Time temperature indicator

Claim 1

An indicator system in sealed container operable to signal the attainment of at least one preselected value corresponding to an integral of temperature, to which said system has been exposed, as a function of time, operable to permit visual inspection of the color of its contents comprising: a. solvolysis medium, where the solvolysis medium is an aqueous solvent, in the sealed container; b. an organic compound in the sealed container which is susceptible to solvolysis by the solvolysis medium said solvolysis following substantially first order kinetics in said medium, said solvolysis resulting in the generation of an acid; c. at least one alkaline material in the solvolysis medium of sufficient basicity to neutralize the acid generated the amount of said alkaline material being less than the stoichiometric equivalent of the total amount of acid which can be generated; d. at least one pH sensitive indicator in the sealed container which undergoes a discernible color change between the pH value of said alkaline material and the pH value of the acid generated; and means for maintaining the solvolysis medium separate from said organic compound; whereby causing said solvolysis medium and said organic compound to be mixed at a preselected time results in acid generation at a rate as a function of temperature predetermined by the selection of the solvolysis medium and organic compound; said acid being reacted with said alkaline substance the amount of said alkaline substance being selected so as to correspond to the amount of acid generated during a preselected time temperature integral value; thereby resulting in an excess of acid present at the end of such integral causing said discernible color change of the pH sensitive indicator.