Patent US2706803A successfully refreshed from Google Patents.
Patent US3945957A successfully refreshed from Google Patents.
US3945957A
Expired / Lapsed
US
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Dry planographic printing ink composition
Assignee: Dai Nippon Printing Co Ltd
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Filing: 1974-10-18
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Granted: 1976-03-23
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Expires: 1994-10-18
Abstract
Abstract A dry planographic printing ink composition which comprises a vehicle for an ink, a pigment and a solvent, characterized by using as a portion of the vehicle 1 to 40% by weight of silicone modified alkyd resin containing 5 to 50% by weight of organopolysiloxanes represented by the average composition formula: ##EQU1## WHEREIN R 1 stands for a mono-valent unsubstituted hydrocarbon group containing 1 to 4 carbon atoms, R 2 stands for a hydrogen atom or mono-valent hydrocarbon group containing 1 to 4 carbon atoms, n is an integer of 1.0 to 2.0, m is an integer of 0.1 to 2.5, but n + m is less than 4. The ink composition is a very favorable dry planographic printing ink composition having a practicable printing adaptability.
Inventors
- 👤 Atsumi Noshiro
- 👤 Yoshio Inoue
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 17:17
CPC Classifications
C; C08; C08L; C08L67/00; C08G; C08G77/00; C08G77/42; C08G77/445; C09; C09D; C09D11/00; C09D11/02; C09D11/10; C09D11/102; C09D11/104; C09D11/105
Claims Analysis
Total Claims: 19
Claim 1
Independent Claim
166 words
A dry planographic printing ink composition which comprises a vehicle for an ink, a pigment and a solvent, characterized by using as a portion of the vehicle 1 to 40% by weight of a silicone modified alkyd resin containing 5 to 50% by weight of an organopolysiloxane represented by the average composition formula: ##EQU5## wherein R 1 is a monovalent unsubstituted hydrocarbon group having 1 to 4 carbon atoms, R 2 is a hydrogen atom or a monovalent hydrocarbon group having 1 to 4 carbon atoms, n is an integer of 1.0 to 2.0, and m is an integer of 0.1 to 2.5, n+m being less than 4, said vehicle being selected from the group consisting of drying oil, synthetic drying oil, rosin, copal, dammer, shellac, hardened rosin, rosin esters, phenolic resins, rosin-modified phenolic resins, maleic acid resins, alkyd resins, petroleum resins, vinyl resins, polyamide resins, epoxy resins, aminoalkyd resins, polyurethane resins, aminoplast resins, nitrocellulose, ethyl cellulose, chlorinated rubber, cyclized rubber, glue, casein, dextrin and zein.
Claim 2
Dependent Claim
166 words
A dry planographic printing ink composition which comprises a vehicle for an ink, a pigment and a solvent, characterized by using as a portion of the vehicle 1 to 40% by weight of a silicone modified alkyd resin containing 5 to 50% by weight of an organopolysiloxane represented by the average composition formula: ##EQU5## wherein R 1 is a monovalent unsubstituted hydrocarbon group having 1 to 4 carbon atoms, R 2 is a hydrogen atom or a monovalent hydrocarbon group having 1 to 4 carbon atoms, n is an integer of 1.0 to 2.0, and m is an integer of 0.1 to 2.5, n+m being less than 4, said vehicle being selected from the group consisting of drying oil, synthetic drying oil, rosin, copal, dammer, shellac, hardened rosin, rosin esters, phenolic resins, rosin-modified phenolic resins, maleic acid resins, alkyd resins, petroleum resins, vinyl resins, polyamide resins, epoxy resins, aminoalkyd resins, polyurethane resins, aminoplast resins, nitrocellulose, ethyl cellulose, chlorinated rubber, cyclized rubber, glue, casein, dextrin and zein.
Claim 3
Dependent Claim
58 words
A dry planographic printing ink composition as claimed in claim 1 wherein the composition consists of 20 to 80% by weight of the vehicle for an ink, 1 to 40% by weight of the silicone modified alkyd resin and 3 to 40% by weight of the pigment based upon the total weight of the composition and the solvent.
Claim 4
Dependent Claim
47 words
A dry planographic printing ink composition as claimed in claim 1 wherein in said organopolysiloxane, R 1 is selected from the group consisting of methyl, ethyl, butyl, vinyl and phenyl and R 2 is selected from the group consisting of hydrogen, methyl, ethyl, propyl, butyl and vinyl.
Claim 5
Dependent Claim
49 words
A dry planographic printing ink composition as claimed in claim 1 wherein the pigment is an inorganic pigment selected from the group consisting of chrome yellow, chrome vermillion, prussian blue, red oxide, cadmium yellow, cadmium red, titanium white, carbon black, alumina white, barium sulfate, calcium carbonate and white lead.
