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Hydrocarbon deasphalting via solvent extraction

Assignee: Universal Oil Products Co
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Filing: 1975-06-25
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Granted: 1976-08-03
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Expires: 1995-06-25
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Abstract

Abstract Maximum removal of asphaltic material, including high molecular weight metallic contaminants, from a hydrocarbonaceous charge stock is achieved through the utilization of a solvent extraction zone provided with direct heating facilities in an upper portion thereof. A portion of the solvent-rich hydrocarbon phase is withdrawn from the extraction zone, increased in temperature and introduced into an asphalt settling zone. The separated solvent/hydrocarbon stream, substantially asphalt-free, is reintroduced into the extraction zone at the higher temperature.

Inventors

  • 👤 Kenneth D. Uitti
  • 👤 Bennie I. Bunas

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 07:02
CPC Classifications
C; C10; C10G; C10G21/00; C10G21/003; B; B01; B01D; B01D11/00; B01D11/04; B01D11/0403; B01D11/0407

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 187 words
A process for deasphalting an asphalt-containing hydrocarbonaceous charge stock, in a solvent extraction zone, which process comprises the steps of: a. countercurrently contacting said charge stock, introduced into said zone through an upper first locus thereof, with a hydrocarbon-selective solvent, introduced into said zone through a lower second locus thereof, at extraction conditions selected to produce a solvent-lean asphaltic stream and a solvent-rich hydrocarbon stream; b. withdrawing said asphaltic stream from said zone through a lower third locus below the second locus thereof, and a solvent-rich deasphalted oil from said zone through an upper fourth locus above the first locus thereof; c. withdrawing at least a portion of said solvent-rich hydrocarbon stream from said zone through a fifth locus above the first locus thereof; d. increasing the temperature of said portion and introducing the heated portion into a separation zone to provide a settled asphaltic phase and a solvent/hydrocarbon phase; e. introducing said asphaltic phase into said zone through a sixth locus above the second locus thereof; and, f. introducing said solvent/hydrocarbon phase into said zone through a seventh locus intermediate the first and fifth loci thereof.
Claim 2
Dependent Claim 187 words
A process for deasphalting an asphalt-containing hydrocarbonaceous charge stock, in a solvent extraction zone, which process comprises the steps of: a. countercurrently contacting said charge stock, introduced into said zone through an upper first locus thereof, with a hydrocarbon-selective solvent, introduced into said zone through a lower second locus thereof, at extraction conditions selected to produce a solvent-lean asphaltic stream and a solvent-rich hydrocarbon stream; b. withdrawing said asphaltic stream from said zone through a lower third locus below the second locus thereof, and a solvent-rich deasphalted oil from said zone through an upper fourth locus above the first locus thereof; c. withdrawing at least a portion of said solvent-rich hydrocarbon stream from said zone through a fifth locus above the first locus thereof; d. increasing the temperature of said portion and introducing the heated portion into a separation zone to provide a settled asphaltic phase and a solvent/hydrocarbon phase; e. introducing said asphaltic phase into said zone through a sixth locus above the second locus thereof; and, f. introducing said solvent/hydrocarbon phase into said zone through a seventh locus intermediate the first and fifth loci thereof.
Claim 3
Dependent Claim 22 words
The process of claim 1 further characterized in that said solvent/hydrocarbon phase is introduced through said seventh locus in a downwardly direction.
Claim 4
Dependent Claim 46 words
The process of claim 1 further characterized in that said extraction conditions include temperatures in the range of about 50°F. to about 600°F., pressures from about 100 to about 1,000 psig. and a solvent/charge stock volumetric ratio in the range of about 2.0:1.0 to about 30.0:1.0.
Claim 5
Dependent Claim 28 words
The process of claim 1 further characterized in that the temperature of the solvent-rich hydrocarbon stream withdrawn through said fifth locus is increased about 25°F. to about 125°F.
Claim 6
Dependent Claim 26 words
The process of claim 1 further characterized in that said solvent comprises a light hydrocarbon containing from about 3 to about 7 carbon atoms per molecule.
Claim 7
Dependent Claim 25 words
The process of claim 1 further characterized in that said solvent comprises a normally liquid naphtha fraction having an end boiling point below about 200°F.
Claim 8
Dependent Claim 19 words
The process of claim 5 further characterized in that said solvent comprises a mixture of normal butane and isopentane.
Claim 9
Dependent Claim 19 words
The process of claim 5 further characterized in that said solvent comprises a mixture of propane and normal butane.
Claim 10
Dependent Claim 13 words
The process of claim 5 further characterized in that said solvent is isopentane.
Claim 11
Dependent Claim 18 words
The process of claim 5 further characterized in that said solvent comprises a mixture of propane and isobutane.

References Cited (Backward Citations)

US2086487A Cited
US2669538A Cited
US2729589A Cited
US2950244A Cited
US3414506A Cited
US3364138A Cited
US3423308A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-08-03 1980-02-02 1980-08-03 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-08-03 1984-02-02 1984-08-03 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-08-03 1988-02-02 1988-08-03 $7700.00 Window Closed / Lapsed

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