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Patent US3940447A successfully refreshed from Google Patents.
US3940447A
Expired / Lapsed
US
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Process for hydroformylation of olefin hydrocarbons
Assignee: Atlantic Richfield Co
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Filing: 1973-12-07
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Granted: 1976-02-24
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Expires: 1993-12-07
Abstract
Abstract A new, solid catalyst suitable for the hydroformylation of low molecular weight olefins is disclosed. The catalyst composition is a hydrido-platinum group metal carbonyl-Group VA electron donor ligand complex on a solid, sodium form natural or synthetic crystalline aluminosilicate support.
Inventors
- 👤 Jin Sun Yoo
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-24 14:34
CPC Classifications
B; B01; B01J; B01J31/00; B01J31/16; B01J31/24; B01J31/2404; B01J29/00; B01J29/04; B01J29/06; B01J29/064; B01J29/068; B01J31/1616; C; C07; C07C; C07C45/00; C07C45/49; C07C45/50; B01J2231/00; B01J2231/30; B01J2231/32; B01J2231/321; B01J2531/00; B01J2531/80; B01J2531/82; B01J2531/822; Y; Y02; Y02P; Y02P20/00; Y02P20/50
Claims Analysis
Total Claims: 10
Claim 1
Independent Claim
141 words
In the process for the hydroformylation of olefin hydrocarbons of 2 to about 16 carbon atoms the improvement which comprises conducting said hydroformylation in contact with a catalyst composition consisting of a major amount of a solid, sodium form crystalline alumino-silicate support, said crystalline aluminosilicate support having a silicato alumina mole ratio of from about 2:1 to 12:1, a sodium oxide-to-alumina mole ratio of from about 0.7:1 to 1.1:1 and pore diameters of from about 6 to 15 Angstroms, and a minor amount of providing about 0.2 to about 0.6 weight per cent rhodium, said rhodium composition having a mole ratio of ligand to metal of about 1.5:1to 3:1, said ligand being R 3 P in which each R is independently selected from the group consisting of phenylalkyl, alkylphenyl, phenyl, and alkyl groups having from 2 to about 16 carbon atoms.
Claim 2
Dependent Claim
141 words
In the process for the hydroformylation of olefin hydrocarbons of 2 to about 16 carbon atoms the improvement which comprises conducting said hydroformylation in contact with a catalyst composition consisting of a major amount of a solid, sodium form crystalline alumino-silicate support, said crystalline aluminosilicate support having a silicato alumina mole ratio of from about 2:1 to 12:1, a sodium oxide-to-alumina mole ratio of from about 0.7:1 to 1.1:1 and pore diameters of from about 6 to 15 Angstroms, and a minor amount of providing about 0.2 to about 0.6 weight per cent rhodium, said rhodium composition having a mole ratio of ligand to metal of about 1.5:1to 3:1, said ligand being R 3 P in which each R is independently selected from the group consisting of phenylalkyl, alkylphenyl, phenyl, and alkyl groups having from 2 to about 16 carbon atoms.
Claim 3
Dependent Claim
29 words
The process of claim 1 wherein the hydroformylation is conducted at a temperature of from about 100° to 350°C. and a pressure of from about 500 to 2500 psig.
Claim 4
Dependent Claim
10 words
The process of claim 2 wherein said olefin is pentene.
Claim 5
Dependent Claim
17 words
The process of claim 1 wherein the catalyst contains about 0.2 to 0.6 weight percent of rhodium.
Claim 6
Dependent Claim
29 words
The process of claim 4 wherein the hydroformylation is conducted at a temperature of from about 100° to 350°C. and a pressure of from about 500 to 2500 psig.
Claim 7
Dependent Claim
10 words
The process of claim 5 wherein said olefin is pentene.
Claim 8
Dependent Claim
56 words
A process of claim 1 wherein said support has pore diameters of from 10 to 14 Angstroms, a silica-to-alumina mole ratio of from about 4:1 to 6:1 and a sodium oxide to alumina mole ratio of about 0.9:1 to 1:1 and said support is a Type Y zeolite, and the activity coefficient is greater than 100.
Claim 9
Dependent Claim
28 words
The process of claim 7 wherein the hydroformylation is conducted at a temperature from about 100° to 350°C. and a pressure of from about 500 to 2,500 psig.
Claim 10
Dependent Claim
10 words
The process of claim 8 wherein said olefin is pentene.
References Cited (Backward Citations)
US3352924A
Cited
GB1332893A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1979-02-23 | 1979-08-25 | 1980-02-24 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1983-02-23 | 1983-08-25 | 1984-02-24 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1987-02-23 | 1987-08-25 | 1988-02-24 | $7700.00 | Window Closed / Lapsed |