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US3944522A Expired / Lapsed US ⏱️ 0.0 years remaining

Aromatic polyhydrazide fiber of high modulus and high tenacity

Assignee: Toray Industries Inc
•
Filing: 1972-06-16
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Granted: 1976-03-16
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Expires: 1992-06-16
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Abstract

Abstract High modulus, high tenacity aromatic polyhydrazide fiber composed of A. a polyterephthal hydrazide unit B. a poly p-benzamide unit and C. a poly p-phenylene terephthalamide unit, and method of making same.

Inventors

  • 👤 Shunroku Tohyama
  • 👤 Takuma Jinda
  • 👤 Shigemitsu Saito
  • 👤 Yoshizo Tsuda
  • 👤 Satoshi Shinohara

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 19:52
CPC Classifications
C; C08; C08G; C08G73/00; C08G73/06; C08G73/08; D; D01; D01F; D01F6/00; D01F6/58; D01F6/74

Claims Analysis

Total Claims: 5
Claim 1
Independent Claim 230 words
High modulus and high tenacity aromatic polyhydrazide fiber composed of a copolymer, at least 85 mol % of the polymer chain of which consists essentially of repeating units from the group consisting of p-phenylene terephthalamide (PT), terethphal hydrazide (HT) and para-benzamide (A) in amounts within the range surrounded by a hexagon obtained by connecting with straight lines the points R, S, T, U, V and W in the triangular coordinates in the FIGURE, which is a ternary diagram of compositions consisting of (HT), (PT) and (A) and the points R, S, T, U, V and W therein represent mol % compositions as follows: (HT) 75 60 42.5 30 60 70 (PT) 0 0 15 40 40 30 (A) 25 40 42.5 30 0 0 said copolymer also including not more than 15 mol % of units selected from the group consisting of (Ar 1 --Z 1 ) and (Ar 1 --Z 1 --Ar 2 --Z 2 ), wherein Ar 1 and Ar 2 are groups selected from the class consisting of ##SPC12## and a group obtained by replacing an H atom of these groups with an alkyl group or halogen, and Ar 1 and Ar 2 may be the same or different; Z 1 and Z 2 are groups selected from the class consisting of --CONH--, --NHCONH--and --CONH.NHCO--, and Z 1 and Z 2 may be the same or different.
Claim 2
Dependent Claim 230 words
High modulus and high tenacity aromatic polyhydrazide fiber composed of a copolymer, at least 85 mol % of the polymer chain of which consists essentially of repeating units from the group consisting of p-phenylene terephthalamide (PT), terethphal hydrazide (HT) and para-benzamide (A) in amounts within the range surrounded by a hexagon obtained by connecting with straight lines the points R, S, T, U, V and W in the triangular coordinates in the FIGURE, which is a ternary diagram of compositions consisting of (HT), (PT) and (A) and the points R, S, T, U, V and W therein represent mol % compositions as follows: (HT) 75 60 42.5 30 60 70 (PT) 0 0 15 40 40 30 (A) 25 40 42.5 30 0 0 said copolymer also including not more than 15 mol % of units selected from the group consisting of (Ar 1 --Z 1 ) and (Ar 1 --Z 1 --Ar 2 --Z 2 ), wherein Ar 1 and Ar 2 are groups selected from the class consisting of ##SPC12## and a group obtained by replacing an H atom of these groups with an alkyl group or halogen, and Ar 1 and Ar 2 may be the same or different; Z 1 and Z 2 are groups selected from the class consisting of --CONH--, --NHCONH--and --CONH.NHCO--, and Z 1 and Z 2 may be the same or different.
Claim 3
Dependent Claim 13 words
The fiber according to claim 1 wherein said copolymer is a random copolymer.
Claim 4
Dependent Claim 44 words
The fiber according to claim 1 wherein the inherent viscosity of said polymer is at least 1.0, said inherent viscosity measured at 25° C in a 0.5 gram polymer per 100 ml. dimethyl acetamide solvent solution, said solvent containing 2.5% by weight lithium chloride.
Claim 5
Dependent Claim 25 words
The fiber according to claim 1 having a tenacity of at least 5.0 g/d and an initial modulus of elasticity of at least 300 g/d.

References Cited (Backward Citations)

US3595951A Cited
US3600350A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-03-16 1979-09-15 1980-03-16 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-03-16 1983-09-15 1984-03-16 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-03-16 1987-09-15 1988-03-16 $7700.00 Window Closed / Lapsed

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