Pressure-sensitive recording materials

Claim 2

A pressure-recording process in which a methine dye is produced by bringing image-wise into reactive contact with the aid of pressure an acid compound having a pKa of about 2-5 with a dye precursor compound corresponding to the following general formula and capable of reacting with said acid compound to form a methine dye: ##EQU11## wherein: R 1 represents an alkoxy substituted phenyl group, an indolyl group, a thienyl group, a carbazolyl group or a pyrrolyl group, R 2 represents an alkoxy substituted aryl group, an indolyl group, a thienyl group, a carbazolyl group or a pyrrolyl group, R 3 represents hydroxyl, alkoxy, or ##EQU12## wherein each of R 8 and R 9 (same or different) represents hydrogen or an alkyl group or R 8 and R 9 together represent the necessary atoms to close a N-morpholinyl nucleus or N-piperidyl nucleus, each of R 4 and R 5 represents hydrogen, or R 4 represents phenyl and R 5 hydrogen, and n is 0 or 1.

Claim 3

A pressure recording process according to claim 1, wherein R 1 and/or R 2 represent a methoxysubstituted phenyl group.

Claim 4

A pressure recording process according to claim 1, wherein the thienyl group is substituted with a N-morpholinyl group.

Claim 5

A pressure-recording process according to claim 1, wherein the dye precursor compound and acid compound are present on separate support sheets and one of them is transferred by pressure from its support into reactive contact with the compound on the other sheet.

Claim 6

A pressure-recording process according to claim 1, wherein the dye precursor compound and acid compound are used in an integral copy-sheet containing on a same support the compound reacting as an acid out of direct chemical contact from the dye precursor compound but in such conditions that reactive contact can be effected through pressure.

Claim 7

A pressure-recording process according to claim 1, wherein at least one of the reactants is kept out of direct chemical contact from the other reactant by enveloping it in capsules or droplets from which the reactant is set free by pressure applied in an image.

Claim 8

A pressure-recoding process according to claim 1, wherein the dye precursor compound is applied to a support in a first hydrophilic binder layer and said first layer is coated with a second layer containing acid-treated clay in another hydrophilic binder shielding the acid clay from direct chemical contact with the dye precursor compound.

Claim 9

A pressure-recording process according to claim 1, wherein the material containing said dye precursor compound is present in a layer coated from a composition prepared by a method including the steps of: 1. dispersing oil droplets in an aqueous solution of a precipitable hydrophilic colloid, 2. adding a dyestuff that can be converted into the dye precursor compound, 3. adding a base to the obtained mixture in a sufficient amount to convert the dyestuff to the corresponding dye precursor compound, and 4. adding aluminum nitrate as precipitating agent to the obtained mixture in order to cause precipitation of the hydrophilic colloid.

Claim 10

A pressure-recording process according to claim 1, wherein the dye precursor compound and acid compound are present in a multiple-sheet pressure-sensitive recording material pack in which one reactant is contained in a coloring coating on the rear side of a first sheet that is writable on the front side and the corresponding co-reactant is provided in a receiving coating on the front side of a further sheet in contact with the rear side of the first sheet, said sheets being separatable from each other and containing the reactants in such condition that the contact of the sheets in the absence of pressure does not allow the formation of color.

Claim 11

A pressure-recording process according to claim 9, wherein the multiple sheet material is in the form of a manifold paper back in which the top sheet has said coloring coating at its rear side; at least one intermediate sheet has said receiving coating on its front side and said coloring coating at its rear side and the third sheet contains said receiving coating at the front side, but has no coating at its rear side.

Claim 12

A pressure-recording material being an integral copysheet containing on a same support an acid compound having a pKa of about 2-5 out of direct-chemical contact from a dye precursor compound but in such conditions that reactive contact can be effected through pressure, wherein said dye precursor compound corresponds to the following general formula: ##EQU13## wherein: R 1 represents an alkoxy substituted phenyl group, an indolyl group, a thienyl group, a carbazolyl group or a pyrrolyl group, R 2 represents an alkoxy substituted aryl group, an indolyl group, a thienyl group, a carbazolyl group or a pyrrolyl group, R 3 represents hydroxyl, alkoxy, or ##EQU14## wherein each of R 8 and R 9 (same or different) represents hydrogen or an alkyl group or R 8 and R 9 together represent the necessary atoms to close a N-morpholinyl nucleus or N-piperidyl nucleus, each of R 4 and R 5 represents hydrogen, or R 4 represents phenyl and R 5 hydrogen, and n is 0 or 1.

Claim 13

A pressure-recording material being an integral copysheet containing on a same support an acid compound having a pKa of about 2-5 out of direct-chemical contact from a dye precursor compound but in such conditions that reactive contact can be effected through pressure, wherein said dye precursor compound corresponds to the following general formula: ##EQU13## wherein: R 1 represents an alkoxy substituted phenyl group, an indolyl group, a thienyl group, a carbazolyl group or a pyrrolyl group, R 2 represents an alkoxy substituted aryl group, an indolyl group, a thienyl group, a carbazolyl group or a pyrrolyl group, R 3 represents hydroxyl, alkoxy, or ##EQU14## wherein each of R 8 and R 9 (same or different) represents hydrogen or an alkyl group or R 8 and R 9 together represent the necessary atoms to close a N-morpholinyl nucleus or N-piperidyl nucleus, each of R 4 and R 5 represents hydrogen, or R 4 represents phenyl and R 5 hydrogen, and n is 0 or 1.

Claim 14

A pressure-recording material according to claim 11, wherein R 1 and/or R 2 represent a methoxysubstituted phenyl group.

Claim 15

A pressure-recording material according to claim 11, wherein at least one of the reactants is kept out of direct chemical contact from the other reactant in capsules or droplets, from which it can be set free by pressure applied in the form of information.

Claim 16

A pressure-recording material according to claim 11, wherein the capsules or droplets are dispersed within the paper sheet itself or in a binder containing the second reactant in dispersed or dissolved form.

Claim 17

A pressure-recording material according to claim 11, wherein the acid compound is in solid particle form.

Claim 18

A pressure-recording material according to claim 15, wherein the solid acidic particles are distributed in an organic film-forming hydrophilic colloid substance insulating said particles from direct chemical contact with the dye precursor compound.

Claim 19

A pressure-recording material according to claim 11, wherein the dye precursor compound is applied to a support in a first hydrophilic binder layer and said first layer is coated with a second layer containing acid-treated clay in another hydrophilic binder shielding the acid clay from direct chemical contact with the dye precursor compound.

Claim 20

A pressure-recording material according to claim 11, being a multiple-sheet pressure-sensitive material in the form of a manifold paper pack in which the top sheet has said coloring coating at the rear side, at least one intermediate sheet has said receiving coating on its front side and said coloring coating at the rear side and the bottom sheet contains said receiving coating at the fron side, but has no coating on the rear side, wherein the coloring coating in said manifold paper pack contains said dye precursor compound and the receiving coating contains said acid compound.

Claim 21

A pressure-recording material according to claim 11, wherein said material is a multiple sheet pressure-sensitive recording material pack in which one reactant is contained in a coloring coating on the rear side of a first sheet that is writable on the front side and the corresponding co-reactant is provided in a receiving coating on the front side of a further sheet being in contact with the rear side of the first sheet, said sheets being separatable from each other and containing the reactants in such conditions that the contact of the sheets in the absence of pressure does not allow the formation of color.