US3935164A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Light stabilized polymer compositions
Assignee: Novartis Corp
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Filing: 1974-05-28
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Granted: 1976-01-27
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Expires: 1994-05-28
Abstract
Abstract Organic polymeric materials normally subject to oxidative and ultraviolet light deterioration are stabilized by incorporating therein a nickel 3,5-bis-dialkyl-4-hydroxybenzoate, an ultraviolet light absorber such as benzophenone or a benzotriazole, and optionally a primary phenolic antioxidant with or without a secondary sulfur containing antioxidant.
Inventors
- 👤 John d. Spivack
- 👤 Peter P. Klemchuk
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-02 14:37
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/04; C08K5/13
Claims Analysis
Total Claims: 15
Claim 1
Independent Claim
147 words
A composition of matter stabilized against oxidative and ultraviolet light deterioration which comprises a. a synthetic organic polymer normally subject to ultraviolet and oxidative deterioration, b. from 0.001 to 5% by weight based on the weight of polymer of a nickel 3,5-di-t-alkyl-4-hydroxybenzoate having up to 8 carbon atoms in the t-alkyl group, c. from 0.001 to 5% by weight based on the weight of polymer of an ultraviolet light absorber selected from (1) 2-hydroxy-4-n-octoxybenzophenone, or (2) a benzotriazole selected from 2-(2'-hydroxy-3',5'-di-t-butylphenyl)-5-chlorobenzotriazole, 2-(2'-hydroxy-3,5-di-t-amylphenyl) benzotriazole or 2-(3'-t-butyl-2'-hydroxy-5'-methylphenyl)-5-chlorobenzotriazole, d. from 0 to 5% by weight based on the weight of a polymer of a phenolic antioxidant selected from n-octadecyl 3',5'-di-t-butyl-4'-hydroxyphenyl) propionate, tetrakis-{methylene 3-(3',5'-di-t-butyl-4'-hydroxyphenyl)propionate}methane, di-n-octadecyl 3,5-di-t-butyl-4-hydroxybenzylphosphonate, tris(3,5-di-t-butyl-4-hydroxybenzyl)isocyanurate, di-octadecyl-2-(3-t-bitu;-5-methyl-4-hydroxybenzyl)malonate, and 1,3,5-tris-(3,5-di-t-butyl-4-hydroxybenzyl)5-triazine-2,4,6-(IH,3H)-trione e. from 0 to 5% by weight based on the weight of polymer of an organosulfur compound selected from dilaurylthiodiproprionate and distearylthiodynapionate, provided that said composition is synergistic in its activity.
Claim 2
Dependent Claim
147 words
A composition of matter stabilized against oxidative and ultraviolet light deterioration which comprises a. a synthetic organic polymer normally subject to ultraviolet and oxidative deterioration, b. from 0.001 to 5% by weight based on the weight of polymer of a nickel 3,5-di-t-alkyl-4-hydroxybenzoate having up to 8 carbon atoms in the t-alkyl group, c. from 0.001 to 5% by weight based on the weight of polymer of an ultraviolet light absorber selected from (1) 2-hydroxy-4-n-octoxybenzophenone, or (2) a benzotriazole selected from 2-(2'-hydroxy-3',5'-di-t-butylphenyl)-5-chlorobenzotriazole, 2-(2'-hydroxy-3,5-di-t-amylphenyl) benzotriazole or 2-(3'-t-butyl-2'-hydroxy-5'-methylphenyl)-5-chlorobenzotriazole, d. from 0 to 5% by weight based on the weight of a polymer of a phenolic antioxidant selected from n-octadecyl 3',5'-di-t-butyl-4'-hydroxyphenyl) propionate, tetrakis-{methylene 3-(3',5'-di-t-butyl-4'-hydroxyphenyl)propionate}methane, di-n-octadecyl 3,5-di-t-butyl-4-hydroxybenzylphosphonate, tris(3,5-di-t-butyl-4-hydroxybenzyl)isocyanurate, di-octadecyl-2-(3-t-bitu;-5-methyl-4-hydroxybenzyl)malonate, and 1,3,5-tris-(3,5-di-t-butyl-4-hydroxybenzyl)5-triazine-2,4,6-(IH,3H)-trione e. from 0 to 5% by weight based on the weight of polymer of an organosulfur compound selected from dilaurylthiodiproprionate and distearylthiodynapionate, provided that said composition is synergistic in its activity.
Claim 3
Dependent Claim
15 words
A composition according to claim 1 which comprises a. polypropylene b. nickel bis-3,5-di-t-butyl-4-hydroxybenzoate c. 2-(2'-hydroxy-3',5'-di-t-amylphenyl)benzotriazole.