Claim 6
Dependent Claim
50 words
A dry planographic printing ink composition as claimed in claim 1 wherein the pigment is an organic pigment selected from the group consisting of an insoluble azo pigment, azo lake pigment, polyazo pigment, phthalocyanine pigment, anthraquinone pigment, thioindigo pigment, perylene pigment, perynone pigment, quinacridone pigment, dioxazine pigment and ilgazine pigment.
Claim 7
Dependent Claim
17 words
A dry planographic printing ink composition as claimed in claim 1 wherein the solvent is a hydrocarbon.
Claim 8
Dependent Claim
34 words
A dry planographic printing ink composition as claimed in claim 6 wherein said solvent is selected from the group consisting of solvent naphtha having a high boiling point, alkylbenzene, spindle oil and machine oil.
Claim 9
Dependent Claim
52 words
A dry planographic printing ink composition as claimed in claim 1 wherein the composition contains the vehicle for an ink, the silicone modified alkyd resin, the pigment, the solvent and an auxiliary agent selected from the group consisting of wax, grease, plasticizer, stabilizing agent, dryer, assistant dryer, thickener, dispersing agent and filler.
Claim 10
Dependent Claim
34 words
A dry planographic printing ink composition as claimed in claim 8 wherein the auxiliary agent is used in a quantity of 5 to 15% by weight based upon the total weight of the composition.
Claim 11
Dependent Claim
19 words
A dry planographic printing ink composition as claimed in claim 1, wherein the vinyl resin is an acrylic resin.
Claim 12
Dependent Claim
84 words
A dry planographic printing ink composition as claimed in claim 1 wherein said silicone modified alkyd resin is a product which is obtained by premixing a vegetable oil with a polyhydric alcohol at a temperature of 200° to 250°C. for about one hour, cooling the obtained mixture to a temperature of 160° to 200°C., mixing the mixture with a polybasic acid and an organopolysiloxane for about one hour and then heating the resultant mixture to a temperature of 250° to 300°C. for several hours.
Claim 13
Dependent Claim
25 words
A dry planographic printing ink composition as claimed in claim 11 wherein the vegetable oil is linseed, perilla, tung, sesame, rape seed or soya-bean oil.
Claim 14
Dependent Claim
44 words
A dry planographic printing ink composition as claimed in claim 11 wherein the polyhydric alcohol is selected from the group consisting of ethylene glycol, diethylene glycol, triethylene glycol, propylene glycol, trimethylene glycol, tetramethylene glycol, glycerine, trimethylol propane, diglycerine, triglycerine, pentaerythritol, dipentaerythritol, mannitol and sorbitol.
Claim 15
Dependent Claim
55 words
A dry planographic printing ink composition as claimed in claim 11 wherein the polybasic acid is selected from the group consisting of phthalic anhydride, terephthalic acid, succinic acid, adipic acid, sebacic acid, maleic acid, maleic anhydride, fumaric acid, itaconic acid, citraconic acid, cyclopentadienemaleic anhydride addition product, terpene-maleic anhydride addition product and rosin-maleic anhydride addition product.
Claim 16
Dependent Claim
72 words
A dry planographic printing ink composition as claimed in claim 1 wherein said silicone modified alkyd resin is a product which is obtained by previously reacting together a vegetable oil, a polyhydric alcohol and a polybasic acid to synthesize an alkyd resin having a high acid value or a high OH value, adding said alkyd resin to an organopolysiloxane and effecting a reaction at a temperature of 140° to 180°C. with dehydration.
Claim 17
Dependent Claim
25 words
A dry planographic printing ink composition as claimed in claim 15 wherein the vegetable oil is linseed, perilla, tung, sesame, rape seed or soya-bean oil.
Claim 18
Dependent Claim
44 words
A dry planographic printing ink composition as claimed in claim 15 wherein the polyhydric alcohol is selected from the group consisting of ethylene glycol, diethylene glycol, triethylene glycol, propylene glycol, trimethylene glycol, tetramethylene glycol, glycerine, trimethylol propane, diglycerine, triglycerine, pentaerythritol, dipentaerythritol, mannitol and sorbitol.
Claim 19
Dependent Claim
55 words
A dry planographic printing ink composition as claimed in claim 15 wherein the polybasic acid is selected from the group consisting of phthalic anhydride, terephthalic acid, succinic acid, adipic acid, sebacic acid, maleic acid, maleic anhydride, fumaric acid, itaconic acid, citraconic acid, cyclopentadienemaleic anhydride addition product, terpene-maleic anhydride addition product and rosin-maleic anhydride addition product.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1979-03-23 | 1979-09-22 | 1980-03-23 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1983-03-23 | 1983-09-22 | 1984-03-23 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1987-03-23 | 1987-09-22 | 1988-03-23 | $7700.00 | Window Closed / Lapsed |