Nitrogen-containing ester and lubricant containing the same

Claim 2

An oil-soluble nitrogen-containing mixed ester of a carboxy-containing interpolymer having low-temperature viscosity improving properties and a reduced specific viscosity of from about 0.05 to about 2, said ester being substantially free of titratable acidity and being characterized by the presence within its polymeric structure of at least one of each of three pendant polar groups: A. a relatively high molecular weight carboxylic ester group having at least eight aliphatic carbon atoms in the ester radical, B. a relatively low molecular weight carboxylic ester group having no more than seven aliphatic carbon atoms in the ester radical, and C. a carbonyl-polyamino group derived from a polyamino compound having one primary or secondary amino group, wherein the molar ratio of (A):(B):(C) is (60-90):(10-30):(2-15).

Claim 3

The ester of claim 1 wherein the molar ratio of (A):(B):(C) is (70-80):(15-25):5.

Claim 4

The ester of claim 1 wherein the carboxy-containing interpolymer has a reduced specific viscosity of from about 0.3 to about 1.

Claim 5

The ester of claim 1 wherein the relatively high molecular weight carboxylic ester group of (A) has from eight to 24 aliphatic carbon atoms, the relatively low molecular weight carboxylic ester group of (B) has from three to five carbon atoms and the carbonyl-polyamino group of (C) is derived from a primary-aminoalkyl-substituted tertiary amine.

Claim 6

The ester of claim 1 wherein the carboxy-containing interpolymer is a terpolymer of one molar proportion of styrene, one molar proportion of maleic anhydride, and less than about 0.3 molar proportion of a vinyl monomer.

Claim 7

An oil-soluble nitrogen-containing mixed-ester of a carboxy-containing interpolymer wherein the carboxy-containing interpolymer has a reduced specific viscosity of from about 0.05 to about 2, the mixed ester has low-temperature viscosity improving properties, and is substantially free of titratable acidity; and the interpolymer is derived from at least two types of monomers, the one type being a low molecular weight aliphatic olefin or styrene, and the other type being an alpha, beta- unsaturated aliphatic acid, anhydride or ester thereof, said nitrogen-containing mixed ester being further characterized by having three types of pendant polar groups derived from the carboxy groups of the interpolymer; said pendant polar groups being A. a relatively high molecular weight carboxylic ester group having at least eight aliphatic carbon atoms in the ester radical, B. a relatively low molecular weight carboxylic ester group having no more than seven aliphatic carbon atoms in the ester radical, and C. a carbonyl-polyamino group derived from a polyamino compound having one primary or secondary amino group; wherein the molar of (A):(B):(C) is (60-90):(10-30):(2-15).

Claim 8

An oil-soluble nitrogen-containing mixed-ester of a carboxy-containing interpolymer wherein the carboxy-containing interpolymer has a reduced specific viscosity of from about 0.05 to about 2, the mixed ester has low-temperature viscosity improving properties, and is substantially free of titratable acidity; and the interpolymer is derived from at least two types of monomers, the one type being a low molecular weight aliphatic olefin or styrene, and the other type being an alpha, beta- unsaturated aliphatic acid, anhydride or ester thereof, said nitrogen-containing mixed ester being further characterized by having three types of pendant polar groups derived from the carboxy groups of the interpolymer; said pendant polar groups being A. a relatively high molecular weight carboxylic ester group having at least eight aliphatic carbon atoms in the ester radical, B. a relatively low molecular weight carboxylic ester group having no more than seven aliphatic carbon atoms in the ester radical, and C. a carbonyl-polyamino group derived from a polyamino compound having one primary or secondary amino group; wherein the molar of (A):(B):(C) is (60-90):(10-30):(2-15).

