Process for preparing aromatic polymers in presence of alkali metal fluoride

Claim 2

A process for the preparation of an aromatic polymer consisting essentially of recurring units of the formula --Ar-Q-- which comprises heating a reaction mixture consisting essentially of an alkali metal fluoride and (a) a halophenol having the formula X-Ar-QH and/or (b) a substantially equimolar mixture of a dihalobenzenoid compound of the formula X-Ar-X and a dihydric phenol of the formula HQ-Ar-QH in which formulae Ar and Q are respectively a bivalent aromatic residue and an oxygen or sulphur atom and may vary from unit to unit in the polymer chain and X is a halogen atom, and each atom X is activated by a single electron attracting group selected from the group consisting of --CO-- and --SO 2 -- in the associated aromatic residue Ar, the amount of alkali metal fluoride being such that the number of fluorine atoms present as alkali metal fluoride together with any of the atoms X in the halophenol X-Ar-QH and/or dihalobenzenoid compound X-Ar-X that are fluorine, in the reaction mixture is at least twice the number of --QH groups in the reaction mixture.

Claim 3

A process according to claim 1 in which Q is an oxygen atom.

Claim 4

A process according to claim 1 in which Q is a sulphur atom.

Claim 5

A process according to claim 1 in which an alkali metal fluoride is heated with an activated halophenol having the formula X-Ar-QH.

Claim 6

A process according to claim 1 in which an alkali metal fluoride is heated with a substantially equimolar mixture of an activated dihalobenzenoid compound of the formula --Ar-X and a dihydric phenol of the formula HQ-Ar-QH.

Claim 7

A process according to claim 1 in which the alkali metal fluoride is potassium fluoride.

Claim 8

A process for the preparation of an aromatic polymer consisting essentially of recurring units of the formula --Ar-Q-- which comprises (1) forming a reaction mixture consisting essentially of a first component consisting of (a) a halophenol having the formula X-Ar-QH and/or (b) a substantially equimolar mixture of a dihalobenzenoid compound of the formula X-Ar-X and a dihydric phenol of the formula HQ-Ar-QH and a second component consisting of at least one of (c) and alkali metal fluoride, (d) a preformed fluorophenate having the formula F-Ar-QM and (e) a substantially equimolar mixture of a difluorobenzenoid compound of the formula F-Ar-F and a preformed bisphenate of the formula MQ-Ar-QM in which formulae AR is a bivalent aromatic residue, Q is an oxygen or sulphur atom, X is a halogen atom, each of said X and F atoms being activated by a single electron attracting group selected from the group consisting of --CO-- and --SO 2 -- in the associated aromatic residue Ar, and M is alkali metal, and said groups Ar and atoms Q may vary from unit to unit in the polymer chain, the amount of said second component being such that the number of fluorine atoms present as alkali metal fluoride, as F in the fluorophenate F-Ar-QM and/or difluorobenzenoid compound F-Ar-F, together with any of the atoms X in the first component that are fluorine, in the reaction mixture is from 2.0 to 2.1 times the number of --QH groups in the reaction mixture, (2) heating said reaction mixture and (3) extracting aromatic polymer from said reaction mixture.

Claim 9

A process for the preparation of an aromatic polymer consisting essentially of recurring units of the formula --Ar-Q-- which comprises (1) forming a reaction mixture consisting essentially of a first component consisting of (a) a halophenol having the formula X-Ar-QH and/or (b) a substantially equimolar mixture of a dihalobenzenoid compound of the formula X-Ar-X and a dihydric phenol of the formula HQ-Ar-QH and a second component consisting of at least one of (c) and alkali metal fluoride, (d) a preformed fluorophenate having the formula F-Ar-QM and (e) a substantially equimolar mixture of a difluorobenzenoid compound of the formula F-Ar-F and a preformed bisphenate of the formula MQ-Ar-QM in which formulae AR is a bivalent aromatic residue, Q is an oxygen or sulphur atom, X is a halogen atom, each of said X and F atoms being activated by a single electron attracting group selected from the group consisting of --CO-- and --SO 2 -- in the associated aromatic residue Ar, and M is alkali metal, and said groups Ar and atoms Q may vary from unit to unit in the polymer chain, the amount of said second component being such that the number of fluorine atoms present as alkali metal fluoride, as F in the fluorophenate F-Ar-QM and/or difluorobenzenoid compound F-Ar-F, together with any of the atoms X in the first component that are fluorine, in the reaction mixture is from 2.0 to 2.1 times the number of --QH groups in the reaction mixture, (2) heating said reaction mixture and (3) extracting aromatic polymer from said reaction mixture.

