Patent US3966692A successfully refreshed from Google Patents.
US3966692A
Expired / Lapsed
US
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Process for halogenating rubber
Assignee: Covestro International SA
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Filing: 1974-06-10
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Granted: 1976-06-29
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Expires: 1994-06-10
Abstract
Abstract A process for halogenating rubber wherein a fluid halogen is dissolved in a flowing stream of the rubber dissolved in an organic solvent. The flow of the stream is maintained at a Reynold's number below 100 while maintaining a pressure which assures complete dissolving of the halogen while also preventing vaporization of volatile constituents in the stream during reaction of the halogen with the rubber.
Inventors
- 👤 Richard E. Driscoll
- 👤 Hugh E. Milligan
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-31 12:14
CPC Classifications
C; C08; C08F; C08F8/00; C08F8/18; C08F8/20; C08F8/22
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
133 words
In a process for halogenating an elastomer wherein a halogen is incorporated into a solution of the elastomer in an organic solvent and reaction of the halogen with the elastomer occurs while both are dissolved in the solvent, the improvement which comprises mixing a fluid halogen with a continuously flowing stream of the elastomer solution and followed by reaction of said halogen with the elastomer of said stream, the Reynold's number of said stream being below 100 during mixing of the halogen and the reaction thereof with the dissolved elastomer in the stream, and wherein a pressure is maintained on said stream which assures substantially complete disolution of the halogen therein during mixing and reaction while also preventing vaporization of volatile components of said stream during reaction of the halogen with the rubber.
Claim 2
Dependent Claim
133 words
In a process for halogenating an elastomer wherein a halogen is incorporated into a solution of the elastomer in an organic solvent and reaction of the halogen with the elastomer occurs while both are dissolved in the solvent, the improvement which comprises mixing a fluid halogen with a continuously flowing stream of the elastomer solution and followed by reaction of said halogen with the elastomer of said stream, the Reynold's number of said stream being below 100 during mixing of the halogen and the reaction thereof with the dissolved elastomer in the stream, and wherein a pressure is maintained on said stream which assures substantially complete disolution of the halogen therein during mixing and reaction while also preventing vaporization of volatile components of said stream during reaction of the halogen with the rubber.
Claim 3
Dependent Claim
28 words
A process as defined in claim 1 wherein the elastomer is butyl rubber and the halogen is selected from the group consisting of chlorine, bromine, or bromine monochloride.
Claim 4
Dependent Claim
32 words
A process as defined in claim 2 wherein the stream of elastomer solution is at a temperature above about 60°F. during dissolving of the halogen and the reaction thereof with the rubber.
Claim 5
Dependent Claim
24 words
A process as in claim 3 wherein the temperature of the solution is at a temperature above about 60°F. and up to about 100°F.
Claim 6
Dependent Claim
63 words
A process as in claim 2 wherein the organic solvent is hexane and the stream of elastomer solution is maintained at a temperature of above about 60°F. and up to about 100°F. during dissolving of the halogen and the reaction thereof with the rubber while a pressure within the range of about 10 psig to about 30 psig is maintained on said stream.
Claim 7
Dependent Claim
33 words
A process as in claim 2 wherein said temperature is within the range of about 80°F. to about 100°F. while said pressure is within the range of about 20 to about 30 psig.
Claim 8
Dependent Claim
35 words
The process as defined in claim 2 wherein the amount of halogen dissolved in the rubber solution is up to about 4 weight percent based upon the weight of the elastomer dissolved in said solution.
Claim 9
Dependent Claim
31 words
A process as defined in claim 2 wherein the viscosity of the rubber solution prior to dissolving the halogen therein is within the range of about 1500 to about 6000 centipoise.
Claim 10
Dependent Claim
27 words
A process as defined in claim 2 wherein the viscosity of the rubber solution following halogenation is within the range of about 1000 to about 1500 centipoise.
Claim 11
Dependent Claim
28 words
A process as defined in claim 2 wherein the rubber solution contains no more than about 2% by weight of water when dissolving and reacting the halogen therein.
References Cited (Backward Citations)
US2631984A
Cited
US2964489A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1979-06-29 | 1979-12-29 | 1980-06-29 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1983-06-29 | 1983-12-29 | 1984-06-29 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1987-06-29 | 1987-12-29 | 1988-06-29 | $7700.00 | Window Closed / Lapsed |