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US3936307A Expired / Lapsed US ⏱️ 0.0 years remaining

Light and heat sensitive composition for producing a colored transfer complex image

Assignee: Panasonic Holdings Corp
•
Filing: 1973-08-02
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Granted: 1976-02-03
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Expires: 1993-08-02
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Abstract

Abstract A light and heat sensitive composition useful particularly in photographic reproduction, the composition comprising a combination of an electron donative material, such as a π-base and an electron acceptive material such as a π-acid both dispersed in an aqueous dispersion medium in the form of discrete particles, at least one of the electron donative and electron acceptive materials being capable of polymerization upon irradiation by actinic light or an actinic corpuscular ray and the materials producing a colored charge transfer complex under predetermined heating conditions.

Inventors

  • 👤 Shirow Asakawa
  • 👤 Katsue Hasegawa
  • 👤 Reiji Sano
  • 👤 Shunsuke Matsuda

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 15:46
CPC Classifications
G; G03; G03F; G03F7/00; G03F7/004; G03F7/027; B; B41; B41M; B41M5/00; B41M5/26; B41M5/30

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 171 words
A photosensitive composition essentially consisting of a dispersion phase in the form of discrete particles of (a) an aromatic compound having an electron donative group and being polymerizable upon exposure to actinic light and (b) an organic compound having a double bond conjugated with an electron attracting group relative to said electron donative group in a solid-hydrophilic-film-forming vehicle in which said combination is insoluble, said compound (a) being a compound selected from the group consisting of N-vinylcarbazole, vinylanthracene, N-benzylacrylamide, N-methoxyphenylmethaacrylamide, β-naphthylvinyl ether, p-phenylstyrene, vinyldiphenylamine, acenaphthylene, vinyl fluorene, β-vinylnaphthalene, 2-vinylphenanthrene, 3-vinylphenanthrene, 1-vinylpyrene and p-phenylenediacrylpropionate, said compound (b) being a compound selected from the group consisting of tetrabromoethylene, 1,2-dibromo-1-iodoethylene, α-chloro-3,5-dinitrostyrene, tetracyanoquinodimethane, tetracyanoethylene, chloranil, bromanil, quinone, anthraquinone, 2,4,7-trinitrofluorenone, trinitrobenzene, and tetranitropyrene, said combination being selected such that melting points of said compounds (a) and (b) differ from each other by more than 10°C and that said compounds (a) and (b) react with each other and produce a colored charge transfer complex when said combination is heated above the lower one of said melting points.
Claim 2
Dependent Claim 171 words
A photosensitive composition essentially consisting of a dispersion phase in the form of discrete particles of (a) an aromatic compound having an electron donative group and being polymerizable upon exposure to actinic light and (b) an organic compound having a double bond conjugated with an electron attracting group relative to said electron donative group in a solid-hydrophilic-film-forming vehicle in which said combination is insoluble, said compound (a) being a compound selected from the group consisting of N-vinylcarbazole, vinylanthracene, N-benzylacrylamide, N-methoxyphenylmethaacrylamide, β-naphthylvinyl ether, p-phenylstyrene, vinyldiphenylamine, acenaphthylene, vinyl fluorene, β-vinylnaphthalene, 2-vinylphenanthrene, 3-vinylphenanthrene, 1-vinylpyrene and p-phenylenediacrylpropionate, said compound (b) being a compound selected from the group consisting of tetrabromoethylene, 1,2-dibromo-1-iodoethylene, α-chloro-3,5-dinitrostyrene, tetracyanoquinodimethane, tetracyanoethylene, chloranil, bromanil, quinone, anthraquinone, 2,4,7-trinitrofluorenone, trinitrobenzene, and tetranitropyrene, said combination being selected such that melting points of said compounds (a) and (b) differ from each other by more than 10°C and that said compounds (a) and (b) react with each other and produce a colored charge transfer complex when said combination is heated above the lower one of said melting points.
Claim 3
Dependent Claim 157 words