Claim 10

A process for the preparation of an aromatic polymer consisting essentially of recurring units of the formula --Ar-Q-- which comprises (1) forming a reaction mixture consisting essentially of a first component consisting of (a) a halophenol having the formula X-Ar-QH and/or (b) a substantially equimolar mixture of a dihalobenzenoid compound of the formula X-Ar-X and a dihydric phenol of the formula HQ-Ar-QH and a second component consisting of at least one of (c) an alkali metal fluoride, (d) a preformed fluorophenate having the formula F-Ar-QM and (e) a substantially equimolar mixture of a difluorobenzenoid compound of the formula F-Ar-F and a preformed bisphenate of the formula MQ-Ar-QM in which formulae Ar is a bivalent aromatic residue, Q is an oxygen or sulphur atom, X is a halogen atom, each of said X and F atoms being activated by a single electron attracting group selected from the group consisting of --CO-- and --SO 2 -- in the associated aromatic residue Ar, and M is alkali metal, and said groups Ar and atoms Q may vary from unit to unit in the polymer chain, the amount of said second component being such that the number of fluorine atoms present as alkali metal fluoride, as F in the fluorophenate F-Ar-QM and/or difluorobenzenoid compound F-Ar-F, together with any of the atoms X in the first component that are fluorine, in the reaction mixture is at least twice the number of --QH groups in the reaction mixture, and the amount of said components (d) and (e) being up to that wherein the number of fluorine atoms present as F in the fluorophenate F-Ar-QM and/or difluorobenzenoid compound F-Ar-F, together with any of the X atoms in the first component that are fluorine, equals twice the number of QH groups in the reaction mixture, (2) heating said reaction mixture and (3) extracting aromatic polymer from said reaction mixture.

Claim 11

A process for the preparation of an aromatic polymer consisting essentially of recurring units of the formula --Ar-Q-- which comprises (1) forming a reaction mixture consisting essentially of a first component consisting of (a) a halophenol having the formula X-Ar-QH and/or (b) a substantially equimolar mixture of a dihalobenzenoid compound of the formula X-Ar-X and a dihydric phenol of the formula HQ-Ar-QH and a second component consisting of at least one of (c) an alkali metal fluoride, (d) a preformed fluorophenate having the formula F-Ar-QM and (e) a substantially equimolar mixture of a difluorobenzenoid compound of the formula F-Ar-F and a preformed bisphenate of the formula MQ-Ar-QM in which formulae Ar is a bivalent aromatic residue, Q is an oxygen or sulphur atom, X is a halogen atom, each of said X and F atoms being activated by a single electron attracting group selected from the group consisting of --CO-- and --SO 2 -- in the associated aromatic residue Ar, and M is alkali metal, and said groups Ar and atoms Q may vary from unit to unit in the polymer chain, the amount of said second component being such that the number of fluorine atoms present as alkali metal fluoride, as F in the fluorophenate F-Ar-QM and/or difluorobenzenoid compound F-Ar-F, together with any of the atoms X in the first component that are fluorine, in the reaction mixture is at least twice the number of --QH groups in the reaction mixture, and the amount of said components (d) and (e) being up to that wherein the number of fluorine atoms present as F in the fluorophenate F-Ar-QM and/or difluorobenzenoid compound F-Ar-F, together with any of the X atoms in the first component that are fluorine, equals twice the number of QH groups in the reaction mixture, (2) heating said reaction mixture and (3) extracting aromatic polymer from said reaction mixture.

Claim 12

A process according to claim 7 in which Q is an oxygen atom.

Claim 13

A process according to claim 8 in which Q is an oxygen atom.

Claim 14

A process according to claim 7 in which Q is a sulphur atom.

Claim 15

A process according to claim 8 in which Q is a sulphur atom.

Claim 16

A process according to claim 7 in which the alkali metal is potassium.

Claim 17

A process according to claim 8 in which the alkali metal is potassium.