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US3935164A Expired / Lapsed US ⏱️ 0.0 years remaining

Light stabilized polymer compositions

Assignee: Novartis Corp
•
Filing: 1974-05-28
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Granted: 1976-01-27
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Expires: 1994-05-28
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Abstract

Abstract Organic polymeric materials normally subject to oxidative and ultraviolet light deterioration are stabilized by incorporating therein a nickel 3,5-bis-dialkyl-4-hydroxybenzoate, an ultraviolet light absorber such as benzophenone or a benzotriazole, and optionally a primary phenolic antioxidant with or without a secondary sulfur containing antioxidant.

Inventors

  • 👤 John d. Spivack
  • 👤 Peter P. Klemchuk

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 18:04
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/04; C08K5/13

Claims Analysis

Total Claims: 15
Claim 1
Independent Claim 147 words
A composition of matter stabilized against oxidative and ultraviolet light deterioration which comprises a. a synthetic organic polymer normally subject to ultraviolet and oxidative deterioration, b. from 0.001 to 5% by weight based on the weight of polymer of a nickel 3,5-di-t-alkyl-4-hydroxybenzoate having up to 8 carbon atoms in the t-alkyl group, c. from 0.001 to 5% by weight based on the weight of polymer of an ultraviolet light absorber selected from (1) 2-hydroxy-4-n-octoxybenzophenone, or (2) a benzotriazole selected from 2-(2'-hydroxy-3',5'-di-t-butylphenyl)-5-chlorobenzotriazole, 2-(2'-hydroxy-3,5-di-t-amylphenyl) benzotriazole or 2-(3'-t-butyl-2'-hydroxy-5'-methylphenyl)-5-chlorobenzotriazole, d. from 0 to 5% by weight based on the weight of a polymer of a phenolic antioxidant selected from n-octadecyl 3',5'-di-t-butyl-4'-hydroxyphenyl) propionate, tetrakis-{methylene 3-(3',5'-di-t-butyl-4'-hydroxyphenyl)propionate}methane, di-n-octadecyl 3,5-di-t-butyl-4-hydroxybenzylphosphonate, tris(3,5-di-t-butyl-4-hydroxybenzyl)isocyanurate, di-octadecyl-2-(3-t-bitu;-5-methyl-4-hydroxybenzyl)malonate, and 1,3,5-tris-(3,5-di-t-butyl-4-hydroxybenzyl)5-triazine-2,4,6-(IH,3H)-trione e. from 0 to 5% by weight based on the weight of polymer of an organosulfur compound selected from dilaurylthiodiproprionate and distearylthiodynapionate, provided that said composition is synergistic in its activity.
Claim 2
Dependent Claim 147 words
A composition of matter stabilized against oxidative and ultraviolet light deterioration which comprises a. a synthetic organic polymer normally subject to ultraviolet and oxidative deterioration, b. from 0.001 to 5% by weight based on the weight of polymer of a nickel 3,5-di-t-alkyl-4-hydroxybenzoate having up to 8 carbon atoms in the t-alkyl group, c. from 0.001 to 5% by weight based on the weight of polymer of an ultraviolet light absorber selected from (1) 2-hydroxy-4-n-octoxybenzophenone, or (2) a benzotriazole selected from 2-(2'-hydroxy-3',5'-di-t-butylphenyl)-5-chlorobenzotriazole, 2-(2'-hydroxy-3,5-di-t-amylphenyl) benzotriazole or 2-(3'-t-butyl-2'-hydroxy-5'-methylphenyl)-5-chlorobenzotriazole, d. from 0 to 5% by weight based on the weight of a polymer of a phenolic antioxidant selected from n-octadecyl 3',5'-di-t-butyl-4'-hydroxyphenyl) propionate, tetrakis-{methylene 3-(3',5'-di-t-butyl-4'-hydroxyphenyl)propionate}methane, di-n-octadecyl 3,5-di-t-butyl-4-hydroxybenzylphosphonate, tris(3,5-di-t-butyl-4-hydroxybenzyl)isocyanurate, di-octadecyl-2-(3-t-bitu;-5-methyl-4-hydroxybenzyl)malonate, and 1,3,5-tris-(3,5-di-t-butyl-4-hydroxybenzyl)5-triazine-2,4,6-(IH,3H)-trione e. from 0 to 5% by weight based on the weight of polymer of an organosulfur compound selected from dilaurylthiodiproprionate and distearylthiodynapionate, provided that said composition is synergistic in its activity.
