Patent US3969089A successfully refreshed from Google Patents.
US3969089A
Expired / Lapsed
US
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Manufacture of combustible gases
Assignee: ExxonMobil Technology and Engineering Co
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Filing: 1975-06-09
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Granted: 1976-07-13
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Expires: 1995-06-09
Abstract
Abstract Substantially sulfur-free combustible fuel gas under superatmospheric pressure is produced by partial combustion or gasification under superatmospheric pressure of a sulfur-containing solid, liquid or gaseous fuel. The gasification is effected within a fluidized bed of particles containing alkaline earth metal compounds (e.g. the oxides) which are capable of reacting with, and of fixing, the fuel sulfur as sulfides under reducing conditions. Sulfide-containing particles are exposed to an oxidizing atmosphere and the sulfides are thereby converted to oxides with the liberation of SO 2 in useful concentrations, and with the liberation of heat. Particles containing regenerated oxides are re-used for fixing more sulfur during fuel gasification. Expedients are described by which it is ensured that the sulfur-fixing activity of the particles is substantially maintained and that the temperatures of the particles during sulfur-fixing and regeneration are maintained within predetermined ranges. The pressurized sulfur-free fuel gas may be directly used to power a gas turbine.
Inventors
- 👤 Gerald Moss
- 👤 John William Thomas Craig
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-26 11:44
CPC Classifications
C; C10; C10G; C10G29/00; C10G29/16; B; B01; B01J; B01J8/00; B01J8/18; B01J8/24; B01J8/26; C01; C01B; C01B3/00; C01B3/02; C01B3/22; C01B3/24; C01B3/28; C01B3/32; C01B3/34; C01B3/36; C10G25/00; C10G25/003; C10G25/06; C10G25/09; F; F23; F23C; F23C2900/00; F23C2900/99008; Y; Y02; Y02E; Y02E20/00; Y02E20/34
Claims Analysis
Total Claims: 10
Claim 1
Independent Claim
332 words
A method for producing a substantially sulphur-free combustible fuel gas from a sulphur-containing fuel comprising: feeding a sulphur-containing fuel into a bed of particles comprising an alkaline earth metal oxide and contained within a reactor, said bed of particles being fluidized by an upwardly flowing stream of an oxygen-containing gas at a superatmospheric pressure, the rate of supply of said oxygen-containing gas and the partial pressure or concentration of oxygen therein being so adjusted in relation to the fuel feed rate that the oxygen supplied is insufficient for complete combustion of the fuel, whereby the sulphur-containing fuel is partially combusted at a temperature in the range from about 800° to about 1000°C. which is varied above and below the recarbonation temperature of said alkaline earth metal oxide at the superatmospheric pressure employed such that the average temperature in the reactor bed is below the recarbonation temperature of the alkaline earth metal oxide whereby a portion of the alkaline earth metal oxide is converted to the corresponding carbonate and a substantially sulphur-free combustible gas is formed as the result of the sulphur from the sulphur-containing fuel becoming fixed in the particles of the bed as an alkaline earth metal sulphide by reaction with the corresponding alkaline earth metal oxide in the particles; recovering a substantially sulphur-free combustible gas from the reactor bed; transferring particles comprising an alkaline earth metal carbonate and an alkaline earth metal sulphide from a first region of the reaction bed of particles to a first region of a regenerator wherein said particles are contained and contacted with an upwardly flowing stream of an oxygen-containing gas at a temperature within the range from 1035°C. to 1300°C., whereby said alkaline earth metal sulphide and said alkaline earth metal carbonate are converted to the corresponding alkaline earth metal oxide with the liberation of sulphur dioxide and carbon dioxide, the temperature in said regenerator being at least partially controlled by controlling the amount of alkaline earth metal carbonate actually formed in said reactor.
Claim 2
Independent Claim
332 words
A method for producing a substantially sulphur-free combustible fuel gas from a sulphur-containing fuel comprising: feeding a sulphur-containing fuel into a bed of particles comprising an alkaline earth metal oxide and contained within a reactor, said bed of particles being fluidized by an upwardly flowing stream of an oxygen-containing gas at a superatmospheric pressure, the rate of supply of said oxygen-containing gas and the partial pressure or concentration of oxygen therein being so adjusted in relation to the fuel feed rate that the oxygen supplied is insufficient for complete combustion of the fuel, whereby the sulphur-containing fuel is partially combusted at a temperature in the range from about 800° to about 1000°C. which is varied above and below the recarbonation temperature of said alkaline earth metal oxide at the superatmospheric pressure employed such that the average temperature in the reactor bed is below the recarbonation temperature of the alkaline earth metal oxide whereby a portion of the alkaline earth metal oxide is converted to the corresponding carbonate and a substantially sulphur-free combustible gas is formed as the result of the sulphur from the sulphur-containing fuel becoming fixed in the particles of the bed as an alkaline earth metal sulphide by reaction with the corresponding alkaline earth metal oxide in the particles; recovering a substantially sulphur-free combustible gas from the reactor bed; transferring particles comprising an alkaline earth metal carbonate and an alkaline earth metal sulphide from a first region of the reaction bed of particles to a first region of a regenerator wherein said particles are contained and contacted with an upwardly flowing stream of an oxygen-containing gas at a temperature within the range from 1035°C. to 1300°C., whereby said alkaline earth metal sulphide and said alkaline earth metal carbonate are converted to the corresponding alkaline earth metal oxide with the liberation of sulphur dioxide and carbon dioxide, the temperature in said regenerator being at least partially controlled by controlling the amount of alkaline earth metal carbonate actually formed in said reactor.
