Patent US3962071A successfully refreshed from Google Patents.
US3962071A
Expired / Lapsed
US
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Process for producing lubricating oils
Assignee: Tonen General Sekiyu KK
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Filing: 1974-05-13
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Granted: 1976-06-08
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Expires: 1994-05-13
Abstract
Abstract A process for producing lubricating oils of enhanced photostability by hydrogenating a lubricating oil fraction of a hydrocrackate in the presence of a palladium catalyst supported on a silica-containing refractory inorganic oxide carrier in which the silica content is less than 40 weight %.
Inventors
- 👤 Takuji Itoh
- 👤 Tadashi Miura
- 👤 Ikuo Akitsuki
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-30 06:36
CPC Classifications
C; C10; C10G; C10G45/00; C10G45/44; C10G45/46; C10G45/52; C10G2400/00; C10G2400/10
Claims Analysis
Total Claims: 8
Claim 1
Independent Claim
217 words
A process for producing lubricating oils of enhanced photostability comprising the following steps in combination: i. hydrocracking a hydrocarbon oil having a kinematic viscosity of more than about 3 cst. at 98.9°C. over a hydrocracking catalyst under hydrocracking reaction conditions thereby producing a hydrocrackate product containing more than about 50 volume % of hydrocarbon oil fractions having lubricating oil viscosity; ii. fractionating said hydrocrackate to obtain at least one hydrocarbon oil fraction having lubricating oil viscosity; and iii. contacting said fraction having lubricating oil viscosity with hydrogen under hydrogenation reaction conditions comprising a reaction temperature of from about 180° to 300°C., a reaction pressure of more than about 10 kg/cm 2 , a liquid hourly space velocity of less than about 10 V/hr/V, and a hydrogen gas flow rate of from about 30 to 3000 Nm 3 /kl in the presence of a hydrogenation catalyst comprising palladium supported on a silicacontaining refractory inorganic oxide carrier in which the silica content is from about 5 to less than 40 weight %, said carrier having a specific surface area of from about 100 to 500 m 2 /g, a pore volume of from about 0.5 to 1.2 ml/g, an average pore radius of from about 30 to 120A and a bulk density of from about 0.5 to 0.7 g/ml.
Claim 2
Dependent Claim
217 words
A process for producing lubricating oils of enhanced photostability comprising the following steps in combination: i. hydrocracking a hydrocarbon oil having a kinematic viscosity of more than about 3 cst. at 98.9°C. over a hydrocracking catalyst under hydrocracking reaction conditions thereby producing a hydrocrackate product containing more than about 50 volume % of hydrocarbon oil fractions having lubricating oil viscosity; ii. fractionating said hydrocrackate to obtain at least one hydrocarbon oil fraction having lubricating oil viscosity; and iii. contacting said fraction having lubricating oil viscosity with hydrogen under hydrogenation reaction conditions comprising a reaction temperature of from about 180° to 300°C., a reaction pressure of more than about 10 kg/cm 2 , a liquid hourly space velocity of less than about 10 V/hr/V, and a hydrogen gas flow rate of from about 30 to 3000 Nm 3 /kl in the presence of a hydrogenation catalyst comprising palladium supported on a silicacontaining refractory inorganic oxide carrier in which the silica content is from about 5 to less than 40 weight %, said carrier having a specific surface area of from about 100 to 500 m 2 /g, a pore volume of from about 0.5 to 1.2 ml/g, an average pore radius of from about 30 to 120A and a bulk density of from about 0.5 to 0.7 g/ml.
Claim 3
Dependent Claim
22 words
A process as defined in claim 1 wherein said hydrocarbon oil in step (i) has a boiling point of above about 350°C.
Claim 4
Dependent Claim
52 words
A process as defined in claim 1 wherein said hydrocarbon oil fraction having lubricating oil viscosity is contacted with hydrogen under hydrofining reaction conditions in the presence of a sulfur-resistant hydrofining catalyst before being contacted in step (iii) with hydrogen under said hydrogenation reaction conditions in the presence of said hydrogenation catalyst.
Claim 5
Dependent Claim
34 words
A process as defined in claim 1 wherein said hydrocarbon oil fraction having lubricating oil viscosity is dewaxed before being contacted with hydrogen under hydrogenation reaction conditions in the presence of said hydrogenation catalyst.
Claim 6
Dependent Claim
24 words
A process according to claim 1 wherein said hydrogenation catalyst comprises 0.1 to 1 weight % palladium on said silica-containing refractory inorganic oxide carrier.
Claim 7
Dependent Claim
21 words
A process as defined in claim 5 wherein said carrier is alumina containing from about 5 to 40 wt. % silica.
Claim 8
Dependent Claim
69 words
A process as defined in claim 5 wherein said hydrogenation reaction conditions comprise a reaction temperature in the range from about 180° to 300°C., a reaction pressure in the range from about 30 to 200 kg/cm 2 , a liquid hourly space velocity in the range from about 0.1 to 3 V/Hr./V and a hydrogen gas flow rate in the range from about 50 to 2000 Nm 3 /kl.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1979-06-08 | 1979-12-08 | 1980-06-08 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1983-06-08 | 1983-12-08 | 1984-06-08 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1987-06-08 | 1987-12-08 | 1988-06-08 | $7700.00 | Window Closed / Lapsed |