Patent US3954677A successfully refreshed from Google Patents.
US3954677A
Expired / Lapsed
US
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Sulfonated aromatic-formaldehyde condensation products
Assignee: ChampionX LLC
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Filing: 1974-11-18
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Granted: 1976-05-04
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Expires: 1994-11-18
Abstract
Abstract Sulfonated aromatic-formaldehyde condensation products are prepared by reacting a sulfonated aromatic compound with formaldehyde to form a condensation product which is neutralized or rendered alkaline by the addition of an aqueous solution of sodium hydroxide and further reacted with a small amount of urea, usually around 0.5 to 1% by weight of the total mass in order to produce a product which can be employed as a dispersant for oil well cementing compositions and exhibits less retardant effect than a similar dispersant prepared without the addition of the urea.
Inventors
- 👤 Robert E. Law
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-24 22:33
CPC Classifications
C; C04; C04B; C04B24/00; C04B24/16; C04B24/20; C04B24/22; C09; C09K; C09K23/00; C09K23/12; C09K8/00; C09K8/42; C09K8/46
Claims Analysis
Total Claims: 6
Claim 1
Independent Claim
173 words
A process of preparing a water soluble dispersant which comprises adding urea to an aqueous solution of a water soluble sulfonate of a condensation product of formaldehyde and an aromatic sulfonic acid, and heating the resultant mixture, the quantity of urea being sufficient to enhance the effectiveness of said dispersant as an additive to disperse and reduce viscosity in oil well cementing compositions with less retardation in the setting of such cementing compositions as compared with the same compositions to which no urea has been added, said aromatic sulfonic acid being prepared by sulfonating an aromatic compound from the group consisting of alpha-naphthol, beta-naphthol, naphthalene, toluene, benzene, phenol, methyl, ethyl, isopropyl and butyl naphthalenes and alkylated benzenes containing 1-8 carbon atoms in the alkyl substituent groups, said aqueous solution of water soluble sulfonate being neutralized to a pH of 7 to 9, and heated with said urea for at least 2 hours at 70°C. to 90°C., the quantity of urea being within the range of 1 to 5% by weight of said sulfonate.
Claim 2
Dependent Claim
173 words
A process of preparing a water soluble dispersant which comprises adding urea to an aqueous solution of a water soluble sulfonate of a condensation product of formaldehyde and an aromatic sulfonic acid, and heating the resultant mixture, the quantity of urea being sufficient to enhance the effectiveness of said dispersant as an additive to disperse and reduce viscosity in oil well cementing compositions with less retardation in the setting of such cementing compositions as compared with the same compositions to which no urea has been added, said aromatic sulfonic acid being prepared by sulfonating an aromatic compound from the group consisting of alpha-naphthol, beta-naphthol, naphthalene, toluene, benzene, phenol, methyl, ethyl, isopropyl and butyl naphthalenes and alkylated benzenes containing 1-8 carbon atoms in the alkyl substituent groups, said aqueous solution of water soluble sulfonate being neutralized to a pH of 7 to 9, and heated with said urea for at least 2 hours at 70°C. to 90°C., the quantity of urea being within the range of 1 to 5% by weight of said sulfonate.
Claim 3
Dependent Claim
21 words
A process as claimed in claim 1 in which said aqueous solution contains 25 to 35% by weight of said sulfonate.
Claim 4
Dependent Claim
135 words
A process as claimed in claim 1 in which said water soluble sulfonate is a condensation product of formaldehyde reacted in aqueous solution with a beta-naphthol-sulfonic acid obtained by reacting beta-naphthol with concentrated sulfuric acid at 100°C. to 150°C. with subsequent cooling and addition of water, followed by addition of formaldehyde in a molar ratio of about 0.9 molr per mole of beta-naphthol sulfonic acid and condensation at 90°C. to 100°C., followed by neutralization to a pH of 8 to 9 with sodium hydroxide to produce a sodium sulfonate, followed by addition of 1% to 5% by weight urea based on said sulfonate and heating at 70°C. to 90°C., the amount of water added being such that the resultant aqueoous solution contains approximately 25 to 35% active urea treated beta-naphthol sulfonic acid-formaldehyde condensate sodium salt.
Claim 5
Dependent Claim
9 words
The product resulting from the process of claim 1.
Claim 6
Dependent Claim
9 words
The product resulting from the process of claim 3.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1979-05-04 | 1979-11-03 | 1980-05-04 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1983-05-04 | 1983-11-03 | 1984-05-04 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1987-05-04 | 1987-11-03 | 1988-05-04 | $7700.00 | Window Closed / Lapsed |