Patent US3963802A successfully refreshed from Google Patents.
US3963802A
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US
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Blend of ethylene copolymer elastomer and a copolyetherester elastomer
Assignee: EIDP Inc
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Filing: 1975-06-20
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Granted: 1976-06-15
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Expires: 1995-06-20
Abstract
Abstract An elastomer comprising a blend of (A) an ethylene copolymer and (B) a copolyetherester derived from a dicarboxylic acid, a diol, and a poly(oxyalkylene)glycol.
Inventors
- 👤 Chi-Kai Shih
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-25 15:19
CPC Classifications
C; C08; C08L; C08L23/00; C08L23/02; C08L23/16; C08L67/00; C08L67/02; C08L67/025
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
191 words
An elastomeric blend of (A) an ethylene copolymer in which the comonomer is selected from the group consisting of an alpha-olefin, a nonconjugated diolefin, and a mixture of both, said copolymer having a melting point not greater than 85°C., and (B) a segmented copolyetherester consisting of 15-95% by weight of short chain ester units which can be derived from a dicaboxylic acid having a molecular weight not greater than 300 and a diol having a molecular weight not greater than 250, and 5-85% by weight of long chain ester units which can be derived from a dicarboxylic acid having a molecular weight not greater than 300 and a poly(oxyalkylene)glycol having a molecular weight of 400-6000, said copolyetherester having a melting point of at least 100°C.; the weight ratio of A:B in said blend being 1:20 to 20:1, with thw provisos that (a) when said copolyetherester contains less than 20% by weight of long chain ester units, the ratio of A:B is less than 1:2 or greater than 2:1 and (b) when said ethylene copolymer has a melting point not greater than 25°C., the ratio of A:B is not greater than 1:1.
Claim 2
Dependent Claim
191 words
An elastomeric blend of (A) an ethylene copolymer in which the comonomer is selected from the group consisting of an alpha-olefin, a nonconjugated diolefin, and a mixture of both, said copolymer having a melting point not greater than 85°C., and (B) a segmented copolyetherester consisting of 15-95% by weight of short chain ester units which can be derived from a dicaboxylic acid having a molecular weight not greater than 300 and a diol having a molecular weight not greater than 250, and 5-85% by weight of long chain ester units which can be derived from a dicarboxylic acid having a molecular weight not greater than 300 and a poly(oxyalkylene)glycol having a molecular weight of 400-6000, said copolyetherester having a melting point of at least 100°C.; the weight ratio of A:B in said blend being 1:20 to 20:1, with thw provisos that (a) when said copolyetherester contains less than 20% by weight of long chain ester units, the ratio of A:B is less than 1:2 or greater than 2:1 and (b) when said ethylene copolymer has a melting point not greater than 25°C., the ratio of A:B is not greater than 1:1.
Claim 3
Dependent Claim
41 words
The blend of claim 1 wherein ethylene copolymer (A) has a melting point of 35°-65°C. and copolyetherester (B) contains 35-65% by weight of long chain ester units, and these polymers are blended in proportions of A:B ranging from 1:20 to 20:1.
Claim 4
Dependent Claim
16 words
The blend of claim 2 wherein the weight ratio of A:B is from 1:20 to 1:1.
Claim 5
Dependent Claim
17 words
The blend of claim 1 wherein ethylene copolymer (A) is an ethylene/propylene/1,4-hexadiene or an ethylene/propylene/ethylidene norbornene terpolymer.
Claim 6
Dependent Claim
27 words
The blend of claim 1 wherein copolyetherester (B) is prepared from poly(tetramethylene ether)glycol, 1,4-butanediol, and terephthalic acid, optionally containing up to 30% of isophthalic or phthalic acid.
Claim 7
Dependent Claim
15 words
The blend of claim 1 wherein a filler and pigment is incorporated into the blend.
Claim 8
Dependent Claim
14 words
The blend of claim 1 wherein a silica filler is incorporated into the blend.
Claim 9
Dependent Claim
203 words
A copolyetherester-containing polymer blend, the copolyetherester of which consists of 15-95% by weight of short chain ester units derived from a dicarboxylic acid having a molecular weight not greater than 300 and a diol having a molecular weight not greater than 250, and 5-85% by weight of long chain ester units derived from a dicarboxylic acid having a molecular weight not greater than 300 and a poly(oxyalkylene) glycol having a molecular weight of 400-6000, said copolyestherester having a melting point of at least 100°C., characterized in that said copolyetherester is blended with an ethylene copolymer having a melting point not greater than 85°C., the comonomer of which is selected from the group consisting of an alpha-olefin, a nonconjugated diolefin, and a mixture of both, these polymers being blended in amounts such that the weight ratio of ethylene copolymer (A) to copolyetherester (B) in the blend is 1:20 to 20:1, with the provisos that (a) when said copolyetherester contains less than 20% by weight of long chain ester units the raio of A:B is less than 1:2 or greater than 2:1, and (b) when said ethylene copolymer has a melting point not greater than 25°C., the ratio of A:B is not greater than 1:1.
Claim 10
Dependent Claim
203 words
A copolyetherester-containing polymer blend, the copolyetherester of which consists of 15-95% by weight of short chain ester units derived from a dicarboxylic acid having a molecular weight not greater than 300 and a diol having a molecular weight not greater than 250, and 5-85% by weight of long chain ester units derived from a dicarboxylic acid having a molecular weight not greater than 300 and a poly(oxyalkylene) glycol having a molecular weight of 400-6000, said copolyestherester having a melting point of at least 100°C., characterized in that said copolyetherester is blended with an ethylene copolymer having a melting point not greater than 85°C., the comonomer of which is selected from the group consisting of an alpha-olefin, a nonconjugated diolefin, and a mixture of both, these polymers being blended in amounts such that the weight ratio of ethylene copolymer (A) to copolyetherester (B) in the blend is 1:20 to 20:1, with the provisos that (a) when said copolyetherester contains less than 20% by weight of long chain ester units the raio of A:B is less than 1:2 or greater than 2:1, and (b) when said ethylene copolymer has a melting point not greater than 25°C., the ratio of A:B is not greater than 1:1.
Claim 11
Dependent Claim
40 words
The blend of claim 3 wherein ethylene copolymer (A) is an ethylene/propylene/1,4-hexadiene or an ethylene/propylene/ethylidene norbornene terpolymer and copolyetherester (B) is prepared from poly(tetramethylene ether) glycol, 1,4-butanediol, and terephthalic acid, optionally containing up to 30% of isophthalic or phthalic acid.
References Cited (Backward Citations)
US3223752A
Cited
US3431322A
Cited
US3534120A
Cited
US3546319A
Cited
US3627712A
Cited
US3644267A
Cited
US3718715A
Cited
US3795644A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1979-06-15 | 1979-12-15 | 1980-06-15 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1983-06-15 | 1983-12-15 | 1984-06-15 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1987-06-15 | 1987-12-15 | 1988-06-15 | $7700.00 | Window Closed / Lapsed |