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US3944481A Expired / Lapsed US ⏱️ 0.0 years remaining

Conversion of crude oil fractions to olefins

Assignee: Dow Chemical Co
•
Filing: 1973-11-05
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Granted: 1976-03-16
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Expires: 1993-11-05
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Abstract

Abstract A catalytic process for hydrocracking crude oil fractions into a C 2 -C 5 alkane mixture having a normal paraffin to isoparaffin molar ratio greater than about 3:1 and thermally cracking this mixture to recover ethylene and propylene. The hydrocracking catalysts used are made from a Group VIII metal, a Group VI B metal or mixtures thereof, with a halogen supported on a silica-alumina support or a natural or synthetic faujasite. The catalysts must be sulfided prior to or during use.

Inventors

  • 👤 Milton Silas Wing
  • 👤 Billy Duane Head

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 16:48
CPC Classifications
C; C10; C10G; C10G69/00; C10G69/02; C10G69/06; C10G2400/00; C10G2400/20

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 212 words
A process for the production of an ethylene-propylene product which comprises: A. hydrocracking a crude oil fraction boiling in the range from 200° to 1000°F. by contacting a mixture of said fraction and hydrogen with a highly active sulfided hydrocracking catalyst under a pressure greater than about 400 psig wherein 1. the molar ratio of hydrogen to said fraction is in the range from about 4:1 to about 50:1; 2. the temperature range is from about 300° to about 565°C.; and 3. the residence time is from about one to about 180 seconds; 4. the catalyst comprises of Group VIII metal, a Group VI B metal, or mixtures thereof and a halogen supported on a catalyst support of silica-alumina mixtures, or a natural or synthetic faujasite; 5. conditions (1) - (3) are selected so as to produce a C 2 - C 5 product in a yield of 91- 95% and to achieve a normal paraffin to isoparaffin molar ratio greater than about 3:1 in the C 2 - C 5 portion of the hydrocracked product; B. separating the hydrocracked product of step (A) to recover a C 2 - C 5 alkane product; C. thermally cracking the C 2 - C 5 product and D. recovering ethylene and propylene as co-products.
Claim 2
Dependent Claim 212 words
A process for the production of an ethylene-propylene product which comprises: A. hydrocracking a crude oil fraction boiling in the range from 200° to 1000°F. by contacting a mixture of said fraction and hydrogen with a highly active sulfided hydrocracking catalyst under a pressure greater than about 400 psig wherein 1. the molar ratio of hydrogen to said fraction is in the range from about 4:1 to about 50:1; 2. the temperature range is from about 300° to about 565°C.; and 3. the residence time is from about one to about 180 seconds; 4. the catalyst comprises of Group VIII metal, a Group VI B metal, or mixtures thereof and a halogen supported on a catalyst support of silica-alumina mixtures, or a natural or synthetic faujasite; 5. conditions (1) - (3) are selected so as to produce a C 2 - C 5 product in a yield of 91- 95% and to achieve a normal paraffin to isoparaffin molar ratio greater than about 3:1 in the C 2 - C 5 portion of the hydrocracked product; B. separating the hydrocracked product of step (A) to recover a C 2 - C 5 alkane product; C. thermally cracking the C 2 - C 5 product and D. recovering ethylene and propylene as co-products.
Claim 3
Dependent Claim 20 words
The method of claim 1 wherein the crude oil fraction is a gas oil boiling in the range from 350°-800°F.
Claim 4
Dependent Claim 49 words
The method of claim 2 wherein 1. the molar ratio of hydrogen to said fraction is in the range from about 10:1 to about 30:1; 2. the temperature range is from about 450° to about 550°C.; and 3. the residence time is from about 5 to about 50 seconds.
Claim 5
Dependent Claim 145 words
In a process for the production of an ethylene-propylene product wherein a crude oil fraction boiling in the range from 200° to 1000°F. is hydrocracked with a highly active sulfided hydrocracking catalyst under a pressure greater than about 400 psig and the hydrocracked product is thermally cracked to yield an ethylene-propylene product, the improvement which comprises contacting the crude oil fraction with hydrogen in a molar ratio of hydrogen to said fraction in the range from about 4:1 to 50:1 at a temperature range from about 300° to about 565°C. with a residence time ranging from about 1 to about 180 seconds so as to produce a C 2 - C 5 product in a yield of 91- 95% and to achieve a normal paraffin to isoparaffin molar ratio greater than about 3:1 in the C 2 - C 5 portion of the hydrocracked product.
