Patent US3974160A successfully refreshed from Google Patents.
← Back to Patent Explorer
US3974160A Expired / Lapsed US ⏱️ 0.0 years remaining

Water-insoluble reactive dyestuffs which are soluble in aprotic solvents

Assignee: Novartis AG
•
Filing: 1973-11-02
•
Granted: 1976-08-10
•
Expires: 1993-11-02
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract Valuable reactive dyestuffs containing no acid, salt-forming, water-solubilizing groups and which, among others, can be applied from organic solvents, especially aprotic solvents correspond to the formula ##EQU1## wherein D represents the radical of an organic dyestuff, Q represents the bridging member --NX 3 --, --O--, --S-- or --NX 3 CO--, whereby X 3 denotes hydrogen or a lower alkyl group, R represents the radical of a nitrogen heterocycle containing at least one substituent which can be split off as anion and which is bound to a ring carbon atom adjacent to a tertiary nitrogen atom, X 1 represents hydrogen, an alkyl or an alkoxyalkyl group and X 2 represents an alkyl or an alkoxyalkyl group having in all at least 4 carbon atoms, whereby X 1 and X 2 must together contain, when X 1 denotes an alkyl or an alkoxyalkyl group, at least 8 carbon atoms, Or X 1 represents a cyclohexyl radical, unsubstituted or substituted by lower alkyl groups having preferably 1 to 4 carbon atoms, and X 2 represents an unsubstituted or substituted alkyl group having at most 18 carbon atoms, a lower alkenyl group having preferably 1 to 4 carbon atoms or a cyclohexyl radical, unsubstituted or substituted by lower alkyl groups having preferably 1 to 4 carbon atoms. Fiber materials dyed with these dyestuffs exhibit very good fastness properties, especially fastness to wet processing, rubbing and dry-cleaning.

Inventors

  • 👤 Herbert Seiler
  • 👤 Paul Dussy

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 17:26
CPC Classifications
C; C09; C09B; C09B62/00; C09B62/02; D; D06; D06P; D06P1/00; D06P1/38; D06P1/90; D06P1/908; D06P1/92; D06P1/922; D06P1/924; D06P1/928; D06P3/00; D06P3/02; D06P3/04; D06P3/10

Claims Analysis

Total Claims: 4
Claim 1
Independent Claim 240 words
A reactive dyestuff, containing no acid, salt-forming, water-solubilizing groups, of the formula ##EQU5## wherein D represents the radical of an anthraquinone dyestuff, which is unsubstituted or substituted only by halogen, cyano, nitro, lower alkyl, lower alkenyl, perfluoro(lower)alkyl, hydroxy(lowr) alkyl, cyanoethyl, β,β-dicyanovinyl, lower alkoxy, phenoxy, methylphenoxy, lower alkylthio, phenylthio, lower alkanoyl, lower alkylsulphonyl, phenylsulfonyloxy, dimethylamino, amino, N-(β-cyanoethyl)-ethylamino, diethylamino, methylethylamino, ethylbenzylamino, ethylbutylamino, N-(β-hydroxyethyl)ethylamino, β-hydroxyethylamino, di(β-hydroxyethyl)amino, N-(β-cyanoethyl)-β -hydroxyethylamino, di(β-cyanoethyl)amino, anilino, oxyanilino, methylamino, dimethylanilino, methylanilino, lower alkanoylamide, lower alkoxycarbonylamide, benzoylamide, lower alkylsulphonylamide, N-lower-alkyl- and N,N-diloweralkyl-lower alkylsulphonylamide or hydroxy, Q represents a bridging member --NX 3 --, --O--, --S-- or --NX 3 CO--, wherein X 3 represents hydrogen or lower alkyl, R represents triazinyl containing only chlorine, bromine or fluorine substituents, each of which can be split off as anion and which is bound to a ring carbon atom adjacent to a tertiary nitrogen atom, X 1 represents hydrogen and X 2 represents alkyl having from 8 to 18 carbon atoms, or X 1 & x 2 represent the same or different alkyl or alkoxyalkyl wherein X 1 and X 2 must together contain from 8 to 36 carbon atoms, or X 1 represents cyclohexyl or cyclohexyl substituted by lower alkyl, and X 2 represents alkyl of 1 to 18 carbon atoms, alkyl of 1 to 18 carbon atoms substituted by a member selected from the group consisting of hydroxyl, lower alkoxy, lower alkenyloxy and cyano, lower alkenyl, cyclohexyl or cyclohexyl substituted by lower alkyl.
Claim 2
Dependent Claim 240 words
A reactive dyestuff, containing no acid, salt-forming, water-solubilizing groups, of the formula ##EQU5## wherein D represents the radical of an anthraquinone dyestuff, which is unsubstituted or substituted only by halogen, cyano, nitro, lower alkyl, lower alkenyl, perfluoro(lower)alkyl, hydroxy(lowr) alkyl, cyanoethyl, β,β-dicyanovinyl, lower alkoxy, phenoxy, methylphenoxy, lower alkylthio, phenylthio, lower alkanoyl, lower alkylsulphonyl, phenylsulfonyloxy, dimethylamino, amino, N-(β-cyanoethyl)-ethylamino, diethylamino, methylethylamino, ethylbenzylamino, ethylbutylamino, N-(β-hydroxyethyl)ethylamino, β-hydroxyethylamino, di(β-hydroxyethyl)amino, N-(β-cyanoethyl)-β -hydroxyethylamino, di(β-cyanoethyl)amino, anilino, oxyanilino, methylamino, dimethylanilino, methylanilino, lower alkanoylamide, lower alkoxycarbonylamide, benzoylamide, lower alkylsulphonylamide, N-lower-alkyl- and N,N-diloweralkyl-lower alkylsulphonylamide or hydroxy, Q represents a bridging member --NX 3 --, --O--, --S-- or --NX 3 CO--, wherein X 3 represents hydrogen or lower alkyl, R represents triazinyl containing only chlorine, bromine or fluorine substituents, each of which can be split off as anion and which is bound to a ring carbon atom adjacent to a tertiary nitrogen atom, X 1 represents hydrogen and X 2 represents alkyl having from 8 to 18 carbon atoms, or X 1 & x 2 represent the same or different alkyl or alkoxyalkyl wherein X 1 and X 2 must together contain from 8 to 36 carbon atoms, or X 1 represents cyclohexyl or cyclohexyl substituted by lower alkyl, and X 2 represents alkyl of 1 to 18 carbon atoms, alkyl of 1 to 18 carbon atoms substituted by a member selected from the group consisting of hydroxyl, lower alkoxy, lower alkenyloxy and cyano, lower alkenyl, cyclohexyl or cyclohexyl substituted by lower alkyl.
Claim 3
Dependent Claim 75 words
A reactive dyestuff as claimed in claim 1, wherein Q represents the --NX 3 -- group, R represents triazinyl having one labile halogen atom, X 1 represents hydrogen and X 2 represents alkyl having from 8 to 18 carbon atoms, or X 1 and X 2 each represent alkyl which together contain from 8 to 36 carbon atoms, or X 1 represents cyclohexyl and X 2 represents alkyl having from 1 to 4 carbon atoms.
Claim 4
Dependent Claim 12 words
A reactive dyestuff as claimed in claim 2, wherein R represents chlorotriazinyl.

References Cited (Backward Citations)

US3022304A Cited
US3095415A Cited
US3186979A Cited
US3828040A Cited
US3758470A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-08-10 1980-02-09 1980-08-10 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-08-10 1984-02-09 1984-08-10 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-08-10 1988-02-09 1988-08-10 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag