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US3939110A Expired / Lapsed US ⏱️ 0.0 years remaining

Aqueous polyelectrolytic electrocoating materials of organic resins

Assignee: Primerica Inc
•
Filing: 1974-01-02
•
Granted: 1976-02-17
•
Expires: 1994-01-02
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Abstract

Abstract Improved aqueous electrocoating materials and methods providing improved coating deposits on metal substrates are obtained by adding an alcohol having from 1 to 8 preferably 2 to 4, carbon atoms to an organic coating resin having reactive sites at least partly but not completely neutralized, so that the alcohol is at least partly dispersed in the resin. The alcohol is preferably added before diluting the resin with water and is about 2.0 to 20 weight percent, preferably about 10 weight percent based on the resin.

Inventors

  • 👤 Kenneth Herman Colberg
  • 👤 Ronald Joseph Zukowski

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 08:28
CPC Classifications
C; C09; C09D; C09D5/00; C09D5/44; C09D5/4484; Y; Y10; Y10S; Y10S524/00; Y10S524/901

Claims Analysis

Total Claims: 4
Claim 1
Independent Claim 221 words
An aqueous polyelectrolytic electrocoating concentrate dispersable in water to form a bath used in contact with an anode and a cathode in an electric circuit of an electrocoating process for electrocoating a metal substrate, which comprises from about 20 to 60 weight percent synthetic polycarboxylic acid resin solids based on the concentrate, said solids being soluble in alcohols haivng from 1 to 5 carbon atoms, and having from 50 to 85 percent of their reactive sites neutralized with a sufficient quantity of water soluble amino compound to maintain the polycarboxylic acid resin solids as a dispersion of anionic polyelectrolyte in the concentrate, and a monohydric alcohol having from 1 to 5 carbon atoms selected from the group consisting of methanol, ethanol, propanol, isopropanol, n-butanol, isobutanol, sec-butanol, tert-butanol, amyl alcohol and isoamyl alcohol, said alcohol being at least partly associated with and dispersed in the resin concentrate in an amount of from 2.0 to 20 weight percent based on the weight of the resin solids, the presence of said alcohol being to at least maintain the resistivity and increase the throwing and wetting power of the medium bath, and to provide a higher quality, more pliable coating which releases more vapors from and leaves less voids in the coating upon curing than if said monohydric alcohol were not present in the concentrate.
Claim 2
Dependent Claim 221 words
An aqueous polyelectrolytic electrocoating concentrate dispersable in water to form a bath used in contact with an anode and a cathode in an electric circuit of an electrocoating process for electrocoating a metal substrate, which comprises from about 20 to 60 weight percent synthetic polycarboxylic acid resin solids based on the concentrate, said solids being soluble in alcohols haivng from 1 to 5 carbon atoms, and having from 50 to 85 percent of their reactive sites neutralized with a sufficient quantity of water soluble amino compound to maintain the polycarboxylic acid resin solids as a dispersion of anionic polyelectrolyte in the concentrate, and a monohydric alcohol having from 1 to 5 carbon atoms selected from the group consisting of methanol, ethanol, propanol, isopropanol, n-butanol, isobutanol, sec-butanol, tert-butanol, amyl alcohol and isoamyl alcohol, said alcohol being at least partly associated with and dispersed in the resin concentrate in an amount of from 2.0 to 20 weight percent based on the weight of the resin solids, the presence of said alcohol being to at least maintain the resistivity and increase the throwing and wetting power of the medium bath, and to provide a higher quality, more pliable coating which releases more vapors from and leaves less voids in the coating upon curing than if said monohydric alcohol were not present in the concentrate.
Claim 3
Dependent Claim 22 words
The improved electrocoating material of claim 1 wherein the alcohol is partly water soluble and has from 2 to 4 carbon atoms.
Claim 4
Dependent Claim 25 words
The improved electrocoating material of claim 2 wherein the alcohol is isopropanol present in an amount of about 10 weight percent based on the resin.

References Cited (Backward Citations)

US3575902A Cited
US3481892A Cited
US3624013A Cited
US3463712A Cited
US3657092A Cited
US3677984A Cited
US3703596A Cited
US3741923A Cited
US3819548A Cited
US3798193A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-02-16 1979-08-18 1980-02-17 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-02-16 1983-08-18 1984-02-17 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-02-16 1987-08-18 1988-02-17 $7700.00 Window Closed / Lapsed

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