US3948844A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Copolyamides containing caprolactam, lauriclactam and 11-aminoundecanoic acid
Assignee: Plate Bonn GmbH
•
Filing: 1974-05-06
•
Granted: 1976-04-06
•
Expires: 1994-05-06
Abstract
Abstract The invention relates to copolyamides containing caprolactam, lauriclactam and 11-aminoundecanoic acid, useful as heat sealing agents.
Inventors
- 👤 Fritz Raabe
- 👤 Eduard De Jong
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 07:27
CPC Classifications
C; C08; C08G; C08G69/00; C08G69/02; C08G69/36
Claims Analysis
Total Claims: 20
Claim 1
Independent Claim
88 words
A composition of matter comprising a copolyamide consisting essentially of recurring units of caprolactam, lauriclactam, 11-aminoundecanoic acid and a hexamethylene diamine salt of an aliphatic dicarboxylic acid corresponding to the formula HOOC--(CH.sub.2).sub.n --COOH (I) in which n is 4, 7, 8, 10 or 11, said units being incorporated in the copolyamide in the following proportions:caprolactam 20-40% by weightlauriclactam 20-35% by weight11-aminoundecanoic acid 15-35% by weighthexamethylene diamine salt ofthe acid of formula (I) 15-40% by weight and a plasticizer which is compatible with a suitable for plasticizing said copolyamide.
Claim 2
Dependent Claim
88 words
A composition of matter comprising a copolyamide consisting essentially of recurring units of caprolactam, lauriclactam, 11-aminoundecanoic acid and a hexamethylene diamine salt of an aliphatic dicarboxylic acid corresponding to the formula HOOC--(CH.sub.2).sub.n --COOH (I) in which n is 4, 7, 8, 10 or 11, said units being incorporated in the copolyamide in the following proportions:caprolactam 20-40% by weightlauriclactam 20-35% by weight11-aminoundecanoic acid 15-35% by weighthexamethylene diamine salt ofthe acid of formula (I) 15-40% by weight and a plasticizer which is compatible with a suitable for plasticizing said copolyamide.
Claim 3
Dependent Claim
44 words
The composition according to claim 1, wherein the units are incorporated in the copolyamide in the following proportions: caprolactam 25-35% by weight
lauriclactam about 30% by weight
11-aminoundecanoic acid
18-25% by weight
hexamethylene diamine salt
of the acid of formula (I)
15-30% by weight.
Claim 4
Dependent Claim
47 words
The composition according to claim 1, wherein the units are incorporated in the copolyamide in the following proportions: caprolactam about 30% by weight
lauriclactam about 30% by weight
11-aminoundecanoic acid
about 20% by weight
hexamethylene diamine salt
of the acid of formula (I)
about 20% by weight.
Claim 5
Dependent Claim
20 words
The composition according to claim 1, wherein n in formula (I) stands for the number 4, 7, 8 or 10.
Claim 6
Dependent Claim
15 words
The composition according to claim 4, wherein n in formula (I) is 7 or 8.
Claim 7
Dependent Claim
101 words
A process for the production of a heat bonding composition comprising the steps of polymerizing caprolactam, lauriclactam, 11-aminoundecanoic acid and hexamethylene diamine salt of an aliphatic dicarboxylic acid corresponding to the formula HOOC--(CH.sub.2).sub.n --COOH (I) in which n is 4, 7, 8, 10 or 11, under pressure at elevated temperature in the following quantitative proportions: caprolactam 20-40% by weight
lauriclactam 20-35% by weight
11-aminoundecanoic acid
15-35% by weight
hexamethylene diamine salt of
the acid of formula (I)
15-40% by weight thereby forming a copolyamide, and incorporating a plasticizer into said copolyamide which is compatible with and suitable for plasticizing said copolyamide.
Claim 8
Dependent Claim
101 words
A process for the production of a heat bonding composition comprising the steps of polymerizing caprolactam, lauriclactam, 11-aminoundecanoic acid and hexamethylene diamine salt of an aliphatic dicarboxylic acid corresponding to the formula HOOC--(CH.sub.2).sub.n --COOH (I) in which n is 4, 7, 8, 10 or 11, under pressure at elevated temperature in the following quantitative proportions: caprolactam 20-40% by weight
lauriclactam 20-35% by weight
11-aminoundecanoic acid
15-35% by weight
hexamethylene diamine salt of
the acid of formula (I)
15-40% by weight thereby forming a copolyamide, and incorporating a plasticizer into said copolyamide which is compatible with and suitable for plasticizing said copolyamide.
Claim 9
Dependent Claim
43 words
A process according to claim 6, wherein the basic units are polymerised in the following quantitative proportions: caprolactam 25-35% by weight
lauriclactam about 30% by weight
11-aminoundecanoic acid
18-25% by weight
hexamethylene diamine salt
15-30% by weight
of the acid of formula (I).
Claim 10
Dependent Claim
45 words
A process according to claim 6, wherein the basic units are polymerised in the following quantitiative proportions: caprolactam about 30% by weight
lauriclactam about 30% by weight
11-aminoundecanoic acid
about 20% by weight
hexamethylene diamine salt
of the acid of formula (I)
20% by weight.
Claim 11
Dependent Claim
20 words
A process according to claim 6 wherein n in formula (I) stands for the number 4, 7, 8 or 10.
Claim 12
Dependent Claim
18 words
A process according to claim 9 wherein n in formula (I) stands for the number 7 or 8.
Claim 13
Dependent Claim
27 words
A process according to claim 6 wherein polymerisation is carried out at a temperature of 280° to 300°C under a pressure of from 10 to 50 atms.
Claim 14
Dependent Claim
23 words
A process according to claim 6 wherein after-condensation is carried out for 1 to 3 hours under normal pressure at 250° to 300°C.
Claim 15
Dependent Claim
27 words
The composition of matter as defined by claim 1, wherein said plasticizer is present in an amount up to about 50% by weight of the total composition.
Claim 16
Dependent Claim
27 words
The composition of matter as defined by claim 13, wherein said plasticizer is present in an amount up to about 25% by weight of the total composition.
Claim 17
Dependent Claim
56 words
The composition of matter as defined by claim 1, wherein said plasticizer is selected from the group consisting of a sulfonic acid derivative of the formula ##SPC2## wherein R 1 is hydrogen or methyl and R 2 is hydrogen, lower alkyl or cyclohexyl; a phenol carboxylic acid; a phenol carboxylic acid alkyl ester and bisphenol A.
Claim 18
Dependent Claim
39 words
The composition of matter as defined by claim 15, wherein said plasticizer is selected from the group consisting of benzene sulfonic acid ethyl amide, toluene sulfonic acid ethyl amide, butyl-p-hydroxy benzoate, lauryl-p-hydroxy-benzoate, p-oxy-benzoic acid, octyl-p-oxy benzoate and bisphenol A.
Claim 19
Dependent Claim
14 words
The composition of matter as defined by claim 1, further comprising an aqueous dispersant.
Claim 20
Dependent Claim
16 words
The composition of matter as defined by claim 17, further comprising a thickener and a stabilizer.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1979-04-06 | 1979-10-06 | 1980-04-06 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1983-04-06 | 1983-10-06 | 1984-04-06 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1987-04-06 | 1987-10-06 | 1988-04-06 | $7700.00 | Window Closed / Lapsed |