US3972868A
Expired / Lapsed
US
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Method for selectively guiding and limiting the reactions of hydroxyl compounds
Assignee: Suomen Sokeri Oy
•
Filing: 1972-07-19
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Granted: 1976-08-03
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Expires: 1992-07-19
Abstract
Abstract The present invention relates to a method for producing, from a hydroxyl compound, a sequence of metal derivatives, which are subsequently made to react selectively for a certain purpose. The present invention relates to a method for selectively guiding reactions with polyhydroxyl compounds so as to occur at a predetermined hydroxyl group or groups, by carrying out said reactions over complexes of polyvalent metals and wherein the recovery of the parent compounds of the reaction products is achieved by adding water to the mixture after the reaction solvent is distilled off.
Inventors
- 👤 Eero Sakari Avela
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-02 10:23
CPC Classifications
C; C07; C07H; C07H15/00; C07H15/02; C07H15/04; C07C; C07C43/00; C07C43/02; C07C43/20; C07C43/23; C07F; C07F1/00; C07F1/005; C07F15/00; C07F15/06; C07F15/065; C07F3/00; C07F3/10; C07F3/103
Claims Analysis
Total Claims: 19
Claim 1
Independent Claim
136 words
A process for producing derivatives of hydroxyl compounds which have at least two hydroxyl groups or a hydroxyl group and at least one additional functional group, which is capable of forming polyvalent metal complexes, which comprises: a. forming a metal complex by reacting said hydroxyl or functional groups with a polyvalent metal compound, said reaction occurring in completely anhydrous conditions to form a metal complexed compound; b. subjecting the metal complexed compound to one or more further reactions selected from the group consisting of substitutions, addition, elimination, oxidation and reduction, which are selectively guided or limited by the presence of said metal complex, which acts either as a blocking group or as a guiding group, said further reactions also occurring in completely anhydrous conditions; and c. removing the metal complex to provide the desired reaction product.
Claim 2
Dependent Claim
136 words
A process for producing derivatives of hydroxyl compounds which have at least two hydroxyl groups or a hydroxyl group and at least one additional functional group, which is capable of forming polyvalent metal complexes, which comprises: a. forming a metal complex by reacting said hydroxyl or functional groups with a polyvalent metal compound, said reaction occurring in completely anhydrous conditions to form a metal complexed compound; b. subjecting the metal complexed compound to one or more further reactions selected from the group consisting of substitutions, addition, elimination, oxidation and reduction, which are selectively guided or limited by the presence of said metal complex, which acts either as a blocking group or as a guiding group, said further reactions also occurring in completely anhydrous conditions; and c. removing the metal complex to provide the desired reaction product.
Claim 3
Dependent Claim
15 words
A process according to claim 1, wherein said additional functional groups are essentially oxygen-containing groups.
Claim 4
Dependent Claim
18 words
A process according to claim 1 wherein said additional functional groups are groups which contain nitrogen or sulphur.
Claim 5
Dependent Claim
18 words
A process according to claim 1, wherein the reactions take place in a reaction-promoting organic anhydrous solvent solution.
Claim 6
Dependent Claim
55 words
A process according to claim 1, wherein the degree of ionization of the hydroxyl compound is controlled by a metal hydride, preferably sodium hydride, and the resultant alcoholate is reacted with a polyvalent metal compound in anhydrous condition to yield the corresponding metal derivative which is thereafter subjected to a further reaction in anhydrous conditions.
Claim 7
Dependent Claim
33 words
A process according to claim 1, wherein the parent hydroxyl compound and reaction products are recovered from the protecting metal derivative of said hydroxyl compound by the addition of water, acid or base.
Claim 8
Dependent Claim
29 words
A process according to claim 4, wherein the organic anhydrous solvent is recovered either before or after the addition of the water, acid or base to the reaction product.
Claim 9
Dependent Claim
38 words
A process according to claim 1 wherein the hydroxyl groups or other functional groups which have remained unreacted may be used for further reactions either before or after addition of water, acid or base, to the reaction mixture.
Claim 10
Dependent Claim
38 words
A process according to claim 1 wherein the reaction of the hydroxyl compound is guided to occur selectively or primarily at one or more functional groups subjecting the polyvalent metal derivate of the hydroxyl compound to the reaction.
Claim 11
Dependent Claim
16 words
A process according to claim 1, wherein said complex of a polyvalent metal is a chelate.
Claim 12
Independent Claim
49 words
A method of using polyvalent metal complexes of hydroxyl compounds or compounds which have a hydroxyl group and at least one additional functional group as starting materials for subsequent selective reactions, which occur in anhydrous conditions, to yield derivatives of the hydroxyl compounds upon removal of the metal complexes.
Claim 13
Independent Claim
49 words
A method of using polyvalent metal complexes of hydroxyl compounds or compounds which have a hydroxyl group and at least one additional functional group as starting materials for subsequent selective reactions, which occur in anhydrous conditions, to yield derivatives of the hydroxyl compounds upon removal of the metal complexes.
Claim 14
Dependent Claim
14 words
A method according to claim 11 wherein the polyvalent metal complex is a chelate.
Claim 15
Dependent Claim
16 words
A method according to claim 11 wherein the additional functional groups are essentially oxygen containing groups.
Claim 16
Dependent Claim
29 words
A method according to claim 11 wherein the subsequent reactions to which the polyvalent metal complex of the hydroxyl compound is subjected are substitution, addition, elimination, oxidation and reduction.
Claim 17
Dependent Claim
36 words
A method according to claim 11 wherein the hydroxyl compound and reaction products are recovered from the protecting metal complexes of the hydroxyl compounds by the addition of water, acid or base to the reaction product.
Claim 18
Dependent Claim
51 words
A process according to claim 1, wherein said hydroxyl compounds are selected from the group consisting of polyhydric ether alcohols, hydroxy aldehydes, hydroxy ketones, diketones in the enol-form, polyketones, polyaldehydes, polyhydric phenols, phenol carboxylic acids and their derivatives, halogenated alcohols, hydroxy and ketoacids and their esters and derivatives of carboxylic acids.
Claim 19
Dependent Claim
43 words
A process according to claim 1, wherein said hydroxyl compounds are selected from the group consisting of 4,6-O-benzylidene-α-D-glucopyranoside, triethylene glycol, 2 methyl-2,4-pentanediol, 1,3 butanediol and pyrocathecol, and the polyvalent metal compound is selected from the group consisting of anhydrous copper and cobalt chloride.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1979-08-03 | 1980-02-02 | 1980-08-03 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1983-08-03 | 1984-02-02 | 1984-08-03 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1987-08-03 | 1988-02-02 | 1988-08-03 | $7700.00 | Window Closed / Lapsed |