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US3963802A Expired / Lapsed US ⏱️ 0.0 years remaining

Blend of ethylene copolymer elastomer and a copolyetherester elastomer

Assignee: EIDP Inc
•
Filing: 1975-06-20
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Granted: 1976-06-15
•
Expires: 1995-06-20
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Abstract

Abstract An elastomer comprising a blend of (A) an ethylene copolymer and (B) a copolyetherester derived from a dicarboxylic acid, a diol, and a poly(oxyalkylene)glycol.

Inventors

  • 👤 Chi-Kai Shih

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 13:28
CPC Classifications
C; C08; C08L; C08L23/00; C08L23/02; C08L23/16; C08L67/00; C08L67/02; C08L67/025

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 191 words
An elastomeric blend of (A) an ethylene copolymer in which the comonomer is selected from the group consisting of an alpha-olefin, a nonconjugated diolefin, and a mixture of both, said copolymer having a melting point not greater than 85°C., and (B) a segmented copolyetherester consisting of 15-95% by weight of short chain ester units which can be derived from a dicaboxylic acid having a molecular weight not greater than 300 and a diol having a molecular weight not greater than 250, and 5-85% by weight of long chain ester units which can be derived from a dicarboxylic acid having a molecular weight not greater than 300 and a poly(oxyalkylene)glycol having a molecular weight of 400-6000, said copolyetherester having a melting point of at least 100°C.; the weight ratio of A:B in said blend being 1:20 to 20:1, with thw provisos that (a) when said copolyetherester contains less than 20% by weight of long chain ester units, the ratio of A:B is less than 1:2 or greater than 2:1 and (b) when said ethylene copolymer has a melting point not greater than 25°C., the ratio of A:B is not greater than 1:1.
Claim 2
Dependent Claim 191 words
An elastomeric blend of (A) an ethylene copolymer in which the comonomer is selected from the group consisting of an alpha-olefin, a nonconjugated diolefin, and a mixture of both, said copolymer having a melting point not greater than 85°C., and (B) a segmented copolyetherester consisting of 15-95% by weight of short chain ester units which can be derived from a dicaboxylic acid having a molecular weight not greater than 300 and a diol having a molecular weight not greater than 250, and 5-85% by weight of long chain ester units which can be derived from a dicarboxylic acid having a molecular weight not greater than 300 and a poly(oxyalkylene)glycol having a molecular weight of 400-6000, said copolyetherester having a melting point of at least 100°C.; the weight ratio of A:B in said blend being 1:20 to 20:1, with thw provisos that (a) when said copolyetherester contains less than 20% by weight of long chain ester units, the ratio of A:B is less than 1:2 or greater than 2:1 and (b) when said ethylene copolymer has a melting point not greater than 25°C., the ratio of A:B is not greater than 1:1.
Claim 3
Dependent Claim 41 words
The blend of claim 1 wherein ethylene copolymer (A) has a melting point of 35°-65°C. and copolyetherester (B) contains 35-65% by weight of long chain ester units, and these polymers are blended in proportions of A:B ranging from 1:20 to 20:1.
Claim 4
Dependent Claim 16 words
The blend of claim 2 wherein the weight ratio of A:B is from 1:20 to 1:1.
Claim 5
Dependent Claim 17 words
The blend of claim 1 wherein ethylene copolymer (A) is an ethylene/propylene/1,4-hexadiene or an ethylene/propylene/ethylidene norbornene terpolymer.
Claim 6
Dependent Claim 27 words
The blend of claim 1 wherein copolyetherester (B) is prepared from poly(tetramethylene ether)glycol, 1,4-butanediol, and terephthalic acid, optionally containing up to 30% of isophthalic or phthalic acid.
Claim 7
Dependent Claim 15 words
The blend of claim 1 wherein a filler and pigment is incorporated into the blend.
Claim 8
Dependent Claim 14 words
The blend of claim 1 wherein a silica filler is incorporated into the blend.
Claim 9
Dependent Claim 203 words
A copolyetherester-containing polymer blend, the copolyetherester of which consists of 15-95% by weight of short chain ester units derived from a dicarboxylic acid having a molecular weight not greater than 300 and a diol having a molecular weight not greater than 250, and 5-85% by weight of long chain ester units derived from a dicarboxylic acid having a molecular weight not greater than 300 and a poly(oxyalkylene) glycol having a molecular weight of 400-6000, said copolyestherester having a melting point of at least 100°C., characterized in that said copolyetherester is blended with an ethylene copolymer having a melting point not greater than 85°C., the comonomer of which is selected from the group consisting of an alpha-olefin, a nonconjugated diolefin, and a mixture of both, these polymers being blended in amounts such that the weight ratio of ethylene copolymer (A) to copolyetherester (B) in the blend is 1:20 to 20:1, with the provisos that (a) when said copolyetherester contains less than 20% by weight of long chain ester units the raio of A:B is less than 1:2 or greater than 2:1, and (b) when said ethylene copolymer has a melting point not greater than 25°C., the ratio of A:B is not greater than 1:1.
Claim 10
Dependent Claim 203 words
A copolyetherester-containing polymer blend, the copolyetherester of which consists of 15-95% by weight of short chain ester units derived from a dicarboxylic acid having a molecular weight not greater than 300 and a diol having a molecular weight not greater than 250, and 5-85% by weight of long chain ester units derived from a dicarboxylic acid having a molecular weight not greater than 300 and a poly(oxyalkylene) glycol having a molecular weight of 400-6000, said copolyestherester having a melting point of at least 100°C., characterized in that said copolyetherester is blended with an ethylene copolymer having a melting point not greater than 85°C., the comonomer of which is selected from the group consisting of an alpha-olefin, a nonconjugated diolefin, and a mixture of both, these polymers being blended in amounts such that the weight ratio of ethylene copolymer (A) to copolyetherester (B) in the blend is 1:20 to 20:1, with the provisos that (a) when said copolyetherester contains less than 20% by weight of long chain ester units the raio of A:B is less than 1:2 or greater than 2:1, and (b) when said ethylene copolymer has a melting point not greater than 25°C., the ratio of A:B is not greater than 1:1.
Claim 11
Dependent Claim 40 words
The blend of claim 3 wherein ethylene copolymer (A) is an ethylene/propylene/1,4-hexadiene or an ethylene/propylene/ethylidene norbornene terpolymer and copolyetherester (B) is prepared from poly(tetramethylene ether) glycol, 1,4-butanediol, and terephthalic acid, optionally containing up to 30% of isophthalic or phthalic acid.

References Cited (Backward Citations)

US3223752A Cited
US3431322A Cited
US3534120A Cited
US3546319A Cited
US3627712A Cited
US3644267A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-06-15 1979-12-15 1980-06-15 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-06-15 1983-12-15 1984-06-15 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-06-15 1987-12-15 1988-06-15 $7700.00 Window Closed / Lapsed

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