Process for the production of high impact compositions of polyethylene and polypropylene block copolymers

Claim 1

A process for the preparation of a binary polypropylene composition having synergistic impact properties which comprises: 1. polymerizing propylene in a slurry in the presence of a catalytic amount of a catalyst formed by admixing a subhalide of a metal selected from the metals of Groups IVa, Va and VIa of the Periodic Table according to Mendeleef and an aluminum compound containing at least one carbon to metal bond to a solids content of 10 to 60 percent by weight to form a polypropylene preblock; 2. removing any volatiles present with said preblock to a level of no more than 5 percent by weight; 3. transferring said preblock while it still contains active catalyst to a continuously agitated reaction zone; 4. introducing ethylene and another α-olefin having from 3 to 8 carbon atoms to said reaction zone; 5. block copolymerizing said ethylene and other α-olefin onto said preblock in the vapor phase to form a random copolymer post block having from about 25 to about 75 mole percent ethylene derived units and constituting from about 5 to about 40 percent by weight of the total block copolymer; 6. deashing the block copolymer thus produced; 7. transferring the deashed copolymer to at least one agitated drying zone; 8. introducing a linear polyethylene having a melt index between about 0.5 and about 0.9 and a density of at least 0.93 to the drying zone in an amount corresponding to between about 3 and about 15 percent by weight of the total of the linear polyethylene component and the block copolymer component, and 9. recovering the polypropylene composition from said drying zone.