Patent US3954708A successfully refreshed from Google Patents.
US3954708A
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Synthetic polymers stabilized with a nickel benzoate and a polyol
Assignee: Novartis Corp
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Filing: 1974-12-12
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Granted: 1976-05-04
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Expires: 1994-12-12
Abstract
Abstract A new composition of nickel salts of hydroxybenzoic acids and polyols are used as stabilisers of polymers.
Inventors
- 👤 Michael Rasberger
- 👤 Jean Rody
- 👤 Paul Moser
- 👤 Helmut Mueller
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 13:07
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/0091
Claims Analysis
Total Claims: 14
Claim 1
Independent Claim
201 words
A composition of matter stabilised against thermal and light degradation and discoloration which comprises a polymonoolefin and a mixture of A. a nickel benzoate of the formula ##SPC3## wherein R 1 denotes hydrogen or alkyl with 1 to 5 carbon atoms, of the substituents R 2 and R 3 , one denotes an alkyl with 3 to 8 carbon atoms and the other denotes --COO - and n denotes a value of 0 to 2, B. a polyol of the formula ##EQU15## wherein R 11 denotes --CH 2 OR 12 and R 12 denotes alkyl with 1 to 18 carbon atoms or phenyl, such that the amount of components (A) and (B) is in the concentration of 0.01 to 5% by weight of the total composition and the molar ratio of A:B is in the range of 1:0.5 to 1:2, C. from 0.05 to 0.1% by weight of the total composition of a hindered phenol antioxidant selected from the group consisting of tetrakis β-(3,5-di-tert-butyl-4-hydroxyphenyl)propionic acid pentaerythritol ester and β-(3,5-di-tert-butyl-4-hydroxyphenyl)propionic acid n-octadecyl ester, and D. from 0 to 0.3% by weight of the total composition of an ester of β-thiodipropionic acid selected from the group consisting of dilauryl β-thiodipropionate and distearyl β-thiodipropionate.
Claim 2
Dependent Claim
201 words
A composition of matter stabilised against thermal and light degradation and discoloration which comprises a polymonoolefin and a mixture of A. a nickel benzoate of the formula ##SPC3## wherein R 1 denotes hydrogen or alkyl with 1 to 5 carbon atoms, of the substituents R 2 and R 3 , one denotes an alkyl with 3 to 8 carbon atoms and the other denotes --COO - and n denotes a value of 0 to 2, B. a polyol of the formula ##EQU15## wherein R 11 denotes --CH 2 OR 12 and R 12 denotes alkyl with 1 to 18 carbon atoms or phenyl, such that the amount of components (A) and (B) is in the concentration of 0.01 to 5% by weight of the total composition and the molar ratio of A:B is in the range of 1:0.5 to 1:2, C. from 0.05 to 0.1% by weight of the total composition of a hindered phenol antioxidant selected from the group consisting of tetrakis β-(3,5-di-tert-butyl-4-hydroxyphenyl)propionic acid pentaerythritol ester and β-(3,5-di-tert-butyl-4-hydroxyphenyl)propionic acid n-octadecyl ester, and D. from 0 to 0.3% by weight of the total composition of an ester of β-thiodipropionic acid selected from the group consisting of dilauryl β-thiodipropionate and distearyl β-thiodipropionate.
Claim 3
Dependent Claim
36 words
A composition according to claim 1 wherein the polyol (B) is of the formula ##EQU16## where R 11 denotes --CH 2 OR 12 and R 12 denotes alkyl with 1 to 12 carbon atoms or phenyl.
Claim 4
Dependent Claim
53 words
A composition according to claim 1 where the nickel benzoate (A) is ##SPC4## where n denotes a value from 0 to 2, and where the polyol (B) is of the formula ##EQU17## where R 11 denotes --CH 2 OR 12 where R 12 denotes alkyl with 1 to 12 carbon atoms or phenyl.
Claim 5
Dependent Claim
26 words
A composition according to claim 3 wherein the polyol (B) is of the formula ##EQU18## where R 12 denotes alkyl with 8 to 12 carbon atoms.