Claim 6
Dependent Claim 145 words
In a process for the production of an ethylene-propylene product wherein a crude oil fraction boiling in the range from 200° to 1000°F. is hydrocracked with a highly active sulfided hydrocracking catalyst under a pressure greater than about 400 psig and the hydrocracked product is thermally cracked to yield an ethylene-propylene product, the improvement which comprises contacting the crude oil fraction with hydrogen in a molar ratio of hydrogen to said fraction in the range from about 4:1 to 50:1 at a temperature range from about 300° to about 565°C. with a residence time ranging from about 1 to about 180 seconds so as to produce a C 2 - C 5 product in a yield of 91- 95% and to achieve a normal paraffin to isoparaffin molar ratio greater than about 3:1 in the C 2 - C 5 portion of the hydrocracked product.
Claim 7
Dependent Claim 22 words
The process of claim 4 wherein the crude oil fraction is a gas oil boiling in the range from 350° to 800°F.
Claim 8
Dependent Claim 47 words
The process of claim 5 wherein the molar ratio of hydrogen to said gas oil is in the range from about 10:1 to about 30:1, the temperature range is from about 450° to about 550°C. and the residence time is from about 5 to about 50 seconds.
Claim 9
Dependent Claim 123 words
A process for the production of an ethylene-propylene product which comprises: A. hydrocracking a crude oil fraction boiling in the range from 200° to 1000°F by contacting a mixture of said fraction and hydrogen with a highly active sulfided hydrocracking catalyst under a pressure greater than about 400 psig wherein 1. the molar ratio of hydrogen to said fraction is in the range from about 4:1 to about 50:1; 2. the temperature range is from about 300° to about 565°C.; and 3. the residence time is from about one to about 180 seconds; 4. the catalyst comprises a Group VIII metal, a Group VI B metal, or mixtures thereof supported on a catalyst support of silica-alumina mixtures, or a natural or synthetic faujasite;
Claim 10
Dependent Claim 123 words
A process for the production of an ethylene-propylene product which comprises: A. hydrocracking a crude oil fraction boiling in the range from 200° to 1000°F by contacting a mixture of said fraction and hydrogen with a highly active sulfided hydrocracking catalyst under a pressure greater than about 400 psig wherein 1. the molar ratio of hydrogen to said fraction is in the range from about 4:1 to about 50:1; 2. the temperature range is from about 300° to about 565°C.; and 3. the residence time is from about one to about 180 seconds; 4. the catalyst comprises a Group VIII metal, a Group VI B metal, or mixtures thereof supported on a catalyst support of silica-alumina mixtures, or a natural or synthetic faujasite;
Claim 11
Dependent Claim 84 words
conditions (1) - (3) are selected so as to produce a C 2 - C 5 product in a yield of 91-95% and to achieve a normal paraffin to isoparaffin molar ratio greater than about 3:1 in the C 2 - C 5 portion of the hydrocracked product; B. separating the hydrocracked product of step (A) to recover a C 2 - C 5 alkane product; C. thermally cracking the C 2 - C 5 product and D. recovering ethylene and propylene as co-products.
Claim 12
Dependent Claim 84 words
conditions (1) - (3) are selected so as to produce a C 2 - C 5 product in a yield of 91-95% and to achieve a normal paraffin to isoparaffin molar ratio greater than about 3:1 in the C 2 - C 5 portion of the hydrocracked product; B. separating the hydrocracked product of step (A) to recover a C 2 - C 5 alkane product; C. thermally cracking the C 2 - C 5 product and D. recovering ethylene and propylene as co-products.
Claim 13
Dependent Claim 20 words
The method of claim 7 wherein the crude oil fraction is a gas oil boiling in the range from 350°-800°F.
Claim 14
Dependent Claim 49 words
The method of claim 8 wherein 1. the molar ratio of hydrogen to said fraction is in the range from about 10:1 to about 30:1; 2. the temperature range is from about 450° to about 550°C.; and 3. the residence time is from about 5 to about 50 seconds.

References Cited (Backward Citations)

US2910428A Cited
US3268437A Cited
US3373220A Cited
US3399132A Cited
US3498906A Cited
US3839484A Cited
US3781195A Cited
US3726789A Cited
US3843510A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-03-16 1979-09-15 1980-03-16 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-03-16 1983-09-15 1984-03-16 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-03-16 1987-09-15 1988-03-16 $7700.00 Window Closed / Lapsed

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