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US3948844A Expired / Lapsed US ⏱️ 0.0 years remaining

Copolyamides containing caprolactam, lauriclactam and 11-aminoundecanoic acid

Assignee: Plate Bonn GmbH
•
Filing: 1974-05-06
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Granted: 1976-04-06
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Expires: 1994-05-06
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Abstract

Abstract The invention relates to copolyamides containing caprolactam, lauriclactam and 11-aminoundecanoic acid, useful as heat sealing agents.

Inventors

  • 👤 Fritz Raabe
  • 👤 Eduard De Jong

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 13:03
CPC Classifications
C; C08; C08G; C08G69/00; C08G69/02; C08G69/36

Claims Analysis

Total Claims: 20
Claim 1
Independent Claim 88 words
A composition of matter comprising a copolyamide consisting essentially of recurring units of caprolactam, lauriclactam, 11-aminoundecanoic acid and a hexamethylene diamine salt of an aliphatic dicarboxylic acid corresponding to the formula HOOC--(CH.sub.2).sub.n --COOH (I) in which n is 4, 7, 8, 10 or 11, said units being incorporated in the copolyamide in the following proportions:caprolactam 20-40% by weightlauriclactam 20-35% by weight11-aminoundecanoic acid 15-35% by weighthexamethylene diamine salt ofthe acid of formula (I) 15-40% by weight and a plasticizer which is compatible with a suitable for plasticizing said copolyamide.
Claim 2
Dependent Claim 88 words
A composition of matter comprising a copolyamide consisting essentially of recurring units of caprolactam, lauriclactam, 11-aminoundecanoic acid and a hexamethylene diamine salt of an aliphatic dicarboxylic acid corresponding to the formula HOOC--(CH.sub.2).sub.n --COOH (I) in which n is 4, 7, 8, 10 or 11, said units being incorporated in the copolyamide in the following proportions:caprolactam 20-40% by weightlauriclactam 20-35% by weight11-aminoundecanoic acid 15-35% by weighthexamethylene diamine salt ofthe acid of formula (I) 15-40% by weight and a plasticizer which is compatible with a suitable for plasticizing said copolyamide.
Claim 3
Dependent Claim 44 words
The composition according to claim 1, wherein the units are incorporated in the copolyamide in the following proportions: caprolactam 25-35% by weight lauriclactam about 30% by weight 11-aminoundecanoic acid 18-25% by weight hexamethylene diamine salt of the acid of formula (I) 15-30% by weight.
Claim 4
Dependent Claim 47 words
The composition according to claim 1, wherein the units are incorporated in the copolyamide in the following proportions: caprolactam about 30% by weight lauriclactam about 30% by weight 11-aminoundecanoic acid about 20% by weight hexamethylene diamine salt of the acid of formula (I) about 20% by weight.
Claim 5
Dependent Claim 20 words
The composition according to claim 1, wherein n in formula (I) stands for the number 4, 7, 8 or 10.
Claim 6
Dependent Claim 15 words
The composition according to claim 4, wherein n in formula (I) is 7 or 8.
Claim 7
Dependent Claim 101 words
A process for the production of a heat bonding composition comprising the steps of polymerizing caprolactam, lauriclactam, 11-aminoundecanoic acid and hexamethylene diamine salt of an aliphatic dicarboxylic acid corresponding to the formula HOOC--(CH.sub.2).sub.n --COOH (I) in which n is 4, 7, 8, 10 or 11, under pressure at elevated temperature in the following quantitative proportions: caprolactam 20-40% by weight lauriclactam 20-35% by weight 11-aminoundecanoic acid 15-35% by weight hexamethylene diamine salt of the acid of formula (I) 15-40% by weight thereby forming a copolyamide, and incorporating a plasticizer into said copolyamide which is compatible with and suitable for plasticizing said copolyamide.
Claim 8
Dependent Claim 101 words
A process for the production of a heat bonding composition comprising the steps of polymerizing caprolactam, lauriclactam, 11-aminoundecanoic acid and hexamethylene diamine salt of an aliphatic dicarboxylic acid corresponding to the formula HOOC--(CH.sub.2).sub.n --COOH (I) in which n is 4, 7, 8, 10 or 11, under pressure at elevated temperature in the following quantitative proportions: caprolactam 20-40% by weight lauriclactam 20-35% by weight 11-aminoundecanoic acid 15-35% by weight hexamethylene diamine salt of the acid of formula (I) 15-40% by weight thereby forming a copolyamide, and incorporating a plasticizer into said copolyamide which is compatible with and suitable for plasticizing said copolyamide.
Claim 9
Dependent Claim 43 words
A process according to claim 6, wherein the basic units are polymerised in the following quantitative proportions: caprolactam 25-35% by weight lauriclactam about 30% by weight 11-aminoundecanoic acid 18-25% by weight hexamethylene diamine salt 15-30% by weight of the acid of formula (I).
Claim 10
Dependent Claim 45 words
A process according to claim 6, wherein the basic units are polymerised in the following quantitiative proportions: caprolactam about 30% by weight lauriclactam about 30% by weight 11-aminoundecanoic acid about 20% by weight hexamethylene diamine salt of the acid of formula (I) 20% by weight.
Claim 11
Dependent Claim 20 words
A process according to claim 6 wherein n in formula (I) stands for the number 4, 7, 8 or 10.
Claim 12
Dependent Claim 18 words
A process according to claim 9 wherein n in formula (I) stands for the number 7 or 8.
Claim 13
Dependent Claim 27 words
A process according to claim 6 wherein polymerisation is carried out at a temperature of 280° to 300°C under a pressure of from 10 to 50 atms.
Claim 14
Dependent Claim 23 words
A process according to claim 6 wherein after-condensation is carried out for 1 to 3 hours under normal pressure at 250° to 300°C.
Claim 15
Dependent Claim 27 words
The composition of matter as defined by claim 1, wherein said plasticizer is present in an amount up to about 50% by weight of the total composition.
Claim 16
Dependent Claim 27 words
The composition of matter as defined by claim 13, wherein said plasticizer is present in an amount up to about 25% by weight of the total composition.
Claim 17
Dependent Claim 56 words
The composition of matter as defined by claim 1, wherein said plasticizer is selected from the group consisting of a sulfonic acid derivative of the formula ##SPC2## wherein R 1 is hydrogen or methyl and R 2 is hydrogen, lower alkyl or cyclohexyl; a phenol carboxylic acid; a phenol carboxylic acid alkyl ester and bisphenol A.
Claim 18
Dependent Claim 39 words
The composition of matter as defined by claim 15, wherein said plasticizer is selected from the group consisting of benzene sulfonic acid ethyl amide, toluene sulfonic acid ethyl amide, butyl-p-hydroxy benzoate, lauryl-p-hydroxy-benzoate, p-oxy-benzoic acid, octyl-p-oxy benzoate and bisphenol A.
Claim 19
Dependent Claim 14 words
The composition of matter as defined by claim 1, further comprising an aqueous dispersant.
Claim 20
Dependent Claim 16 words
The composition of matter as defined by claim 17, further comprising a thickener and a stabilizer.

References Cited (Backward Citations)

US3378532A Cited
US3355409A Cited
US3515702A Cited
US3756997A Cited
US3784495A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-04-06 1979-10-06 1980-04-06 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-04-06 1983-10-06 1984-04-06 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-04-06 1987-10-06 1988-04-06 $7700.00 Window Closed / Lapsed

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