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US3937688A
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Copolyamides from an isomeric mixture of heptadecane dicarboxylic acid
Assignee: General Mills Chemicals Inc
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Filing: 1974-05-28
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Granted: 1976-02-10
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Expires: 1994-05-28
Abstract
Abstract Copolyamides of a C 19 diacid, a coacid selected from isophthalic acid, terephthalic acid, alkyl substituted isophthalic acid or esters thereof and a diamine selected from hexamethylene diamine and trimethyl hexamethylene diamine.
Inventors
- 👤 Edgar R. Rogier
- 👤 Allan H. Jevne
- 👤 Gerald L. Schwebke
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 08:56
CPC Classifications
C; C08; C08G; C08G69/00; C08G69/02; C08G69/26; C08G69/265
Claims Analysis
Total Claims: 10
Claim 1
Independent Claim
29 words
A noncrystalline, moisture insensitive polyamide consisting essentially of an amidification product of an acid component of (a) a mixture of isomers of heptadecane dicarboxylic acid having the formula ##EQU6##
Claim 2
Dependent Claim
29 words
A noncrystalline, moisture insensitive polyamide consisting essentially of an amidification product of an acid component of (a) a mixture of isomers of heptadecane dicarboxylic acid having the formula ##EQU6##
Claim 3
Dependent Claim
175 words
wherein x is an integer from 1 to 15, y is an integer from 1 to 15 and the sum of x and y is 16, and (b) an acid which is isophthalic acid, terephthalic acid, alkyl substituted isophthalic acid wherein the alkyl radical has from 1 to 12 carbon atoms or mixtures thereof; wherein the equivalent percentage of the heptadecane dicarboxylic acid in the acid component is from about 15 to 80% and of the acid which is isophthalic acid, terephthalic acid, alkyl substituted isophthalic acid or mixtures thereof is from about 85 to 20% based on the total acid component; and a diamine component which is hexamethylene diamine, or trimethylhexamethylene diamine, wherein the equivalents of the acid component and the diamine component are substantially equal, wherein the amidification reaction is conducted at a temperature between about 100°C. and 300°C., and wherein the amidification product has a logarithmic viscosity number of about 30 to 150 as measured in orthochlorophenol solvent at a concentration of 0.005 g./ml. by weight and at a temperature of 30°C.
Claim 4
Dependent Claim
175 words
wherein x is an integer from 1 to 15, y is an integer from 1 to 15 and the sum of x and y is 16, and (b) an acid which is isophthalic acid, terephthalic acid, alkyl substituted isophthalic acid wherein the alkyl radical has from 1 to 12 carbon atoms or mixtures thereof; wherein the equivalent percentage of the heptadecane dicarboxylic acid in the acid component is from about 15 to 80% and of the acid which is isophthalic acid, terephthalic acid, alkyl substituted isophthalic acid or mixtures thereof is from about 85 to 20% based on the total acid component; and a diamine component which is hexamethylene diamine, or trimethylhexamethylene diamine, wherein the equivalents of the acid component and the diamine component are substantially equal, wherein the amidification reaction is conducted at a temperature between about 100°C. and 300°C., and wherein the amidification product has a logarithmic viscosity number of about 30 to 150 as measured in orthochlorophenol solvent at a concentration of 0.005 g./ml. by weight and at a temperature of 30°C.
Claim 5
Dependent Claim
18 words
The embodiments of the invention in which an exclusive property or privilege is claimed are defined as follows:
Claim 6
Dependent Claim
16 words
The polyamide of claim 1 wherein the logarithmic viscosity number is from about 40 to 120.
Claim 7
Dependent Claim
16 words
The polyamide of claim 1 wherein the acid component is heptadecane dicarboxylic acid and isophthalic acid.
Claim 8
Dependent Claim
16 words
The polyamide of claim 1 wherein the acid component is heptadecane dicarboxylic acid and terephthalic acid.
Claim 9
Dependent Claim
35 words
The polyamide of claim 1 wherein the acid component is heptadecane dicarboxylic acid and alkyl substituted isophthalic acid having the formula ##SPC2## wherein R is an alkyl radical having from 1 to 12 carbon atoms.
Claim 10
Dependent Claim
26 words
The polyamide of claim 1 wherein the acid component includes a monocarboxylic acid in an amount up to about 1.5 equivalent percent of the acid component.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1979-02-09 | 1979-08-11 | 1980-02-10 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1983-02-09 | 1983-08-11 | 1984-02-10 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1987-02-09 | 1987-08-11 | 1988-02-10 | $7700.00 | Window Closed / Lapsed |