Crosslinked vinylcarbonyl resins having α-amino acid functionality

Claim 2

A resin having α amino acid functionality and which is derived from a crosslinked vinylcarbonyl copolymeric backbone, said resin having the followng general formula: ##EQU3## wherein R is H or C 1 - C 4 alkyl; R 1 is H or C 1 - C 10 alkyl; R 2 and R 3 are independently selected from H,C.sub. 1 -C 18 alkyl, aryl, alkylaryl, and cycloalkyl; and R 4 and R 5 are independently selected from H, C 1 - C 18 alkyl, and arylalkyl or taken together are linked to form a cyclic ring, said resin being crosslinked with about 2 to 30% by weight of at least one crosslinking monomer selected from polyvinyl aromatic hydrocarbons and polyvinyl ethers and esters of polyhydric alcohols.

Claim 3

A resin as claimed in claim 1 wherein the vinylcarbonyl copolymeric backbone is acrolein.

Claim 4

A resin as claimed in claim 1 wherein the functional moiety is α-alkylglycine.

Claim 5

A resin as claimed in claim 1 wherein functional moiety is N-methyl-α-alkylglycine.

Claim 6

A resin as claimed in claim 1 wherein the crosslinker is divinylbenzene.

Claim 7

A resin as claimed in claim 1 wherein the crosslinker is a mixture of divinylbenzene and diethyleneglycol divinyl ether.

Claim 8

A resin as claimed in claim 1 which is macroreticular in structure.

Claim 9

A resin as claimed in claim 1 wherein the resin is gellular in structure.

Claim 10

A process for preparing an amphoteric ion exchange resin having α amino acid functionality which comprises the steps of copolymerizing by suspension polymerization a vinylcarbonyl monomer of the general formula: ##EQU4## wherein R is H or C 1 - C 4 alkyl; R 1 is H or C 1 - C 10 alkyl; and R 2 and R 3 are independently selected from H, C 1 - C 18 alkyl, aryl, alkylaryl and cycloalkyl, in the presence of at least one crosslinking monomer selected from polyvinyl aromatic hydrocarbons and polyvinyl ether and esters of polyhydric alcohols, thereafter reacting the copolymer by the Strecker synthesis with an inorganic ionic cyanide component and with an amine of the formula (R 4 ) (R 5 ) NH wherein R 4 and R 5 are independently selected from H, C 1 - C 18 alkyl and arylalkyl and taken together R 4 and R 5 may define a cyclic radical, and finally hydrolizing the reaction product to obtain an α-amino acid resin.

Claim 11

A process for preparing an amphoteric ion exchange resin having α amino acid functionality which comprises the steps of copolymerizing by suspension polymerization a vinylcarbonyl monomer of the general formula: ##EQU4## wherein R is H or C 1 - C 4 alkyl; R 1 is H or C 1 - C 10 alkyl; and R 2 and R 3 are independently selected from H, C 1 - C 18 alkyl, aryl, alkylaryl and cycloalkyl, in the presence of at least one crosslinking monomer selected from polyvinyl aromatic hydrocarbons and polyvinyl ether and esters of polyhydric alcohols, thereafter reacting the copolymer by the Strecker synthesis with an inorganic ionic cyanide component and with an amine of the formula (R 4 ) (R 5 ) NH wherein R 4 and R 5 are independently selected from H, C 1 - C 18 alkyl and arylalkyl and taken together R 4 and R 5 may define a cyclic radical, and finally hydrolizing the reaction product to obtain an α-amino acid resin.

Claim 12

A process as claimed in claim 9 wherein the amine component comprises ammonium chloride.

Claim 13

A process as claimed in claim 9 wherein the the cyanide component comprises potassium or sodium cyanide.

Claim 14

A process as claimed in claim 9 wherein the copolymeric backbone comprises acrolein.