO 4 ) 3 and ammonium-6-molybdoaluminate (III), said compounds (A) and (B) being present in a total amount from about 0.25 to about 100 weight parts per 100 weight parts of polymer.
Claim 26
Dependent Claim 25 words
A composition of claim 22 wherein said polymer contains copolymerized therewith up to about 50% by weight of at least one other olefinically unsaturated monomer.
Claim 27
Dependent Claim 21 words
A composition of claim 23 wherein said polymer contains copolymerized therewith up to about 20% by weight of said other monomer.
Claim 28
Dependent Claim 46 words
A composition of claim 24 wherein said other monomer is selected from the group consisting of 1-olefins containing from 2 to 12 carbon atoms, vinyl esters, α,β-olefinically unsaturated carboxylic acids and esters thereof, amides of α,β-olefinically unsaturated carboxylic acids, and esters of fumaric and maleic acid.
Claim 29
Dependent Claim 18 words
A composition of claim 25 wherein said compound has an average particle size less than about 200 microns.

References Cited (Backward Citations)

US3261790A Cited
US3326832A Cited
US3386934A Cited
US3438934A Cited
US3870679A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-08-17 1980-02-16 1980-08-17 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-08-17 1984-02-16 1984-08-17 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-08-17 1988-02-16 1988-08-17 $7700.00 Window Closed / Lapsed

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