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US3933994A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for desulfurizing gases

Assignee: Kaiser Steel Delaware Inc
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Filing: 1974-03-20
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Granted: 1976-01-20
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Expires: 1994-03-20
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Abstract

Abstract A desulfurizing process wherein a gas stream containing SO 2 is contacted with a citric acid or citrate-containing solution, and a gas stream containing H 2 S is contacted with the resulting solution, whereby elemental sulfur is precipitated and removed. The rate of flow of the respective gases contacting the aforesaid solution is such that the amount of H 2 S and SO 2 contained in the solution after said solution has been contacted with the gas streams is substantially in the ratio of two mols of H 2 S to one mol of SO 2 . A portion at least of the solution from which elemental sulfur is removed is passed to the first step of the process, for contacting the gas stream containing SO 2 .

Inventors

  • 👤 Gerald L. Rounds

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-07 21:46
CPC Classifications
C; C01; C01B; C01B17/00; C01B17/02; C01B17/04; C01B17/05

Claims Analysis

Total Claims: 3
Claim 1
Independent Claim 234 words
A continuous process for desulfurizing the coke oven gas and sinter plant gas resulting from operation of an integrated steel mill and forming elemental sulfur which comprises, a. conveying a stream of sinter plant gas from its source to a heat exchanger to extract heat from said gas; b. contacting the cooled stream of sinter plant gas with a citric acid-containing solution to reduce the SO 2 content of said stream and increase the SO 2 content of said solution; c. returning the resulting stream of gas to the said heat exchanger to return heat thereto; d. discharging the resulting gas of increased temperature into a stack; e. contacting a stream of coke oven gas free of by-product constituents with the solution resulting from step b) to reduce the H 2 S content of said coke oven gas stream and increase the H 2 S content of said solution; f. the relative rates of flow of the two said gas streams being such that the amount of H 2 S and SO 2 contained in the solution resulting from step e) is substantially in the ratio of two moles of H 2 S to one mole of SO 2 , whereby elemental sulfur precipitates out of the solution; g. removing precipitated sulfur from the last said solution, and h. passing at least a portion of the solution resulting from step f) to step a).
Claim 2
Dependent Claim 234 words
A continuous process for desulfurizing the coke oven gas and sinter plant gas resulting from operation of an integrated steel mill and forming elemental sulfur which comprises, a. conveying a stream of sinter plant gas from its source to a heat exchanger to extract heat from said gas; b. contacting the cooled stream of sinter plant gas with a citric acid-containing solution to reduce the SO 2 content of said stream and increase the SO 2 content of said solution; c. returning the resulting stream of gas to the said heat exchanger to return heat thereto; d. discharging the resulting gas of increased temperature into a stack; e. contacting a stream of coke oven gas free of by-product constituents with the solution resulting from step b) to reduce the H 2 S content of said coke oven gas stream and increase the H 2 S content of said solution; f. the relative rates of flow of the two said gas streams being such that the amount of H 2 S and SO 2 contained in the solution resulting from step e) is substantially in the ratio of two moles of H 2 S to one mole of SO 2 , whereby elemental sulfur precipitates out of the solution; g. removing precipitated sulfur from the last said solution, and h. passing at least a portion of the solution resulting from step f) to step a).
Claim 3
Dependent Claim 36 words
The process of claim 1 wherein the said gases, after their sulfur contents have been lowered, are discharged from the citric acid containing solution at a temperature of about 50°C, and then reheated to about 100°C.

References Cited (Backward Citations)

US515084A Cited
US925751A Cited
US2031802A Cited
US2729543A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-01-19 1979-07-21 1980-01-20 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-01-19 1983-07-21 1984-01-20 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-01-19 1987-07-21 1988-01-20 $7700.00 Window Closed / Lapsed

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