US3963504A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Porous ceramic structure
Assignee: WR Grace and Co
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Filing: 1974-12-24
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Granted: 1976-06-15
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Expires: 1994-12-24
Abstract
Abstract A porous ceramic monolithic structure prepared by shaping a ceramic filled polyolefinic material containing a plasticizer, shaping, extracting the plasticizer and treating to remove the polyolefin. The monolithic structure is characterized by uniform pore openings. It has uniform channels of an essentially rectangular cross section, laterally through the length of the monolith, varying in size from 0.025 to 0.20 inches.
Inventors
- 👤 Christian Bent Lundsager
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-28 21:42
CPC Classifications
C; C04; C04B; C04B38/00; C04B38/06; C04B38/0615; C04B38/062; B; B01; B01D; B01D53/00; B01D53/34; B01D53/74; B01D53/86; B01J; B01J37/00; B01J37/0009; B01J37/0018; Y; Y10; Y10T; Y10T428/00; Y10T428/24; Y10T428/24149
Claims Analysis
Total Claims: 6
Claim 1
Independent Claim
170 words
A ceramic monolith structure prepared by a process comprising the following steps: a. homogeneously blending a composition consisting essentially of 15-80 volume percent of a polyolefin having a molecular weight of at least 150,000 and a standard load melt index of substantially zero, 5-67 volume percent of a ceramic filler, 15-80 volume percent of a plasticizer; selected from a group consisting of mineral oils, glycols, triethyl phosphate, polyvinyl alcohol, and polyvinyl pyrrolidone, b. heating said composition to about 125° to 175°C., molding to form a plastic sheet and impressing ribs thereon, c. rolling said plastic sheet so that said ribs contact said sheet, heating to about 150°-250°C. to fuse the contacting areas together thermoplastically, d. extracting the plasticizer with water or an organic solvent, e. removing said polyolefin by heating to 240°-700°C. to form a porous ceramic structure and burn off the polyolefin and, f. firing said porous ceramic structure at a temperature of about 1300°-1450°C. for a period of time sufficient to sinter said porous ceramic structure, characterized by:
Claim 2
Dependent Claim
170 words
A ceramic monolith structure prepared by a process comprising the following steps: a. homogeneously blending a composition consisting essentially of 15-80 volume percent of a polyolefin having a molecular weight of at least 150,000 and a standard load melt index of substantially zero, 5-67 volume percent of a ceramic filler, 15-80 volume percent of a plasticizer; selected from a group consisting of mineral oils, glycols, triethyl phosphate, polyvinyl alcohol, and polyvinyl pyrrolidone, b. heating said composition to about 125° to 175°C., molding to form a plastic sheet and impressing ribs thereon, c. rolling said plastic sheet so that said ribs contact said sheet, heating to about 150°-250°C. to fuse the contacting areas together thermoplastically, d. extracting the plasticizer with water or an organic solvent, e. removing said polyolefin by heating to 240°-700°C. to form a porous ceramic structure and burn off the polyolefin and, f. firing said porous ceramic structure at a temperature of about 1300°-1450°C. for a period of time sufficient to sinter said porous ceramic structure, characterized by:
Claim 3
Dependent Claim
124 words
uniform channels of an essentially rectangular cross section laterally through the length of the monolith, varying in size from 0.025 to 0.20 inches; said channels being arranged in a pattern so that in the first direction a given channel adjoins the next channel separated by a common wall, and in a second direction, perpendicular to the first direction, a given channel adjoins one or more of the other channels sharing one wall with the adjacent other channel or channels, 2. a coefficient of thermal expansion of 1.2 to 3.0 × 10 - 6 per degree Fahrenheit, 3. a porosity of 20-30 percent, 4. A density of about 0.2 to 0.8 grams per cubic centimeter, 5. an average pore size of 4 to 8 microns.
Claim 4
Dependent Claim
124 words
uniform channels of an essentially rectangular cross section laterally through the length of the monolith, varying in size from 0.025 to 0.20 inches; said channels being arranged in a pattern so that in the first direction a given channel adjoins the next channel separated by a common wall, and in a second direction, perpendicular to the first direction, a given channel adjoins one or more of the other channels sharing one wall with the adjacent other channel or channels, 2. a coefficient of thermal expansion of 1.2 to 3.0 × 10 - 6 per degree Fahrenheit, 3. a porosity of 20-30 percent, 4. A density of about 0.2 to 0.8 grams per cubic centimeter, 5. an average pore size of 4 to 8 microns.
Claim 5
Dependent Claim
23 words
The monolithic structure according to claim 1 wherein the ceramic filler is selected from the group consisting of alumina, corderite, mullite and silica.
Claim 6
Dependent Claim
13 words
The ceramic structure according to claim 1 wherein the plasticizer is mineral oil.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1979-06-15 | 1979-12-15 | 1980-06-15 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1983-06-15 | 1983-12-15 | 1984-06-15 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1987-06-15 | 1987-12-15 | 1988-06-15 | $7700.00 | Window Closed / Lapsed |