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US3962055A Expired / Lapsed US ⏱️ 0.0 years remaining

Photosensitive compositions containing benzothiazole sensitizers

Assignee: Eastman Kodak Co
•
Filing: 1975-06-26
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Granted: 1976-06-08
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Expires: 1995-06-26
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Abstract

Abstract The invention relates to photopolymerizable polymeric compositions useful as coating and moldable compositions which are hardenable by ultraviolet radiation. These coating and moldable compositions comprise mixtures of of photopolymerizable or unsaturated compounds and at least one photoinitiator selected from the group consisting of halo-alkyl benzoxazoles, benzimidazoles and benzothiazoles.

Inventors

  • 👤 James G. Pacifici
  • 👤 Charles A. Kelly

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 13:01
CPC Classifications
C; C08; C08F; C08F2/00; C08F2/46; C08F2/48; C08F2/50; C08F299/00; C08F299/02; C08F299/04; C08F299/0442; C08F299/0457

Claims Analysis

Total Claims: 15
Claim 1
Independent Claim 106 words
A molding and coating composition capable of being hardenable by ultraviolet radiation comprising a mixture of a photopolymerizable or photocrosslinkable ethylenically unsaturated compound and from 0.01 to 10% by weight of a photoinitiator selected from the group consisting of aryl heterocyclic compounds having the formula ##SPC2## wherein R 1 , R 2 , R 3 and R 4 are hydrogen, alkyl, alkoxy, carboxy, alkoxycarbonyl, chlorine, bromine, nitro, amino and can be the same or different; Y is a sulfur atom; R 5 is CH 2 X, CHX 2 , CX 3 , aryl-CH 2 X; aryl-CHX 2 and aryl-CX 3 where X is chlorine and bromine.
Claim 2
Dependent Claim 106 words
A molding and coating composition capable of being hardenable by ultraviolet radiation comprising a mixture of a photopolymerizable or photocrosslinkable ethylenically unsaturated compound and from 0.01 to 10% by weight of a photoinitiator selected from the group consisting of aryl heterocyclic compounds having the formula ##SPC2## wherein R 1 , R 2 , R 3 and R 4 are hydrogen, alkyl, alkoxy, carboxy, alkoxycarbonyl, chlorine, bromine, nitro, amino and can be the same or different; Y is a sulfur atom; R 5 is CH 2 X, CHX 2 , CX 3 , aryl-CH 2 X; aryl-CHX 2 and aryl-CX 3 where X is chlorine and bromine.
Claim 3
Dependent Claim 74 words
A molding and coating composition according to claim 1 wherein said photoinitiator has the formula: ##SPC3## wherein R 1 , R 2 , R 3 and R 4 are hydrogen, alkyl, alkoxy, carboxy, alkoxycarbonyl, chlorine, bromine, nitro, amino and can be the same or different; R 5 is --CH 2 X, --CHX 2 , --CX 3 , --aryl CH 2 X, --aryl CHX 2 and --aryl CX 3 where X is chlorine or bromine.
Claim 4
Dependent Claim 51 words
A molding and coating composition according to claim 2 wherein said photoinitiator has the formula: ##SPC4## wherein R 1 , R 2 , R 3 and R 4 are hydrogen, alkyl, alkoxy, carboxy, alkoxycarbonyl, chlorine, bromine, nitro, amino and can be the same or different and X is chlorine or bromine.
Claim 5
Dependent Claim 51 words
A molding and coating composition according to claim 2 wherein said photoinitiator has the formula: ##SPC5## wherein R 1 , R 2 , R 3 and R 4 are hydrogen, alkyl, alkoxy, carboxy, alkoxycarbonyl, chlorine, bromine, nitro, amino and can be the same or different and X is chlorine or bromine.
Claim 6
Dependent Claim 51 words
A molding and coating composition according to claim 2 wherein said photoinitiator has the formula: ##SPC6## wherein R 1 , R 2 , R 3 and R 4 are hydrogen, alkyl, alkoxy, carboxy, alkoxycarbonyl, chlorine, bromine, nitro, amino and can be the same or different and X is chlorine or bromine.
Claim 7
Dependent Claim 51 words
A molding and coating composition according to claim 2 wherein said photoinitiator has the formula: ##SPC7## wherein R 1 , R 2 , R 3 and R 4 are hydrogen, alkyl, alkoxy, carboxy, alkoxycarbonyl, chlorine, bromine, nitro, amino and can be the same or different and X is chlorine or bromine.
Claim 8
Dependent Claim 51 words
A molding and coating composition according to claim 2 wherein said photoinitiator has the formula: ##SPC8## wherein R 1 , R 2 , R 3 and R 4 are hydrogen, alkyl, alkoxy, carboxy, alkoxycarbonyl, chlorine, bromine, nitro, amino and can be the same or different and X is chlorine or bromine.
Claim 9
Dependent Claim 51 words
A molding and coating composition according to claim 2 wherein said photoinitiator has the formula: ##SPC9## wherein R 1 , R 2 , R 3 and R 4 are hydrogen, alkyl, alkoxy, carboxy, alkoxycarbonyl, chlorine, bromine, nitro, amino and can be the same or different and X is chlorine or bromine.
Claim 10
Dependent Claim 16 words
A molding and coating composition according to claim 3 wherein said photoinitiator has the formula: ##SPC10##
Claim 11
Dependent Claim 16 words
A molding and coating composition according to claim 4 wherein said photoinitiator has the formula: ##SPC11##
Claim 12
Dependent Claim 16 words
A molding and coating composition according to claim 5 wherein said photoinitiator has the formula: ##SPC12##
Claim 13
Dependent Claim 16 words
A molding and coating composition according to claim 6 wherein said photoinitiator has the formula: ##SPC13##
Claim 14
Dependent Claim 16 words
A molding and coating composition according to claim 7 wherein said photoinitiator has the formula: ##SPC14##
Claim 15
Dependent Claim 16 words
A molding and coating composition according to claim 8 wherein said photoinitiator has the formula: ##SPC15##

References Cited (Backward Citations)

US2773822A Cited
US3622334A Cited
US3645772A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-06-08 1979-12-08 1980-06-08 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-06-08 1983-12-08 1984-06-08 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-06-08 1987-12-08 1988-06-08 $7700.00 Window Closed / Lapsed

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