A photosensitive composition essentially consisting of a dispersion phase in the form of discrete particles of (a) an aromatic compound having an electron donative group and (b) an organic compound having a double bond conjugated with an electron attracting group relative to said electron donative group and being polymerizable upon exposure to actinic light in a solid-hydrophilic-film-forming vehicle in which said combination is insoluble, said compound (a) being a compound selected from the group consisting of β-naphthylamine, 1,6-diaminopyrene, phenothiazine, dibenzophenothiazine, acridine, phenazine, o-phenanthroline, tetramethylbenzene, anthracene, benzidine, and diaminodiphenylamine, said compound (b) being a compound selected from the group consisting of tetrabromoethylene, 1,2-dibromo-1-iodoethylene, α-chloro-3,5-dinitrostyrene, said combination being selected such that melting points of said compounds (a) and (b) are different from each other by more than 10°C and that said compounds (a) and (b) react with each other and produce a colored charge transfer complex when said combination is heated above the lower one of said melting points.
Claim 4
Dependent Claim 157 words
A photosensitive composition essentially consisting of a dispersion phase in the form of discrete particles of (a) an aromatic compound having an electron donative group and (b) an organic compound having a double bond conjugated with an electron attracting group relative to said electron donative group and being polymerizable upon exposure to actinic light in a solid-hydrophilic-film-forming vehicle in which said combination is insoluble, said compound (a) being a compound selected from the group consisting of β-naphthylamine, 1,6-diaminopyrene, phenothiazine, dibenzophenothiazine, acridine, phenazine, o-phenanthroline, tetramethylbenzene, anthracene, benzidine, and diaminodiphenylamine, said compound (b) being a compound selected from the group consisting of tetrabromoethylene, 1,2-dibromo-1-iodoethylene, α-chloro-3,5-dinitrostyrene, said combination being selected such that melting points of said compounds (a) and (b) are different from each other by more than 10°C and that said compounds (a) and (b) react with each other and produce a colored charge transfer complex when said combination is heated above the lower one of said melting points.
Claim 5
Dependent Claim 31 words
A photosensitive composition as claimed in claim 2, wherein said solid-hydrophilic-film-forming vehicle is selected from the group consisting of gelatin, casein, gums, starch derivatives, polyvinyl alcohol, water-soluble polyacryl acids and polyvinylpyrrolidone.
Claim 6
Dependent Claim 50 words
A photosensitive composition as claimed in claim 2, wherein said combination is admixed with a sensitizing amount of an additive capable of initiating photopolymerization of said compound (b), said additive having a melting point at least 10°C higher than the lower value of the respective melting points of said compounds.
Claim 7
Dependent Claim 18 words
A photosensitive composition as claimed in claim 1 wherein compound (a) is N-vinylcarbazole and compound (b) is tetracyanoquinodimethane.
Claim 8
Dependent Claim 18 words
A photosensitive composition as claimed in claim 1 wherein compound (a) is vinylanthracene and compound (b) is anthraquinone.
Claim 9
Dependent Claim 18 words
A photosensitive composition as claimed in claim 2 wherein compound (a) is β-naphthylamine and compound (b) is α-chloro-3,5-dinitrostyrene.
Claim 10
Dependent Claim 31 words
A photosensitive composition as claimed in claim 1, wherein said solid-hydrophilic-film-forming vehicle is selected from the group consisting of gelatin, casein, gums, starch derivatives, polyvinyl alcohol, water-soluble polyacryl acids and polyvinylpyrrolidone.
Claim 11
Dependent Claim 50 words
A photosensitive composition as claimed in claim 1, wherein said combination is admixed with a sensitizing amount of an additive capable of initiating photopolymerization of said compound (a), said additive having a melting point at least 10°C higher than the lower value of the respective melting points of said compounds.

References Cited (Backward Citations)

US3607266A Cited
US3790376A Cited
US3697276A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-02-02 1979-08-04 1980-02-03 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-02-02 1983-08-04 1984-02-03 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-02-02 1987-08-04 1988-02-03 $7700.00 Window Closed / Lapsed

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