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US3954901A Expired / Lapsed US ⏱️ 0.0 years remaining

Polyester resin composition

Assignee: Nippon Ester Co Ltd
•
Filing: 1974-01-09
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Granted: 1976-05-04
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Expires: 1994-01-09
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Abstract

Abstract A polyester resin composition obtained by mixing a molten polyester having an average degree of polymerization ranging from about 5 to 50 mainly comprising a terephthalic acid unit, a p-hydroxybenzoic acid unit and an ethylene glycol unit, and one hardener selected from the group consisting of a diglycidyl compound, hexaalkoxymethylmelamine or the condensate thereof, and a blocked isocyanate, with the composition being suitable for the preparation of a powder paint. The thus produced polyester resin composition can be finely pulverized with ease, shows no blocking property, facilitates pigmentation and provides beautiful coatings excellent in weather resistance, solvent resistance, humidity resistance, antifouling property, and with intimate adhesiveness to metal.

Inventors

  • 👤 Toru Watanabe
  • 👤 Rinzo Ohno
  • 👤 Takashige Kato
  • 👤 Singo Sasaki
  • 👤 Kunio Tsukamoto

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 22:22
CPC Classifications
C; C09; C09D; C09D167/00; C09D167/04; C08; C08G; C08G18/00; C08G18/06; C08G18/70; C08G18/72; C08G18/80; C08G18/8061; C08G18/807; C08G63/00; C08G63/02; C08G63/60; C09D163/00; C08G2150/00; C08G2150/20

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 213 words
A polyester resin composition for a powder paint, which is obtained by mixing a molten polyester having an average degree of polymerization ranging from about 5 to 50 and a hexaalkoxymethylmelamine or a condensate thereof as a hardener, said polyester being prepared by depolymerizing a highly polymerized polyester having an intrinsic viscosity of not less than 0.4 using a substantially non-volatile alcohol and/or a substantially non-volatile ester, said non-volatile alcohol or ester being non-volatile at about 200°-280°C, said substantially non-volatile alcohol being a polyhydric alcohol having 3 or more hydroxy groups, and said substantially non-volatile ester being the esterification product between said non-volatile polyhydric alcohol and an aliphatic monocarboxylic acid having at least one alcoholic hydroxy group in its molecule, or bis-β-hydroxyethyl terephthalate and/or β-hydroxyethyl p-hydroxyethoxybenzoate, and having as the main acid units, about 40 to 80 mol% of terephthalic acid units, about 20 to 60 mol% of p-hydroxybenzoic acid units and about 0 to 30 mol% of aliphatic dicarboxylic acid units and, as the main alcohol units, ethylene glycol units, and having free hydroxy and/or carboxy groups wherein the amount of said hexaalkoxymethylmelamine or the condensate thereof satisfies the following relationship; ##EQU6## wherein M and H represent, respectively, the alkoxy group equivalents and the hydroxy group equivalents of said polyester resin composition.
Claim 2
Dependent Claim 213 words
A polyester resin composition for a powder paint, which is obtained by mixing a molten polyester having an average degree of polymerization ranging from about 5 to 50 and a hexaalkoxymethylmelamine or a condensate thereof as a hardener, said polyester being prepared by depolymerizing a highly polymerized polyester having an intrinsic viscosity of not less than 0.4 using a substantially non-volatile alcohol and/or a substantially non-volatile ester, said non-volatile alcohol or ester being non-volatile at about 200°-280°C, said substantially non-volatile alcohol being a polyhydric alcohol having 3 or more hydroxy groups, and said substantially non-volatile ester being the esterification product between said non-volatile polyhydric alcohol and an aliphatic monocarboxylic acid having at least one alcoholic hydroxy group in its molecule, or bis-β-hydroxyethyl terephthalate and/or β-hydroxyethyl p-hydroxyethoxybenzoate, and having as the main acid units, about 40 to 80 mol% of terephthalic acid units, about 20 to 60 mol% of p-hydroxybenzoic acid units and about 0 to 30 mol% of aliphatic dicarboxylic acid units and, as the main alcohol units, ethylene glycol units, and having free hydroxy and/or carboxy groups wherein the amount of said hexaalkoxymethylmelamine or the condensate thereof satisfies the following relationship; ##EQU6## wherein M and H represent, respectively, the alkoxy group equivalents and the hydroxy group equivalents of said polyester resin composition.
Claim 3
Dependent Claim 31 words
The polyester resin composition for a powder paint as described in claim 1, wherein said polyester is a polyester having a terminal carboxyl group content ranging from 50 to 200 g.eq./ton.
Claim 4
Dependent Claim 46 words
The polyester resin composition for a powder paint as described in claim 2, wherein the terminal carboxyl group content of said polyester is obtained by mixing a molten polyester, obtained by adding a polycarboxylic anhydride to the hydroxy groups contained therein, and a polycarboxylic anhydride-free polyester.
Claim 5
Dependent Claim 37 words
The polyester resin composition for a powder paint as described in claim 2, wherein said hexaalkoxymethylmelamine is represented by the following structural formula; ##EQU7## wherein R represents an alkyl group having not more than 6 carbon atoms.
Claim 6
Dependent Claim 23 words
The polyester resin composition for a powder paint as described in claim 1, wherein said hardener is mixed at temperatures less than 150°C.

References Cited (Backward Citations)

US3370037A Cited
US3515696A Cited
US3463760A Cited
US3502620A Cited
US3624232A Cited
US3759854A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-05-04 1979-11-03 1980-05-04 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-05-04 1983-11-03 1984-05-04 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-05-04 1987-11-03 1988-05-04 $7700.00 Window Closed / Lapsed

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