Claim 6
Dependent Claim
28 words
A composition according to claim 1 where the amount of components (A) and (B) is in the concentration of 0.05 to 1.5% by weight of the total composition.
Claim 7
Dependent Claim
28 words
A composition according to claim 1 where the amount of components (A) and (B) is in the concentration of 0.1 to 0.8% by weight of the total composition.
Claim 8
Dependent Claim
11 words
A composition according to claim 1 where the polymonoolefin is polypropylene.
Claim 9
Dependent Claim
13 words
A composition according to claim 1 where n denotes a value of 0.75.
Claim 10
Dependent Claim
16 words
A composition according to claim 3 where the glycol (B) is C.sub.12 H.sub.25 OCH.sub.2 CHOHCH.sub.2 OH.
Claim 11
Dependent Claim
16 words
A composition according to claim 3 where the glycol (B) is C.sub.8 H.sub.17 OCH.sub.2 CHOHCH.sub.2 OH.
Claim 12
Dependent Claim
185 words
a composition of matter stabilised against thermal and light degradation and discoloration which comprises a polymonoolefin and a mixture of A. a nickel benzoate of the formula ##SPC5## wherein R 1 denotes hydrogen or alkyl with 1 to 5 carbon atoms, of the substituents R 2 and R 3 one denotes an alkyl with 3 to 8 carbon atoms and the other denotes --COO - and n denotes a value of 0 to 2, B. a glycol of the formula CH.sub.3 CH.sub.2 (OCH.sub.2 CH.sub.2).sub.2 OCH.sub.2 CHOHCH.sub.2 OH, such that the amount of components (A) and (B) is in the concentration of 0.01 to 5% by weight of the total composition and the molar ratio of A:B is in the range of 1:05.5 to 1:2 C. from 0.05 to 0.1% by weight of the total composition of a hindered phenol antioxidant selected from the group consisting of tetrakis β-(3,5-di-tert-butyl-4-hydroxyphenyl)propionic acid pentaerythritol ester and β-(3,5-di-tert-butyl-4-hydroxyphenyl)propionic acid n-octadecyl ester, and D. from 0 to 0.3% by weight of the total composition of an ester of β-thiodipropionic acid selected from the group consisting of dilauryl β-thiodipropionate and distearyl β-thiodipropionate.
Claim 13
Dependent Claim
185 words
a composition of matter stabilised against thermal and light degradation and discoloration which comprises a polymonoolefin and a mixture of A. a nickel benzoate of the formula ##SPC5## wherein R 1 denotes hydrogen or alkyl with 1 to 5 carbon atoms, of the substituents R 2 and R 3 one denotes an alkyl with 3 to 8 carbon atoms and the other denotes --COO - and n denotes a value of 0 to 2, B. a glycol of the formula CH.sub.3 CH.sub.2 (OCH.sub.2 CH.sub.2).sub.2 OCH.sub.2 CHOHCH.sub.2 OH, such that the amount of components (A) and (B) is in the concentration of 0.01 to 5% by weight of the total composition and the molar ratio of A:B is in the range of 1:05.5 to 1:2 C. from 0.05 to 0.1% by weight of the total composition of a hindered phenol antioxidant selected from the group consisting of tetrakis β-(3,5-di-tert-butyl-4-hydroxyphenyl)propionic acid pentaerythritol ester and β-(3,5-di-tert-butyl-4-hydroxyphenyl)propionic acid n-octadecyl ester, and D. from 0 to 0.3% by weight of the total composition of an ester of β-thiodipropionic acid selected from the group consisting of dilauryl β-thiodipropionate and distearyl β-thiodipropionate.
Claim 14
Dependent Claim
22 words
A composition according to claim 11 wherein the nickel benzoate (A) is ##SPC6## where n denotes a value from 0 to 2.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1979-05-04 | 1979-11-03 | 1980-05-04 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1983-05-04 | 1983-11-03 | 1984-05-04 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1987-05-04 | 1987-11-03 | 1988-05-04 | $7700.00 | Window Closed / Lapsed |