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US3936414A Expired / Lapsed US ⏱️ 0.0 years remaining

Flame-retardant resin compositions

Assignee: Lyondell Chemical Technology LP
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Filing: 1970-12-04
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Granted: 1976-02-03
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Expires: 1990-12-04
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Abstract

Abstract This specification discloses that certain polychlorinated or polybrominated aromatic hydrocarbon compounds can be incorporated in thermosetting polymer compositions to make the thermosetting compositions flame retardant without injuring the desirable physical and electrical properties of the thermosetting compositions when in the thermoset state. These polyhalogenated aromatic hydrocarbons are apparently caused to react into the thermosetting composition, provided there is a minimum of 1 mol of a polyunsaturated monomer containing carbon to carbon unsaturation for each 3 mols of polychlorinated aromatic hydrocarbons. The thermosetting compositions generally contain a polyunsaturated monomer, a polyunsaturated polymer with carbon to carbon double bond unsaturation or a polyphenylene ether polymer which may be used in place of some or all of the polyunsaturated polymer, and a polyhalogenated aromatic hydrocarbon, containing at least 50% by weight combined chlorine or bromine and whose molecular weight is greater than 200. These thermosetting compositions can be heat cured or thermoset by a free radical initiator at a temperature of at least 130°C, and can contain pigments, reinforcing fibers, release agents, coupling agents, and other incidental amounts of additives commonly used in thermosetting resin compositions.

Inventors

  • 👤 Carl Leonard Wright
  • 👤 Harry Hoyt Beacham

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 08:28
CPC Classifications
B; B29; B29C; B29C70/00; B29C70/58; B32; B32B; B32B15/00; B32B15/04; B32B15/08; C; C08; C08F; C08F283/00; C08F283/06; C08F283/08; C08K; C08K5/00; C08K5/02; C08K5/03; C08L; C08L67/00; C08L67/06; Y; Y10; Y10S; Y10S260/00; Y10S260/24; Y10S525/00; Y10S525/905

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 111 words
A thermosetting composition comprising: 1. 10 to 50 parts by weight of a polyunsaturated monomer; 2. 5 to 30 parts by weight of a polychlorinated or polybrominated aromatic hydrocarbon containing at least 50% by weight chlorine or bromine and having a molecular weight of at least 200; 3. 20 to 60 parts by weight of a polyphenylene ether polymer; 4. 0-30 parts by weight of a polyunsaturated polymer having carbon to carbon unsaturation and 5. 2-10 parts by weight per 100 parts of all of (1) plus (2) plus (3) plus (4) of a peroxide catalyst which has a 10 hour half-life in benzene at a temperature in excess of 100°C.
Claim 2
Dependent Claim 111 words
A thermosetting composition comprising: 1. 10 to 50 parts by weight of a polyunsaturated monomer; 2. 5 to 30 parts by weight of a polychlorinated or polybrominated aromatic hydrocarbon containing at least 50% by weight chlorine or bromine and having a molecular weight of at least 200; 3. 20 to 60 parts by weight of a polyphenylene ether polymer; 4. 0-30 parts by weight of a polyunsaturated polymer having carbon to carbon unsaturation and 5. 2-10 parts by weight per 100 parts of all of (1) plus (2) plus (3) plus (4) of a peroxide catalyst which has a 10 hour half-life in benzene at a temperature in excess of 100°C.
Claim 3
Dependent Claim 16 words
The composition of claim 1 further comprising a fluid in which the thermosetting composition is dispersed.
Claim 4
Dependent Claim 25 words
The composition of claim 1 in which the fluid is a solvent selected from the group consisting of chlorinated hydrocarbon solvents and aromatic hydrocarbon solvents.
Claim 5
Dependent Claim 32 words
The composition of claim 1 in which the polychlorinated or polybrominated aromatic hydrocarbon is selected from the group consisting of chlorinated or brominated biphenyls, chlorinated or brominated terphenyls, trichlorobenzene, and chlorinated naphthalenes.
Claim 6
Dependent Claim 35 words
The composition of claim 1 in which the polyunsaturated monomer is selected from the group consisting of diallyl phthalate, diallyl isophthalate, diallyl chlorendate, diallyl maleate, triallyl cyanurate, triallyl isocyanurate, glycol dimethylacrylate, and a divinyl benzene.
Claim 7
Dependent Claim 27 words
The composition of claim 1 in which the peroxide catalyst is selected from the group consisting of dicumyl peroxide, tertiary butyl perbenzoate, 2,5-dimethyl-2,5-di(tertiary-butylperoxy) hexyne-3 and 2,5-dimethyl-2,5-di(tertiary-butylperoxy) hexane.
Claim 8
Dependent Claim 27 words
The composition of claim 1 further comprising an inert filler selected from the group consisting of inorganic fillers, fibrous fillers, fibrous mats, woven fabric and non-woven fabric.

References Cited (Backward Citations)

US3361847A Cited
US3356761A Cited
US3507832A Cited
US3663654A Cited
US3862263A Cited
US3787532A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-02-02 1979-08-04 1980-02-03 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-02-02 1983-08-04 1984-02-03 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-02-02 1987-08-04 1988-02-03 $7700.00 Window Closed / Lapsed

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