Claim 4
Dependent Claim
15 words
A composition according to claim 1 which comprises a. polypropylene b. nickel bis-3,5-di-t-butyl-4-hydroxybenzoate c. 2-(2'-hydroxy-3',5'-di-t-butylphenyl)-5-chlorobenzotriazole.
Claim 5
Dependent Claim
15 words
A composition according to claim 1 which comprises a. polypropylene b. nickel bis-3,5-di-t-butyl-4-hydroxybenzoate c. 2-hydroxy-4-n-octoxybenzophenone.
Claim 6
Dependent Claim
15 words
A composition according to claim 1 which comprises a. polypropylene b. nickel bis-3,5-di-t-butyl-4-hydroxybenzoate c. 2-(3'-t-butyl-2'-hydroxy-5'-methylphenyl)-5-chlorobenzotriazole.
Claim 7
Dependent Claim
18 words
A composition according to claim 1 which comprises a. polypropylene b. nickel bis-3,5-di-t-butyl-4-hydroxybenzoate c. 2-(2'-hydroxy-3',5'-di-t-amylphenyl)benzotriazole d. n-octadecyl 3(3',5'-di-t-butyl-4'-hydroxyphenyl)propionate.
Claim 8
Dependent Claim
18 words
A composition according to claim 1 which comprises a. polypropylene b. nickel bis-3,5-di-t-butyl-4-hydroxybenzoate c. 2-(2'-hydroxy-3',5'-di-t-butylphenyl)benzotriazole d. n-octadecyl 3(3',5'-di-t-butyl-4-hydroxyphenyl)propionate.
Claim 9
Dependent Claim
18 words
A composition according to claim 1 which comprises a. polypropylene b. nickel bis-3,5-di-t-butyl-4-hydroxybenzoate c. 2-hydroxy-4-n-octoxybenzophenone d. n-octadecyl 3(3',5'-di-t-butyl-4'-hydroxyphenyl)propionate.
Claim 10
Dependent Claim
18 words
A composition according to claim 1 which comprises a. polypropylene b. nickel bis-3,5-di-t-butyl-4-hydroxybenzoate c. 2-(5'-t-butyl-2'-hydroxy-5'-methylphenyl)-5-chlorobenzotriazole d. n-octadecyl 3(3',5'-di-t-butyl-4-hydroxyphenyl)propionate.
Claim 11
Dependent Claim
18 words
A composition according to claim 1 which comprises a. polypropylene b. nickel bis-3,5-di-t-butyl-4-hydroxybenzoate c. 2-(2'-hydroxy-3',5'-di-t-amylphenyl)benzotriazole d. tetrakis {methylene-3-(3',5'-di-t-butyl-4'-hydroxyphenyl)propionate}methane.
Claim 12
Dependent Claim
17 words
A composition according to claim 1 which comprises a. polypropylene b. nickel bis-3,5-di-t-butyl-4-hydroxybenzoate c. 2-(2'-hydroxy-3',5'-di-t-amylphenyl)benzotriazole d. di-n-octadecyl-3,5-di-t-butyl-4-hydroxybenzylphosphonate.
Claim 13
Dependent Claim
19 words
A composition according to claim 1 which comprises a. polypropylene b. nickel bis-3,5-di-t-butyl-4-hydroxybenzoate c. 2-(2'-hydroxy-3',5'-di-t-amylphenyl)benzotriazole d. 1,3,5-tris-(3,5-di-t-butyl-4-hydroxybenzyl)-5-triazine-2,4,6-(1H, 3H, 5H)-trione.
Claim 14
Dependent Claim
17 words
A composition according to claim 1 which comprises a. polypropylene b. nickel bis-3,5-di-t-butyl-4-hydroxybenzoate c. 2-(2'-hydroxy-3',5'-di-t-amylphenyl)benzotriazole d. di-n-octadecyl-2-(3-t-butyl-4-methyl-4-hydroxybenzyl)malonate.
Claim 15
Dependent Claim
20 words
A composition according to claim 1 which comprises a. polypropylene b. nickel bis-3,5-di-t-butyl-4-hydroxybenzoate c. 2-(2'-hydroxy-3',5'-di-t-amylphenyl)benzotriazole d. n-octadecyl 3(3',5'-di-t-butyl-4'-hydroxyphenyl)propionate e. distearylthiodipropionate.
References Cited (Backward Citations)
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1979-01-26 | 1979-07-28 | 1980-01-27 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1983-01-26 | 1983-07-28 | 1984-01-27 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1987-01-26 | 1987-07-28 | 1988-01-27 | $7700.00 | Window Closed / Lapsed |