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Heat-resistant adhesive lacquers as wire coatings

Assignee: Von Roll Schweiz AG
•
Filing: 1974-09-12
•
Granted: 1976-06-01
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Expires: 1994-09-12
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Abstract

Abstract A heat-curable adhesive lacquer is provided which comprises: (a) a polyurethane-ester-imide having (i) terminal isocyanate groups blocked by a monohydric phenol, and (ii) free hydroxyl groups and (b) an essentially linear epoxide or polyester resin having secondary hydroxyl groups and a molecular weight of above 30,000, the lacquer achieving, on drying, a B-state which is stable on storage such that the lacquer softens again when further heat is supplied to give a cross-linked resin in the C-state, which is heat stable.

Inventors

  • 👤 Hans Mosimann
  • 👤 Peter Heim
  • 👤 Charles Borer

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 11:51
CPC Classifications
H; H01; H01B; H01B3/00; H01B3/18; H01B3/30; H01B3/40; C; C08; C08G; C08G18/00; C08G18/06; C08G18/08; C08G18/10; C08G18/28; C08G18/40; C08G18/58; C08G18/64; C08G18/6415; C08G18/6438; C08G59/00; C08G59/18; C08G59/40; C08G59/4007; C08G59/4014; C08G59/4028; C08L; C08L63/00; H01B3/302; H01B3/303; H01B3/306; Y; Y10; Y10S; Y10S525/00; Y10S525/93

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 183 words
A heat-curable adhesive lacquer for coating electrically insulated wires consisting essentially of: 1. a polyurethane-ester-imide having terminal isocyanate groups blocked by a monohydric phenol, said polyurethane-ester-imide being derived from (A) an ester-imide containing hydroxyl groups obtained from a dicarboxylic acid of the formula: ##SPC6## and a polyalcohol of the formula: HOCH.sub.2 --CH.sub.2 --O--CH.sub.2 --CH.sub.2 --O--CH.sub.2 --CH.sub.2 OH (b.sub.1) and of the formula: ##SPC7## in the molar ratios: a : (b 1 + b 2 ) = 1 : 1.2 to 1 : 2 b 1 : b 2 = 1 : 1 to 10 : 1 and (B) a polyisocyanate of the formula: ##SPC8## ##SPC9## or a mixture of two or more thereof and the ratio of the hydroxyl groups to the isocyanate groups is from 1 : 1 to 1 : 1.5 and 2. an essentially linear epoxide resin having secondary hydroxyl groups and a molecular weight of at least 30,000, the lacquer, on drying, being a storage-stable at room temperature and being in a non-adhesive state such that the lacquer softens on further heating to give a thermoset, adhesive, heat-stable resin.
Claim 2
Dependent Claim 183 words
A heat-curable adhesive lacquer for coating electrically insulated wires consisting essentially of: 1. a polyurethane-ester-imide having terminal isocyanate groups blocked by a monohydric phenol, said polyurethane-ester-imide being derived from (A) an ester-imide containing hydroxyl groups obtained from a dicarboxylic acid of the formula: ##SPC6## and a polyalcohol of the formula: HOCH.sub.2 --CH.sub.2 --O--CH.sub.2 --CH.sub.2 --O--CH.sub.2 --CH.sub.2 OH (b.sub.1) and of the formula: ##SPC7## in the molar ratios: a : (b 1 + b 2 ) = 1 : 1.2 to 1 : 2 b 1 : b 2 = 1 : 1 to 10 : 1 and (B) a polyisocyanate of the formula: ##SPC8## ##SPC9## or a mixture of two or more thereof and the ratio of the hydroxyl groups to the isocyanate groups is from 1 : 1 to 1 : 1.5 and 2. an essentially linear epoxide resin having secondary hydroxyl groups and a molecular weight of at least 30,000, the lacquer, on drying, being a storage-stable at room temperature and being in a non-adhesive state such that the lacquer softens on further heating to give a thermoset, adhesive, heat-stable resin.
Claim 3
Dependent Claim 20 words
A lacquer according to claim 1 in which the epoxide resin is a condensation product of bisphenol A and epichlorohydrin.
Claim 4
Dependent Claim 18 words
A lacquer according to claim 1 in which the monohydric phenol is phenol, a cresol or a xylenol.
Claim 5
Dependent Claim 42 words
A lacquer according to claim 1 which comprises as a solvent, the monohydric phenol, in excess over the minimum proportion necessary for blocking the isocyanate groups, or a different organic solvent, or a mixture of said monohydric phenol and said organic solvent.
Claim 6
Dependent Claim 27 words
A lacquer according to claim 4 wherein the organic solvent is a hydrocarbon, a carboxylic acid ester, a ketone, dimethylformamide, dimethylacetamide or N-methylpyrrolidone or a mixture thereof.
Claim 7
Dependent Claim 20 words
A lacquer according to claim 1 wherein the proportion of epoxide resin is 80% or more based on solids present.

References Cited (Backward Citations)

US3177090A Cited
US3395118A Cited
US3311527A Cited
US3320090A Cited
US3384679A Cited
US3504627A Cited
US3714289A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-06-01 1979-12-01 1980-06-01 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-06-01 1983-12-01 1984-06-01 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-06-01 1987-12-01 1988-06-01 $7700.00 Window Closed / Lapsed

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