Patent US2849949A successfully refreshed from Google Patents.
Patent US3975326A successfully refreshed from Google Patents.
US3975326A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Process for the addition of additives to thermoplastics
Assignee: Stamicarbon BV
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Filing: 1975-03-04
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Granted: 1976-08-17
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Expires: 1995-03-04
Abstract
Abstract In processes for processing thermoplastic resins which processes require mixing the thermoplastic resin with an additive consisting of a salt of an aliphatic carboxylic acid, the improvement of mixing the salt of the aliphatic carboxylic acid with (1) an amide of an aliphatic carboxylic acid of at least ten carbon atoms and (2) a mineral oil that is substantially non-volatile under the processing conditions, to facilitate addition of a measured amount of the additive and to prevent discoloration.
Inventors
- 👤 Christiaan G. de Vrieze
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-04 10:12
CPC Classifications
C; C08; C08J; C08J3/00; C08J3/20; C08J3/22; C08J3/226; C08J2491/00
Claims Analysis
Total Claims: 12
Claim 1
Independent Claim
244 words
In a process for adding to a molten thermoplastic resin or to a solution of a thermoplastic resin solid additives including heat stabilizers, antioxidants, UV-stabilizers, lubricants, antistatic agents, antiblocking agents and corrosion-inhibitors and containing only minor amounts, if any, of finely divided non-melting compounds which additives comprise at least one metal salt of an aliphatic carboxylic acid of at least 10 carbon atoms, said metal being a metal of Group I, II or III of the Periodic Table, said metal salt having a melting point of up to 250°C, the improvement comprising mixing said metal salt of an aliphatic carboxylic acid of at least 10 carbon atoms containing additive composition with at least 10% by weight, based on the weight of said salt, and up to 200% based on said salt, of an amide of a carboxylic acid having at least 10 carbon atoms and a mineral oil which is substantially non-volatile under the process conditions, to form a mixture and heating the mixture to a molten state, at a temperature less than the melting point of said additive and subsequently adding said melt to a themoplastic which is molten or in solution wherein the amount of each additive is up to 1% by weight based on the weight of the thermoplastic resin, wherein the amount of said mineral oil is at least 10% by weight of the total amount of said additives and is up to three times the weight of said additives.
Claim 2
Dependent Claim
244 words
In a process for adding to a molten thermoplastic resin or to a solution of a thermoplastic resin solid additives including heat stabilizers, antioxidants, UV-stabilizers, lubricants, antistatic agents, antiblocking agents and corrosion-inhibitors and containing only minor amounts, if any, of finely divided non-melting compounds which additives comprise at least one metal salt of an aliphatic carboxylic acid of at least 10 carbon atoms, said metal being a metal of Group I, II or III of the Periodic Table, said metal salt having a melting point of up to 250°C, the improvement comprising mixing said metal salt of an aliphatic carboxylic acid of at least 10 carbon atoms containing additive composition with at least 10% by weight, based on the weight of said salt, and up to 200% based on said salt, of an amide of a carboxylic acid having at least 10 carbon atoms and a mineral oil which is substantially non-volatile under the process conditions, to form a mixture and heating the mixture to a molten state, at a temperature less than the melting point of said additive and subsequently adding said melt to a themoplastic which is molten or in solution wherein the amount of each additive is up to 1% by weight based on the weight of the thermoplastic resin, wherein the amount of said mineral oil is at least 10% by weight of the total amount of said additives and is up to three times the weight of said additives.
Claim 3
Dependent Claim
22 words
The process of claim 1, wherein said mineral oil is a colorless white oil which has a boiling range that exceed 250°C.
Claim 4
Dependent Claim
21 words
The process of claim 1, wherein the amount of mineral oil is at most equal to the weight of said additives.
Claim 5
Dependent Claim
24 words
The process of claim 1, wherein the amount by weight of mineral oil is at most 0.3% by weight, based on the thermoplastics material.
Claim 6
Dependent Claim
23 words
The process of claim 1, wherein said mineral oil has a viscosity of 45 to 105 seconds Redwood No. 1 at 140°F (60°C).
Claim 7
Dependent Claim
42 words
The process of claim 1, wherein the amount by weight of carboxylic acid amide with at least 10 carbon atoms is at least 10% by weight of the amount of salt of an aliphatic carboxylic acid with at least 10 carbon atoms.
Claim 8
Dependent Claim
24 words
The process of claim 6, wherein the amount of amide is 40 to 200% by weight based on the salt of the carboxylic acid.
Claim 9
Dependent Claim
24 words
The process of claim 7, wherein the amount of amide is 80 to 120% by weight based on the salt of the carboxylic acid.
Claim 10
Dependent Claim
20 words
The process of claim 1, wherein the thermoplastics material used is a polyolefin prepared in solution by low-pressure polymerization process.
Claim 11
Dependent Claim
10 words
The process of claim 9, wherein the polyolefin is polyethylene.
Claim 12
Dependent Claim
31 words
The process of claim 1, wherein said amide is present in an amount ranging from 50 to 200% by weight based on the weight of the salt of the carboxylic acid.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1979-08-17 | 1980-02-16 | 1980-08-17 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1983-08-17 | 1984-02-16 | 1984-08-17 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1987-08-17 | 1988-02-16 | 1988-08-17 | $7700.00 | Window Closed / Lapsed |