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Dishwashing compositions

Assignee: Lever Brothers Co
•
Filing: 1973-10-01
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Granted: 1976-06-15
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Expires: 1993-10-01
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Abstract

Abstract A dishwashing composition which can be used in the conventional manner to obtain good foaming and detergency and can also be used in dilutions of about 5:1 or less to obtain a non-stick effect on aluminium pans contains from 10-50% of a detergent of which from 5-40% is a calcium/magnesium sensitive anionic synthetic detergent, from 0.01-2% of a selected alkyl phosphate monoester, and from 1 to 40% of a solubilizer. An example of such a composition has the following formulaton: % ______________________________________ Sodium dodecyl benzene 30.0 sulphonate Ammonium C 12 -C 15 primary 8.0 alcohol 3EO sulphate Lauryl phosphate (12%) 0.5 Succinic acid 1.5 Glutaric acid 1.0 Ethanol 6.0 Urea 6.0 Water and ammonia to pH 5 balance ______________________________________

Inventors

  • 👤 Peter Leonard Dawson
  • 👤 Michael Tom Rothwell

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 05:04
CPC Classifications
C; C11; C11D; C11D1/00; C11D1/02; C11D1/34; C11D1/345

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 305 words
In a liquid hand dishwashing composition of the type having a pH of not more than 7 and comprising from about 10 to about 50% by weight of a detergent active compound from 5 to 40% by weight of which is a calcium/magnesium sensitive anionic synthetic detergent selected from the group consisting essentially of C 11-18 α and random alkene sulphonates, random C 13-18 alkane sulphonates, C 10 -C 15 alkyl benzene sulphonates, C 11 -C 15 primary and secondary alcohol sulphates and mixtures thereof, and water the improvement which comprises in incorporating in the composition from 0.01 to 2% by weight of a phosphate monoester having the general formulae ##EQU5## wherein x + y + z is from 9-17 and one of x,y and z may be zero, and n is zero or 1, ##EQU6## wherein R and R 1 are C 8 -C 18 alkyl groups and one of R and R 1 may be hydrogen, ##EQU7## where a + b is from 10-16 and one of a and b may be zero and n is zero or 1, and (iv) analogues of said esters having the formulae (i), (ii) and (iii), the alkyl groups being substituted by alkenyl groups, and from 1 to 40% by weight of a nonionic or anionic solubilizer, a 0.05% aqueous solution of which will remain clear at 24°H of hardness and neutral pH at temperatures of from 20°-45°C the ratio of the total amount of detergent active compound and solubilizer to the amount of phosphate monoester in the composition being from 1500:1 to 30:1 when the phosphate monoester is derived from a linear primary alcohol, from 1000:1 to 50:1 when the phosphate monoester is derived from a branched chain primary alcohol, and from 600:1 to 150:1 when the phosphate monoester is derived from a linear secondary alcohol.
Claim 2
Dependent Claim 305 words
In a liquid hand dishwashing composition of the type having a pH of not more than 7 and comprising from about 10 to about 50% by weight of a detergent active compound from 5 to 40% by weight of which is a calcium/magnesium sensitive anionic synthetic detergent selected from the group consisting essentially of C 11-18 α and random alkene sulphonates, random C 13-18 alkane sulphonates, C 10 -C 15 alkyl benzene sulphonates, C 11 -C 15 primary and secondary alcohol sulphates and mixtures thereof, and water the improvement which comprises in incorporating in the composition from 0.01 to 2% by weight of a phosphate monoester having the general formulae ##EQU5## wherein x + y + z is from 9-17 and one of x,y and z may be zero, and n is zero or 1, ##EQU6## wherein R and R 1 are C 8 -C 18 alkyl groups and one of R and R 1 may be hydrogen, ##EQU7## where a + b is from 10-16 and one of a and b may be zero and n is zero or 1, and (iv) analogues of said esters having the formulae (i), (ii) and (iii), the alkyl groups being substituted by alkenyl groups, and from 1 to 40% by weight of a nonionic or anionic solubilizer, a 0.05% aqueous solution of which will remain clear at 24°H of hardness and neutral pH at temperatures of from 20°-45°C the ratio of the total amount of detergent active compound and solubilizer to the amount of phosphate monoester in the composition being from 1500:1 to 30:1 when the phosphate monoester is derived from a linear primary alcohol, from 1000:1 to 50:1 when the phosphate monoester is derived from a branched chain primary alcohol, and from 600:1 to 150:1 when the phosphate monoester is derived from a linear secondary alcohol.
Claim 3
Dependent Claim 24 words
A dishwashing composition according to claim 1 wherein the alkyl phosphate ester is in the form of a sodium, potassium or ammonium half salt.
Claim 4
Dependent Claim 18 words
A dishwashing composition according to claim 1 comprising from 0.02 to 0.1% by weight of the phosphate monoester.
Claim 5
Dependent Claim 27 words
A dishwashing composition according to claim 1 comprising from 0.5 to 5% by weight of an acid pH controller having a pKa in the range of 3-6.
Claim 6
Dependent Claim 29 words
A dishwashing composition according to claim 4 wherein the pH controller is selected from the group consisting of malonic, succinic, glutaric, citric, tartaric and lactic acid, and mixtures thereof.
Claim 7
Dependent Claim 27 words
A dishwashing composition according to claim 4 wherein the pH controller is selected from the group consisting of phthalic, adipic, fumaric and benzoic acid, and mixtures thereof.

References Cited (Backward Citations)

US2874124A Cited
US3032578A Cited
US3462520A Cited
US3513099A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-06-15 1979-12-15 1980-06-15 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-06-15 1983-12-15 1984-06-15 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-06-15 1987-12-15 1988-06-15 $7700.00 Window Closed / Lapsed

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