Claim 3
Dependent Claim 15 words
A composition according to claim 1 which comprises a. polypropylene b. nickel bis-3,5-di-t-butyl-4-hydroxybenzoate c. 2-(2'-hydroxy-3',5'-di-t-amylphenyl)benzotriazole.
Claim 4
Dependent Claim 15 words
A composition according to claim 1 which comprises a. polypropylene b. nickel bis-3,5-di-t-butyl-4-hydroxybenzoate c. 2-(2'-hydroxy-3',5'-di-t-butylphenyl)-5-chlorobenzotriazole.
Claim 5
Dependent Claim 15 words
A composition according to claim 1 which comprises a. polypropylene b. nickel bis-3,5-di-t-butyl-4-hydroxybenzoate c. 2-hydroxy-4-n-octoxybenzophenone.
Claim 6
Dependent Claim 15 words
A composition according to claim 1 which comprises a. polypropylene b. nickel bis-3,5-di-t-butyl-4-hydroxybenzoate c. 2-(3'-t-butyl-2'-hydroxy-5'-methylphenyl)-5-chlorobenzotriazole.
Claim 7
Dependent Claim 18 words
A composition according to claim 1 which comprises a. polypropylene b. nickel bis-3,5-di-t-butyl-4-hydroxybenzoate c. 2-(2'-hydroxy-3',5'-di-t-amylphenyl)benzotriazole d. n-octadecyl 3(3',5'-di-t-butyl-4'-hydroxyphenyl)propionate.
Claim 8
Dependent Claim 18 words
A composition according to claim 1 which comprises a. polypropylene b. nickel bis-3,5-di-t-butyl-4-hydroxybenzoate c. 2-(2'-hydroxy-3',5'-di-t-butylphenyl)benzotriazole d. n-octadecyl 3(3',5'-di-t-butyl-4-hydroxyphenyl)propionate.
Claim 9
Dependent Claim 18 words
A composition according to claim 1 which comprises a. polypropylene b. nickel bis-3,5-di-t-butyl-4-hydroxybenzoate c. 2-hydroxy-4-n-octoxybenzophenone d. n-octadecyl 3(3',5'-di-t-butyl-4'-hydroxyphenyl)propionate.
Claim 10
Dependent Claim 18 words
A composition according to claim 1 which comprises a. polypropylene b. nickel bis-3,5-di-t-butyl-4-hydroxybenzoate c. 2-(5'-t-butyl-2'-hydroxy-5'-methylphenyl)-5-chlorobenzotriazole d. n-octadecyl 3(3',5'-di-t-butyl-4-hydroxyphenyl)propionate.
Claim 11
Dependent Claim 18 words
A composition according to claim 1 which comprises a. polypropylene b. nickel bis-3,5-di-t-butyl-4-hydroxybenzoate c. 2-(2'-hydroxy-3',5'-di-t-amylphenyl)benzotriazole d. tetrakis {methylene-3-(3',5'-di-t-butyl-4'-hydroxyphenyl)propionate}methane.
Claim 12
Dependent Claim 17 words
A composition according to claim 1 which comprises a. polypropylene b. nickel bis-3,5-di-t-butyl-4-hydroxybenzoate c. 2-(2'-hydroxy-3',5'-di-t-amylphenyl)benzotriazole d. di-n-octadecyl-3,5-di-t-butyl-4-hydroxybenzylphosphonate.
Claim 13
Dependent Claim 19 words
A composition according to claim 1 which comprises a. polypropylene b. nickel bis-3,5-di-t-butyl-4-hydroxybenzoate c. 2-(2'-hydroxy-3',5'-di-t-amylphenyl)benzotriazole d. 1,3,5-tris-(3,5-di-t-butyl-4-hydroxybenzyl)-5-triazine-2,4,6-(1H, 3H, 5H)-trione.
Claim 14
Dependent Claim 17 words
A composition according to claim 1 which comprises a. polypropylene b. nickel bis-3,5-di-t-butyl-4-hydroxybenzoate c. 2-(2'-hydroxy-3',5'-di-t-amylphenyl)benzotriazole d. di-n-octadecyl-2-(3-t-butyl-4-methyl-4-hydroxybenzyl)malonate.
Claim 15
Dependent Claim 20 words
A composition according to claim 1 which comprises a. polypropylene b. nickel bis-3,5-di-t-butyl-4-hydroxybenzoate c. 2-(2'-hydroxy-3',5'-di-t-amylphenyl)benzotriazole d. n-octadecyl 3(3',5'-di-t-butyl-4'-hydroxyphenyl)propionate e. distearylthiodipropionate.

References Cited (Backward Citations)

US3206431A Cited
US3481897A Cited
US3464953A Cited
US3464943A Cited
US3607828A Cited
US3642690A Cited
US3786021A Cited
US3838099A Cited
US3843595A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-01-26 1979-07-28 1980-01-27 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-01-26 1983-07-28 1984-01-27 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-01-26 1987-07-28 1988-01-27 $7700.00 Window Closed / Lapsed

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