Claim 9

A nitrogen-containing mixed ester according to claim 6 of a carboxy-containing interpolymer having a reduced specific viscosity of from about 0.05 to about 2, said interpolymer being derived from at least 2 monomers, the one being ethylene, propylene, isobutene or styrene and the other being maleic acid or anhydride, itaconic acid or anhydride or acrylic acid or ester, said ester being substantially free of titratable acidity and being characterized by the presence within its polymeric structure of at least one of each of three pendant polar groups derived from the carboxy groups of said ester: A. a relatively high molecular weight carboxylic ester group having at least eight aliphatic carbon atoms in the ester radical, B. a relatively low molecular weight carboxylic ester group having no more than seven aliphatic carbon atoms in the ester radical, C. a carbonyl-polyamino group derived from a polyamino compound having one primary or secondary amine group wherein the molar ratio of (A):(B):(C) is (60-90):(10-30):(2-15).

Claim 10

A nitrogen-containing mixed ester according to claim 7 wherein the molar ratio of (A):(B):(C) is (70-80):(15-25):(5).

Claim 11

A nitrogen-containing mixed ester according to claim 7 wherein the interpolymer is a styrene-maleic anhydride interpolymer having a reduced specific viscosity of from about 0.3 to about 1.

Claim 12

A nitrogen-containing mixed ester according to claim 7 wherein the relatively high molecular weight carboxylic ester group of (A) has from eight to 24 aliphatic carbon atoms, the relatively low molecular weight carboxylic acid group of (B) has from three to five carbon atoms and the carbonyl-polyamino group of (C) is derived from a primary-aminoalkyl-substituted tertiary amine.

Claim 13

A nitrogen-containing mixed ester according to claim 7 wherein the carboxy-containing interpolymer is a terpolymer of one molar proportion of styrene, one molar proportion of maleic anhydride, and less than about 0.3 molar proportion of a vinyl monomer.

Claim 14

A nitrogen-containing mixed ester characterized by low-temperature viscosity improving properties prepared by the process comprising the steps: 1. Partially esterifying a styrene-maleic anhydride interpolymer having a reduced specific viscosity of from about 0.05 to about 2 with a mixture of a relatively high molecular weight alcohol having at least seven aliphatic carbon atoms and a relatively low molecular weight alcohol having no more than six aliphatic carbon atoms so as to convert from about 50% to about 98% of the carboxy radicals of the interpolymer to ester radicals, the molar ratio of the relatively high molecular weight alcohol to the relatively low molecular weight alcohol being from about 2:1 to about 9:1, and 2. Substantially neutralizing the remaining carboxy radicals of said interpolymers with a polyamino compound having one primary or secondary amino group.

Claim 15

A nitrogen-containing mixed ester characterized by low-temperature viscosity improving properties prepared by the process comprising the steps: 1. Partially esterifying a styrene-maleic anhydride interpolymer having a reduced specific viscosity of from about 0.05 to about 2 with a mixture of a relatively high molecular weight alcohol having at least seven aliphatic carbon atoms and a relatively low molecular weight alcohol having no more than six aliphatic carbon atoms so as to convert from about 50% to about 98% of the carboxy radicals of the interpolymer to ester radicals, the molar ratio of the relatively high molecular weight alcohol to the relatively low molecular weight alcohol being from about 2:1 to about 9:1, and 2. Substantially neutralizing the remaining carboxy radicals of said interpolymers with a polyamino compound having one primary or secondary amino group.

Claim 16

A nitrogen-containing mixed ester according to claim 12 wherein the esterification of step (1) is carried out in a step-wise manner by esterifying the interpolymer first with the relatively high molecular weight alcohol and then with the relatively low molecular weight alcohol.

Claim 17

A nitrogen-containing mixed ester according to claim 12 wherein the esterification step of (1) is carried out by first esterifying the interpolymer with the relatively high molecular weight alcohol so as to convert at least about 70% of the carboxy radicals of the interpolymer to ester radicals and then with the relatively low molecular weight alcohol so as to convert at least about 90% of the carboxy radicals of the interpolymer to ester radicals.

Claim 18

A nitrogen-containing mixed ester according to claim 12 wherein said polyamino compound is N-aminoalkyl-substituted morpholine.