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US3970586A
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Perfluoroalkane sulfonamido-alkane phosphonic and phosphonic acid derivatives
Assignee: Bayer AG
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Filing: 1975-05-07
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Granted: 1976-07-20
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Expires: 1995-05-07
Abstract
Abstract An ω-perfluoroalkane sulfonamido-alkane phosphonic or phosphinic acid or salt of the formula ##EQU1## in which R F is a perfluoroalkyl radical with from 1 to 12 carbon atoms; x and n each independently is 0 or 1, Y is hydrogen or a lower aliphatic radical with up to 5 carbon atoms, Z is an aliphatic radical with up to 5 carbon atoms, a cycloaliphatic, araliphatic or aromatic radical, and R is hydrogen, an alkali metal, alkaline earth metal or ammonium radical. The compounds are useful as surfactants in depressing the surface tension of water.
Inventors
- 👤 Reinhard Schliebs
- 👤 Manfred Wechsberg
- 👤 Johann Nikolaus Meussdoerffer
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-26 19:45
CPC Classifications
C; C07; C07F; C07F9/00; C07F9/02; C07F9/28; C07F9/38; C07F9/3804; C07F9/3808; C07F9/30; C07F9/32; C07F9/3205; C07F9/3211; C07F9/547; C07F9/553; C07F9/576; C07F9/58
Claims Analysis
Total Claims: 8
Claim 1
Independent Claim
84 words
An ω-perfluoroalkane sulfonamido-alkane phosphonic or phosphinic acid or salt of the formula ##EQU7## in which R F is a perfluoroalkyl radical with from 1 to 12 carbon atoms, x and n each independently is 0 or 1, Y is hydrogen or a lower aliphatic radical with up to 5 carbon atoms, Z is an aliphatic radical with up to 5 carbon atoms, a cycloaliphatic, araliphatic or aromatic radical, and R is hydrogen, an alkali metal, alkaline earth metal, ammonium radical or substituted ammonium radical.
Claim 2
Dependent Claim
84 words
An ω-perfluoroalkane sulfonamido-alkane phosphonic or phosphinic acid or salt of the formula ##EQU7## in which R F is a perfluoroalkyl radical with from 1 to 12 carbon atoms, x and n each independently is 0 or 1, Y is hydrogen or a lower aliphatic radical with up to 5 carbon atoms, Z is an aliphatic radical with up to 5 carbon atoms, a cycloaliphatic, araliphatic or aromatic radical, and R is hydrogen, an alkali metal, alkaline earth metal, ammonium radical or substituted ammonium radical.
Claim 3
Dependent Claim
54 words
An acid or salt according to claim 1, wherein R f is a perfluoroalkyl radical with from 4 to 8 carbon atoms, Y is hydrogen or methyl, Z is alkyl of up to 4 carbon atoms, cyclopentyl, cyclohexyl, benzyl, phenethyl, phenyl or tolyl, and R is hydrogen, sodium, potassium, ammonium, trimethylammonium, triethylammonium or pyridinium.
Claim 4
Dependent Claim
10 words
A salt according to claim 1 of the formula ##EQU8##
Claim 5
Dependent Claim
10 words
A salt according to claim 1 of the formula ##EQU9##
Claim 6
Dependent Claim
47 words
A process for the production of a compound according to claim 1, comprising reacting a perfluoroalkane sulfonyl fluoride of the formula R F --SO 2 --F with an ω-aminoalkane phosphonic acid or phosphinic acid or salt of the formula ##EQU10## in the presence of a tertiary amine.
Claim 7
Dependent Claim
18 words
A surface-active composition comprising a surface-active amount of a compound according to claim 1 and a liquid diluent.
Claim 8
Dependent Claim
24 words
The method of reducing the surface tension of a liquid which comprises adding thereto a surface-active amount of a compound according to claim 1.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1979-07-20 | 1980-01-19 | 1980-07-20 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1983-07-20 | 1984-01-19 | 1984-07-20 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1987-07-20 | 1988-01-19 | 1988-07-20 | $7700.00 | Window Closed / Lapsed |