Abstract Quinoline-2-carboxylic acids having in the 4-position a halogen atom or an optionally substituted hydrocarbyl group attached through an oxygen atom, optionally substituted by a hydrocarbyl group in the 3 position and optionally substituted in any of the 5, 6, 7 and 8 positions by halogen atoms, nitro or cyano groups, or optionally substituted hydrocarbyl groups each attained directly or through an oxygen atom, and containing in the substituents in the 3, 4, 5, 6, 7 and 8 positions a total of at least 3 carbon atoms form complexes with metals, especially copper. These complexes may be extracted by organic solvents from aqueous solutions of metal salts treated with the quinoline-2-carboxylic acids. The quinoline-2-carboxylic acids may be prepared from the corresponding 4-hydroxy compounds by (a) treating with a phosphorus halide, if necessary reacting the product with the alkali metal derivative of an alcohol or phenol and hydrolysing the ester group or (b) treating with a hydrocarbyl halide in presence of a base.
A quinoline-2-carboxylic acid of the formula ##SPC3## wherein R is a methoxy group or an alkyl group containing up to 12 carbon atoms, R 1 is a hydrogen atom or a methyl group, R 2 is a branched chain alkoxy group containing up to 12 carbon atoms, a phenoxy group substituted by one or two alkyl groups containing a total of not more than 12 carbon atoms or a benzyloxy group substituted by one or two alkyl groups containing a total of not more than 12 carbon atoms, and R 3 is a hydrogen atom or a n-propyl group.
Claim 2
Dependent Claim
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A quinoline-2-carboxylic acid of the formula ##SPC3## wherein R is a methoxy group or an alkyl group containing up to 12 carbon atoms, R 1 is a hydrogen atom or a methyl group, R 2 is a branched chain alkoxy group containing up to 12 carbon atoms, a phenoxy group substituted by one or two alkyl groups containing a total of not more than 12 carbon atoms or a benzyloxy group substituted by one or two alkyl groups containing a total of not more than 12 carbon atoms, and R 3 is a hydrogen atom or a n-propyl group.
Claim 3
Dependent Claim
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A quinoline-2-carboxylic acid as claimed in claim 1 wherein the groups, R, R 1 , R 2 and R 3 contain a total of from 6 to 20 aliphatic carbon atoms.
Claim 4
Dependent Claim
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A quinoline-2-carboxylic acid as claimed in claim 1 wherein the group R 2 is an isodecyloxy group.
Claim 5
Dependent Claim
12 words
A quinoline-2-carboxylic acid as claimed in claim 1 which is 3-n-propyl-6-n-butyl-4-isodecyloxyquinoline-2-carboxylic acid.