US3948600A
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Selected ammonium sulfonate catalysts for an improved process utilizing mild curing conditions in durable press finishing of cellulose-containing fabrics
Abstract In mild cure finishing, strong catalysts are required because of the modest curing conditions employed in the process. Suitable catalysts for mild cure finishing include strong inorganic acids, strong organic acids, active inorganic complexes, salt/acid combinations, and salts that are strong Lewis acids (i.e, certain metal salts). Ammonium salts of inorganic acids, although often used in other types of treatments for producing wrinkle resistant textiles, are not satisfactory catalysts for mild cure finishing. Unexpectedly and surprisingly, it has been discovered that ammonium salts of certain, but not all, sulfonic acids can serve as effective catalysts for mild cure finishing of cellulose-containing fabrics to produce wrinkle resistance and durable press properties. Among ammonium sulfonates which provide the catalysis needed for mild cure finishing are ammonium methanesulfonate, ammonium carboxymethanesulfonate (NH4O3SCH2COOH), ammonium benzenesulfonate, and ammonium p-toluenesulfonate.
In a mild cure finishing process for producing durable press textile fabrics that are composed of at least 50% of a cellulosic fiber whereby the textiles are impregnated with an aqueous solution containing an N-methylolamide crosslinking agent and a strongly acidic catalyst, curing said textile, without pre-drying, at a temperature of about 60°C to 105°C to reduce moisture content of the finished textile to about 2 to 5%, the improvement characterized by using as catalyst an ammonium sulfonate salt selected from the group consisting of: ammonium methanesulfonate; ammonium carboxymethanesulfonate (NH 4 O 3 SCH 2 COOH), ammonium benzenesulfonate, and ammonium p-toluenesulfonate.
Claim 2
Dependent Claim
101 words
In a mild cure finishing process for producing durable press textile fabrics that are composed of at least 50% of a cellulosic fiber whereby the textiles are impregnated with an aqueous solution containing an N-methylolamide crosslinking agent and a strongly acidic catalyst, curing said textile, without pre-drying, at a temperature of about 60°C to 105°C to reduce moisture content of the finished textile to about 2 to 5%, the improvement characterized by using as catalyst an ammonium sulfonate salt selected from the group consisting of: ammonium methanesulfonate; ammonium carboxymethanesulfonate (NH 4 O 3 SCH 2 COOH), ammonium benzenesulfonate, and ammonium p-toluenesulfonate.
Claim 3
Dependent Claim
13 words
The improvement as characterized in claim 1 wherein the catalyst is ammonium methanesulfonate.
Claim 4
Dependent Claim
13 words
The improvement as characterized in claim 1 wherein the catalyst is ammonium carboxymethanesulfonate.
Claim 5
Dependent Claim
13 words
The improvement as characterized in claim 1 wherein the catalyst is ammonium benzenesulfonate.
Claim 6
Dependent Claim
13 words
The improvement as characterized by claim 1 wherein the catalyst is ammonium p-toluenesulfonate.