Patent US3944522A successfully refreshed from Google Patents.
US3944522A
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US
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Aromatic polyhydrazide fiber of high modulus and high tenacity
Assignee: Toray Industries Inc
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Filing: 1972-06-16
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Granted: 1976-03-16
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Expires: 1992-06-16
Abstract
Abstract High modulus, high tenacity aromatic polyhydrazide fiber composed of A. a polyterephthal hydrazide unit B. a poly p-benzamide unit and C. a poly p-phenylene terephthalamide unit, and method of making same.
Inventors
- 👤 Shunroku Tohyama
- 👤 Takuma Jinda
- 👤 Shigemitsu Saito
- 👤 Yoshizo Tsuda
- 👤 Satoshi Shinohara
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-24 21:36
CPC Classifications
C; C08; C08G; C08G73/00; C08G73/06; C08G73/08; D; D01; D01F; D01F6/00; D01F6/58; D01F6/74
Claims Analysis
Total Claims: 5
Claim 1
Independent Claim
230 words
High modulus and high tenacity aromatic polyhydrazide fiber composed of a copolymer, at least 85 mol % of the polymer chain of which consists essentially of repeating units from the group consisting of p-phenylene terephthalamide (PT), terethphal hydrazide (HT) and para-benzamide (A) in amounts within the range surrounded by a hexagon obtained by connecting with straight lines the points R, S, T, U, V and W in the triangular coordinates in the FIGURE, which is a ternary diagram of compositions consisting of (HT), (PT) and (A) and the points R, S, T, U, V and W therein represent mol % compositions as follows: (HT) 75 60 42.5 30 60 70
(PT) 0 0 15 40 40 30
(A) 25 40 42.5 30 0 0 said copolymer also including not more than 15 mol % of units selected from the group consisting of (Ar 1 --Z 1 ) and (Ar 1 --Z 1 --Ar 2 --Z 2 ), wherein Ar 1 and Ar 2 are groups selected from the class consisting of ##SPC12## and a group obtained by replacing an H atom of these groups with an alkyl group or halogen, and Ar 1 and Ar 2 may be the same or different; Z 1 and Z 2 are groups selected from the class consisting of --CONH--, --NHCONH--and --CONH.NHCO--, and Z 1 and Z 2 may be the same or different.
Claim 2
Dependent Claim
230 words
High modulus and high tenacity aromatic polyhydrazide fiber composed of a copolymer, at least 85 mol % of the polymer chain of which consists essentially of repeating units from the group consisting of p-phenylene terephthalamide (PT), terethphal hydrazide (HT) and para-benzamide (A) in amounts within the range surrounded by a hexagon obtained by connecting with straight lines the points R, S, T, U, V and W in the triangular coordinates in the FIGURE, which is a ternary diagram of compositions consisting of (HT), (PT) and (A) and the points R, S, T, U, V and W therein represent mol % compositions as follows: (HT) 75 60 42.5 30 60 70
(PT) 0 0 15 40 40 30
(A) 25 40 42.5 30 0 0 said copolymer also including not more than 15 mol % of units selected from the group consisting of (Ar 1 --Z 1 ) and (Ar 1 --Z 1 --Ar 2 --Z 2 ), wherein Ar 1 and Ar 2 are groups selected from the class consisting of ##SPC12## and a group obtained by replacing an H atom of these groups with an alkyl group or halogen, and Ar 1 and Ar 2 may be the same or different; Z 1 and Z 2 are groups selected from the class consisting of --CONH--, --NHCONH--and --CONH.NHCO--, and Z 1 and Z 2 may be the same or different.
Claim 3
Dependent Claim
13 words
The fiber according to claim 1 wherein said copolymer is a random copolymer.
Claim 4
Dependent Claim
44 words
The fiber according to claim 1 wherein the inherent viscosity of said polymer is at least 1.0, said inherent viscosity measured at 25° C in a 0.5 gram polymer per 100 ml. dimethyl acetamide solvent solution, said solvent containing 2.5% by weight lithium chloride.
Claim 5
Dependent Claim
25 words
The fiber according to claim 1 having a tenacity of at least 5.0 g/d and an initial modulus of elasticity of at least 300 g/d.
References Cited (Backward Citations)
US3595951A
Cited
US3600350A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1979-03-16 | 1979-09-15 | 1980-03-16 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1983-03-16 | 1983-09-15 | 1984-03-16 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1987-03-16 | 1987-09-15 | 1988-03-16 | $7700.00 | Window Closed / Lapsed |