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US3962514A Expired / Lapsed US ⏱️ 0.0 years remaining

Exuded transition metal spinel films on glass-ceramic articles

Assignee: Corning Glass Works
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Filing: 1974-01-01
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Granted: 1976-06-08
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Expires: 1994-01-01
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Abstract

Abstract Suitable glass-ceramic base compositions, including some siicates, aluminosilicates, lithium aluminosilicates, and boroaluminates, are modified by the addition of suitable quantities of transition metal oxides prior to melting and forming into thermallycrystallizable glass articles. Appropriate crystallization and post-crystallization heat treatments are thereafter employed to cause crystallization of the articles and the formation and growth of films thereon, which films are characterized by the presence of transition metal compounds of spinel structure therein. Such films demonstrate useful electrical, magnetic, catalytic and/or light-absorptive properties.

Inventors

  • 👤 Hermann L. Rittler

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 20:47
CPC Classifications
C; C03; C03C; C03C10/00; C03C10/0054; C03C10/0018; C03C10/0027; C03C2217/00; C03C2217/20; C03C2217/21; C03C2217/229; C03C2217/23; Y; Y10; Y10T; Y10T428/00; Y10T428/26; Y10T428/263; Y10T428/31; Y10T428/315

Claims Analysis

Total Claims: 2
Claim 1
Independent Claim 86 words
A glass-ceramic article having a. a composition consisting essentially in weight percent on the oxide basis as calculated from the batch, of about 20-35% Al 2 O 3 , 5-35% B 2 O 3 , 28-60% MnO 2 , 0-15% BaO, and 0-35% La 2 O 3 ; and b. an exuded transition metal-containing surface film ranging in thickness from about 0.1-4 microns composed predominantly of crystalline species selected from the group consisting of Mn 3 O 4 and Mn 2 Al 2 O 4 .
Claim 2
Dependent Claim 86 words
A glass-ceramic article having a. a composition consisting essentially in weight percent on the oxide basis as calculated from the batch, of about 20-35% Al 2 O 3 , 5-35% B 2 O 3 , 28-60% MnO 2 , 0-15% BaO, and 0-35% La 2 O 3 ; and b. an exuded transition metal-containing surface film ranging in thickness from about 0.1-4 microns composed predominantly of crystalline species selected from the group consisting of Mn 3 O 4 and Mn 2 Al 2 O 4 .

References Cited (Backward Citations)

US2920971A Cited
US2961352A Cited
US2996418A Cited
US3100158A Cited
US3148079A Cited
US3497366A Cited
US3676097A Cited
US3489577A Cited
US3725091A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-06-08 1979-12-08 1980-06-08 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-06-08 1983-12-08 1984-06-08 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-06-08 1987-12-08 1988-06-08 $7700.00 Window Closed / Lapsed

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