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Method for obtaining polyester laminates and said laminates

Assignee: Ashland LLC
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Filing: 1972-02-02
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Granted: 1976-03-23
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Expires: 1992-02-02
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Abstract

Abstract This invention relates to a method for obtaining improved adhesion in the preparation of polyester laminates by treating the surface with an isocyanate containing ethylenic unsaturation and then applying a polyester adhesive containing a peroxide curing agent and to the said laminates.

Inventors

  • 👤 William E. Jackson

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 15:13
CPC Classifications
B; B32; B32B; B32B27/00; B32B27/06; B32B27/08; C; C08; C08F; C08F299/00; C08F299/02; C08F299/04; C08F299/0442; C08F299/045; B32B27/36; B32B7/00; B32B7/04; B32B7/12; C08J; C08J5/00; C08J5/12; C08J5/124; C08J5/125; B32B2262/00; B32B2262/10; B32B2262/101; C08J2367/00; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31551; Y10T428/31565; Y10T428/31786

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 85 words
A method of forming a laminate of two specimens comprising treating the surface of a polyester specimen with an organic isocyanate containing ethylenic unsaturation, then applying a fluid adhesive comprising an organic peroxide curative and an unsaturated polyester to at least one of the specimens to be laminated, placing the treated polyester specimen in laminating relationship with the other specimen and curing the adhesive to bond the specimens together, said polyester specimen being the reaction product of a polycarboxylic acid or anhydride with a polyol.
Claim 2
Independent Claim 85 words
A method of forming a laminate of two specimens comprising treating the surface of a polyester specimen with an organic isocyanate containing ethylenic unsaturation, then applying a fluid adhesive comprising an organic peroxide curative and an unsaturated polyester to at least one of the specimens to be laminated, placing the treated polyester specimen in laminating relationship with the other specimen and curing the adhesive to bond the specimens together, said polyester specimen being the reaction product of a polycarboxylic acid or anhydride with a polyol.
Claim 3
Dependent Claim 45 words
The method of claim 1 wherein the peroxide has the formula ##EQU1## where R 1 , R' 1 , R 2 , R' 2 , R 3 and R' 3 are alkyl, aryl, or haloaryl and at least one R group can be peroxy alkyl.
Claim 4
Dependent Claim 46 words
The method of claim 1 wherein the compound used for treating the surface of the polyester specimen is the reaction product of an organic polyisocyanate with a reactive hydrogen material selected from the class of unsaturated carboxylic acid, unsaturated organic amines, unsaturated alcohol and unsaturated polyols.
Claim 5
Dependent Claim 20 words
The method of claim 1 wherein the treating compound is a reaction product of an organic polyisocyanate and diallyl amine.
Claim 6
Dependent Claim 15 words
The method of claim 3 wherein the reactive hydrogen material is an unsaturated polyester polyol.
Claim 7
Dependent Claim 20 words
The method of claim 3 wherein the reactive hydrogen material is said polyol and further is a hydroxyl terminated polybutadiene.

References Cited (Backward Citations)

US2606892A Cited
US2905582A Cited
US3505252A Cited
US3396063A Cited
US3463698A Cited
US3526572A Cited
US3546041A Cited
US3642553A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-03-23 1979-09-22 1980-03-23 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-03-23 1983-09-22 1984-03-23 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-03-23 1987-09-22 1988-03-23 $7700.00 Window Closed / Lapsed

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