Novel organofunctional silicon compounds substituted with halogen and processes for making same

Claim 2

Process as claimed in claim 1 wherein the amounts of the olefinically unsaturated silicon compound and said active hydrogen atom containing compound are adequate to provide at least one atom of active hydrogen per olefinically unsaturated group of said silicon.

Claim 3

Process as claimed in claim 1 wherein said active hydrogen atom containing compound is acidic and the reaction is carried out in the presence of a basic catalyst.

Claim 4

Process as claimed in claim 1 wherein said active hydrogen atom containing compound is essentially neutral and the reaction is carried out in the presence of an acidic catalyst.

Claim 5

Organofunctional silicon compounds selected from the class consisting of silanes of the formula: Ra( (YR'')cSiR''''d) and siloxane polymers and copolymers containing the unit of the formula: wherein a is an integer of 1 to 3; b is an integer of 1 to 6; c is an integer of 1 to 4; d is an integer of 0 to 3; e is an integer of 1 to 3; f is an integer of 0 to 2; R is a radical free of aliphatic unsaturation having a valence of 1 to 6, said valence being equal in the case of said silanes to b times c divided by a and in the case of said siloxane polymers and copolymers to b times e divided by a, R being selected from the class consisting of, monovalent hydrocarbon groups having one to 18 carbon atoms per group, substituted monovalent hydrocarbon groups having one to 18 carbon atoms per group substituted with substituents from the class consisting of halogen, alkoxy, cyano, nitro and hydroxy groups; substituted monovalent hydrocarbon groups substituted with a substituent having the formula R3O(CnH2nO)x- wherein R3 is a monovalent hydrocarbon group having one to 18 carbon atoms, n is an integer of 2 to 4, and x is an integer of 1 to 100, and having one to 18 carbon atoms per group in addition to those in said substituent; acyl groups having one to 18 carbon atoms per group; substituted acyl groups substituted with a substituent from the class consisting of hydroxy, alkoxy groups having one to 18 carbon atoms per alkoxy groUp, and R3O(CnH2nO)x- groups and having one to 18 carbon atoms per group in addition to those of said substituent; divalent hydrocarbon groups having two to 18 carbon atoms; divalent groups of the formula CnH2nO)xCnH2n-; divalent groups of the formula wherein R4 is a divalent hydrocarbon groups having two to 18 carbon atoms per group; divalent groups of the formula wherein R5 is a divalent hydrocarbon having two to 18 carbon atoms per group; divalent groups of the formula divalent groups of the formula trivalent hydrocarbon groups having three to 18 carbon atoms per group; trivalent groups of the formula trivalent groups of the formula wherein R6 is a trivalent hydrocarbon group having three to 18 carbon atoms per group; tetravalent hydrocarbon groups having three to 18 carbon atoms per group; tetravalent groups of the formula pentavalent hydrocarbon groups having four to 18 carbon atoms per group; pentavalent groups of the formula:

Claim 6

Organofunctional silicon compound as claimed in claim 6 wherein said compound is 3-(2-(2,2,2-trifluoroethoxy)-1-chloroethyl)heptamethyltrisiloxane.

Claim 7

Organofunctional silicon compound as claimed in claim 6 wherein said compound is 2-(2,2,2-trifluoroethoxy)-1-chloroethyltrimethylsilane.

Claim 8

Organofunctional silicon compound as claimed in claim 6 wherein said compound is 3-((2,2,2-trifluoroethoxy)chlorocyclohexyl)heptamethyltrisiloxane.

Claim 9

Organofunctional silicon compound as claimed in claim 6 wherein said compound is 2-(2,2,2-trifluoroethoxy)-1-chloroethylmethylsiloxane cyclic trimers and tetramers.

Claim 10

Organofunctional silicon compound as claimed in claim 6 wherein said compound is 3-(2-(1H,1H-perfluorooctyloxy)-1-chloroethyl)heptamethyltrisiloxane.

Claim 11

Organofunctional silicon compound as claimed in claim 6 wherein said compound is 2-ethoxy-1-chloroethylmethyldiethoxysilane.

Claim 12

Organofunctional silicon compound as claimed in claim 6 wherein said compound is 3(2-ethoxy-1-chloroethyl)heptamethyltrisiloxane. 14. Organofunctional silicon compound as claimed in claim 6 wherein said compound is 2-ethoxy-1-bromoethyltriethoxysilane.

Claim 13

Organofunctional silicon compound as claimed in claim 6 wherein said compound is 2-(2-hydroxyethoxy)-1-chloroethyltrimethylsilane.

Claim 14

Organofunctional silicon compound as claimed in claim 6 wherein said compound is Me3SiO(C6H2Br3OCH2CHClSiMeO)10SiMe3.

Claim 15

Organofunctional silicon compound as claimed in claim 6 wherein said compound is 2-acetoxy-1-chloroethylmethyldiethoxysilane.

Claim 16

Organofunctional silicon compound as claimed in claim 6 wherein said compound is 2-(2,2,2-trifluoroethoxy)-1-chloroethyltriethylsilane.

Claim 17

Organofunctional silicon compound as claimed in claim 6 wherein said compound is 2-ethoxy-1-chloroethyltriethylsilane.

Claim 18

Organofunctional silicon compound as claimed in claim 6 wherein said compound is 3-(2-(methoxyethoxy)-1-chloroethyl)heptamethyltrisiloxane.

Claim 19

Organofunctional silicon compound as claimed in claim 6 wherein said compound is 3-(2-methoxy-1-chloroethyl)heptamethyltrisiloxane.

Claim 20

Organofunctional silicon compound as claimed in claim 6 wherein said compound is 3-(2-(2-propoxy)-1-chloroethyl)heptamethyltrisiloxane.

Claim 21

Organofunctional silicon compound as claimed in claim 6 wherein said compound is 3-(2-butoxy-1-chloroethyl)heptamethyltrisiloxane.

Claim 22

Organofunctional silicon compound as -(in claim 6 wherein said compound is 3(2-acetoxy-1-chloroethyl)heptamethyltrisiloxane.

Claim 23

Organofunctional silicon compound as claimed in claim 6 wherein said compound is 2-acetoxy-1-chloroethyltriethylsilane.

Claim 24

Organofunctional silicon compound as claimed in claim 6 wherein said compound is the gelled reaction product of a siloxane fluid comprised of vinylmethyl siloxy units and dimethyl siloxy units with ethylene glycol and t-butyl hypochlorite.