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US3944494A Expired / Lapsed US ⏱️ 0.0 years remaining

Stabilization of trichlorodifluoro benzenes

Assignee: EIDP Inc
•
Filing: 1974-05-16
•
Granted: 1976-03-16
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Expires: 1994-05-16
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Abstract

Abstract Trichlorodifluorobenzene is thermally stabilized particularly in the presence of engineering metals by contacting it, especially when at temperatures greater than about 200°C, with solid alkaline earth carbonates or with alkali or alkaline earth borates in a sufficient amount. The method is particularly useful in Rankine-cycle engines using trichlorodifluorobenzene as the working fluid, when the stabilizer is contained in the boiler.

Inventors

  • 👤 Walter Mahler

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 22:02
CPC Classifications
F; F01; F01K; F01K25/00; F01K25/08

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 61 words
In a method of heat transfer wherein trichlorodifluorobenzenes are cycled through a thermal gradient including temperatures above about 200°C, the improvement which comprises contacting said trichlorodifluorobenzenes with a thermally stabilizing amount of a solid acid acceptor selected from the group consisting of alkali metal borates, alkali metal phosphates, alkaline earth metal carbonates, alkaline earth metal borates and alkaline earth metal phosphates.
Claim 2
Dependent Claim 61 words
In a method of heat transfer wherein trichlorodifluorobenzenes are cycled through a thermal gradient including temperatures above about 200°C, the improvement which comprises contacting said trichlorodifluorobenzenes with a thermally stabilizing amount of a solid acid acceptor selected from the group consisting of alkali metal borates, alkali metal phosphates, alkaline earth metal carbonates, alkaline earth metal borates and alkaline earth metal phosphates.
Claim 3
Dependent Claim 18 words
The method of claim 1 in which the trichlorodifluorobenzenes are in contact with steel, aluminum- or nickel-base alloys.
Claim 4
Dependent Claim 21 words
The method of claim 2 wherein the trichlorodifluorobenzenes are contacted with said acid acceptor at a temperature between 300°C and 430°C.
Claim 5
Dependent Claim 12 words
The method of claim 3 wherein said acid acceptor is sodium borate.
Claim 6
Dependent Claim 12 words
The method of claim 3 wherein said acid acceptor is calcium carbonate.
Claim 7
Dependent Claim 17 words
The method of claim 3 wherein said acid acceptor is Na 5 P 3 O 10 .
Claim 8
Dependent Claim 17 words
The method of claim 3 wherein said acid acceptor is Na 6 P 6 O 13 .

References Cited (Backward Citations)

US2824061A Cited
US3774393A Cited
US3834166A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-03-16 1979-09-15 1980-03-16 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-03-16 1983-09-15 1984-03-16 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-03-16 1987-09-15 1988-03-16 $7700.00 Window Closed / Lapsed

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