Claim 3
Dependent Claim
23 words
The process of claim 1 wherein the sulfur-containing fuel is partially combusted at a temperature within the range from about 840° to 900°C.
Claim 4
Dependent Claim
14 words
The method of claim 1 wherein said alkaline earth metal oxide is calcium oxide.
Claim 5
Dependent Claim
22 words
The process of claim 2 wherein said bed of particles in the reactor comprises about 19 wt. % alkaline earth metal carbonate.
Claim 6
Independent Claim
254 words
A method for producing a substantially sulphur-free combustible fuel gas from a sulphur-containing fuel comprising: feeding a sulphur-containing fuel into a bed of particles comprising an alkaline earth metal oxide and contained within a reactor, said bed of particles being fluidized by an upwardly flowing stream of an oxygen-containing gas at a super-atmospheric pressure, the rate of supply of said oxygen-containing gas and the partial pressure or concentration of oxygen therein being so adjusted in relation to the fuel feed rate that the oxygen supplied is insufficient for complete combustion of the fuel, whereby the sulphur-containing fuel is partially combusted at a temperature in the range from about 800° to about 1000°C. to form a substantially sulphur-free combustible gas and the sulphur of the sulphur-containing fuel is fixed in the particles of the bed partially as an alkaline earth metal sulphide and partially as an alkaline earth metal sulphate by reaction of said sulphur with the alkaline earth metal oxide in said bed; recovering a substantially sulphur-free combustible gas from the reactor bed; transferring particles from the base of said reactor bed and containing alkaline earth metal sulphate and particles from the top of said reactor bed containing alkaline earth metal sulphide to a first region of a regenerator wherein said particles are contained and contacted with an upwardly flowing stream of an oxygen-containing gas at a temperature within the range from 1035°C. to 1300°C., whereby said alkaline earth metal sulphide and said alkaline earth metal sulfate are converted to alkaline earth metal oxide.
Claim 7
Independent Claim
254 words
A method for producing a substantially sulphur-free combustible fuel gas from a sulphur-containing fuel comprising: feeding a sulphur-containing fuel into a bed of particles comprising an alkaline earth metal oxide and contained within a reactor, said bed of particles being fluidized by an upwardly flowing stream of an oxygen-containing gas at a super-atmospheric pressure, the rate of supply of said oxygen-containing gas and the partial pressure or concentration of oxygen therein being so adjusted in relation to the fuel feed rate that the oxygen supplied is insufficient for complete combustion of the fuel, whereby the sulphur-containing fuel is partially combusted at a temperature in the range from about 800° to about 1000°C. to form a substantially sulphur-free combustible gas and the sulphur of the sulphur-containing fuel is fixed in the particles of the bed partially as an alkaline earth metal sulphide and partially as an alkaline earth metal sulphate by reaction of said sulphur with the alkaline earth metal oxide in said bed; recovering a substantially sulphur-free combustible gas from the reactor bed; transferring particles from the base of said reactor bed and containing alkaline earth metal sulphate and particles from the top of said reactor bed containing alkaline earth metal sulphide to a first region of a regenerator wherein said particles are contained and contacted with an upwardly flowing stream of an oxygen-containing gas at a temperature within the range from 1035°C. to 1300°C., whereby said alkaline earth metal sulphide and said alkaline earth metal sulfate are converted to alkaline earth metal oxide.
Claim 8
Dependent Claim
43 words
The method of claim 5 wherein the temperature in the regenerator bed is controlled, at least partially, by controlling the ratio of particles transferred from the lower portion of the reactor bed and particles transferred from the upper portion of said reactor bed.
Claim 9
Dependent Claim
86 words
A method according to claim 6 wherein an off-gas containing SO 2 is withdrawn from the regenerator and the concentration of SO 2 in the off-gas leaving the regenerator bed is monitored, and wherein the oxygen-containing gas supplied into regenerator bed comprises an inert diluent gas, the concentration or partial pressure of inert diluent gas being varied in accordance with the concentration of SO 2 in the regenerator bed off-gases, whereby substantially to control the concentration or partial pressure of SO 2 in the regenerator off-gases.
Claim 10
Dependent Claim
13 words
The method of claim 5 wherein said alkaline earth oxide is calcium oxide.
References Cited (Backward Citations)
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1979-07-13 | 1980-01-12 | 1980-07-13 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1983-07-13 | 1984-01-12 | 1984-07-13 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1987-07-13 | 1988-01-12 | 1988-07-13 | $7700.00 | Window Closed / Lapsed |